Fuel cell power plant and method for operating the same

• US 4,128,700 A
• Filed: 11/26/1977
• Issued: 12/05/1978
• Est. Priority Date: 11/26/1977
• Status: Expired due to Term

• Current Assignee: United Technologies Corporation (Raytheon Technologies Corporation d/b/a RTX)
• Original Assignee: United Technologies Corporation (Raytheon Technologies Corporation d/b/a RTX)
• Inventors: Sederquist, Richard A.
• Primary Examiner(s): Skapars, Anthony
• Application Number:
  US05/855,118
• Time in Patent Office: 374 Days
• Field of Search: 429/17, 429/19, 429/20, 429/26
• US Class Current: 429/415
• CPC Class Codes: H01M 8/0612 from carbon-containing material
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

In a fuel cell power plant the anode and cathode exhausts are combined and burned in a burner with a first portion of the burner exhaust being delivered into fuel conditioning apparatus to provide the heat for converting a carbonaceous fuel to hydrogen. The hydrogen is then fed to the anode side of the fuel cells. A second portion of the burner exhaust is preferably used to drive a turbocharger for compressing the fuel cell oxidant which is usually air. If the fuel cells do not operate on pressurized reactants, then the energy in the second portion of the burner exhaust can be used for any other suitable purpose.

Claims

1. In the method of operating a fuel cell power plant comprising a plurality of fuel cells, burner means, and fuel conditioning apparatus including a catalytic reactor for producing hydrogen, the steps of:

burning a mixture of fuel cell anode and cathode exhausts in said burner means;

feeding a carbonaceous fuel and a first portion of the burner means exhaust into said fuel conditioning apparatus and reacting the fuel therein;

feeding the fuel conditioning apparatus output to the anode side of the fuel cells; and

venting a second portion of the burner means exhaust.

2. The method according to claim 1 wherein said fuel cells operate on pressurized air as the oxidant, and wherein said power plant includes a turbocharger for pressurizing the air fed to the cathode side of said fuel cells, the additional step of driving said turbocharger with said second portion of the burner means exhaust prior to venting said second portion.

3. The method according to claim 1 including the step of preheating at least one of either the anode exhaust or cathode exhaust prior to introducing the exhaust into the burner means, said preheating being accomplished using the heat in the burner means exhaust.

4. The method according to claim 2 wherein the burner means includes a recycle burner and a vent burner, each receiving a portion of the fuel cell cathode exhaust and a portion of the fuel cell anode exhaust, the first portion of the burner means exhaust being the recycle burner exhaust and the second portion of the burner means exhaust being the vent burner means exhaust.

5. The method according to claim 4 wherein the vent burner is operated at or above stoichiometric conditions.

6. The method according to claim 2 wherein said burner means operates at or above stoichiometric conditions.

7. The method according to claim 5 wherein the mass flow rate of the first portion of the burner means exhaust is two to three times the mass flow rate of the second portion of the burner means exhaust.

8. The method according to claim 1 wherein the fuel conditioning apparatus includes a thermal gasifier, and wherein said step of feeding the carbonaceous fuel and the first portion of the burner means exhaust into the fuel conditioning apparatus comprises first feeding the carbonaceous fuel and the first portion of the burner means exhaust into the thermal gasifier and then feeding the thermal gasifier exhaust into the catalytic reactor, said reactor being a steam reforming reactor and operating solely on the heat in the thermal gasifier exhaust.

9. The method according to claim 2 wherein said catalytic reactor is a steam reforming reactor and the heat for driving the steam reforming reaction is the sensible heat in said first portion of the burner means exhaust.

10. In the method of operating a fuel cell power plant comprising a plurality of fuel cells, turbocharger means, recycle burner means, vent burner means, and fuel conditioning apparatus including a catalytic steam reforming reactor for producing hydrogen, the steps of:

feeding a first portion of the fuel cell anode exhaust and a first portion of the fuel cell cathode exhaust into the recycle burner means and burning the same therein;

feeding a second portion of the fuel cell anode exhaust and a second portion of the fuel cell cathode exhaust into the vent burner means and burning said second portions therein;

compressing air in the turbocharger and delivering said compressed air into the cathode side of the fuel cells as the oxidant therefor;

driving the turbocharger using the energy in the vent burner means exhaust by delivering said vent burner means exhaust into said turbocharger;

feeding a carbonaceous fuel and the recycle burner means exhaust into the fuel conditioning apparatus and reacting the fuel therein to produce hydrogen; and

feeding the hydrogen so produced to the anode side of the fuel cells.

11. The method according to claim 10 wherein the fuel conditioning apparatus includes a thermal gasifier upstream of the catalytic reactor, and said step of feeding the carbonaceous fuel and recycle burner means exhaust into the fuel conditioning apparatus comprises feeding the carbonaceous fuel and recycle burner means exhaust into the thermal gasifier and feeding the thermal gasifier output into the catalytic reactor.

12. The method according to claim 10 including using at least some of the heat generated in the burner means to preheat at least one of either the anode and cathode exhausts upstream of the recycle burner means and vent burner means.

13. In the method of operating a fuel cell power plant comprising a plurality of fuel cells which operate on pressurized air as the oxidant and pressurized hydrogen as the fuel, the steps of:

combining and burning the fuel cell anode and cathode exhausts;

catalytically reacting carbonaceous fuel and a first portion of the combusted anode and cathode exhausts in an endothermic steam reforming reaction using only the sensible heat in the combusted anode and cathode exhausts to drive the steam reforming reaction;

introducing the hydrogen produced by the steam reforming reaction into the anode side of the fuel cells; and

using the energy of a second portion of the combusted anode and cathode exhausts to pressurize the air fed to the cathode side of the fuel cells.

14. A fuel cell power plant comprising:

a plurality of fuel cells each having a cathode side and an anode side;

a source of carbonaceous fuel;

a source of air;

turbocharger means for compressing said air;

fuel conditioning apparatus for producing hydrogen, said apparatus including a catalytic reactor;

means for combusting a mixture of anode side exhaust and cathode side exhaust, wherein the fuel for said combustion is hydrogen in the anode side exhaust and the oxidant for said combustion is in the cathode side exhaust;

means for introducing the anode side exhaust and the cathode side exhaust into said means for combusting;

means for introducing a carbonaceous fuel and a first portion of the combusted anode and cathode side exhausts into said fuel conditioning apparatus;

means for introducing the hydrogen produced in said fuel conditioning apparatus into said anode sides of said fuel cells as the fuel therefor;

means for delivering a second portion of the combusted anode and cathode side exhausts into said turbocharger means for driving said turbocharger means; and

means for introducing the air compressed by said turbocharger means into said cathode sides of said fuel cells as the oxidant therefor.

15. The fuel cell power plant according to claim 14 wherein said fuel conditioning apparatus includes a thermal gasifier upstream of said catalytic reactor.

16. The fuel cell power plant according to claim 14 wherein said means for combusting comprises a recycle burner and a vent burner, said means for introducing the anode and cathode side exhausts into said means for combusting comprises means for introducing a portion of each of said anode and cathode side exhausts into each of said recycle and vent burners, and wherein said first portion of the combusted anode and cathode side exhausts is the exhausts from said recycle burner and said second portion of said exhausts is the exhausts from said vent burner.

17. A method for operating a fuel cell power plant wherein the power plant includes a plurality of fuel cells each having an anode side and a cathode side, comprising the steps of:

mixing the exhaust from the anode sides of the fuel cells with the exhaust from the cathode sides of the fuel cells and combusting said mixture to produce a hot gas stream;

mixing a carbonaceous fuel with a first portion of said hot gas stream and converting said fuel to hydrogen using the energy in said first portion of said hot gas stream, said step of converting including catalytic steam reforming of said fuel;

delivering said hydrogen produced into the anode sides of said fuel cells;

pressurizing air in a turbocharger and delivering said pressurized air into the cathode sides of said fuel cells; and

driving the turbocharger by delivering into said turbocharger a second portion of said hot gas stream.

18. The method of operating a fuel cell power plant, said power plant including a plurality of fuel cells each having an anode side and a cathode side, comprising the steps of:

mixing a first portion of the exhaust from the anode sides of the fuel cells with a first portion of the exhaust from the cathode sides of the fuel cells and combusting said mixture in a first burner to produce a first hot gas stream;

mixing a second portion of the exhaust from the anode sides of the fuel cells with a second portion of the exhaust from the cathode sides of the fuel cells and combusting said mixture to produce a second hot gas stream;

mixing a carbonaceous fuel with said first hot gas stream and converting said fuel to hydrogen using the energy in said first hot gas stream, said step of converting including catalytic steam reforming of said fuel;

delivering said hydrogen produced into the anode sides of said fuel cells;

pressurizing air in a turbocharger and delivering said pressurized air into the cathode sides of said fuel cells; and

driving the turbocharger by delivering thereinto said second hot gas stream.

19. The method according to claim 18 wherein said step of converting includes thermally gasifying said fuel before steam reforming said fuel.

20. The method according to claim 18 including the step of preheating at least one of said first or second portions of either said anode sides exhaust or said cathode sides exhausts or said mixtures of said exhausts using the heat generated by combusting said mixtures.