Method for waste recovery from a process of the production of diphenylolpropane

• US 4,131,749 A
• Filed: 08/25/1977
• Issued: 12/26/1978
• Est. Priority Date: 09/12/1976
• Status: Expired due to Term

• Current Assignee: Instytut Ciezkiej Syntezy Organicznej "Blachownia"
• Original Assignee: Instytut Ciezkiej Syntezy Organicznej "Blachownia"
• Inventors: Grzywa, Edward, Kiedik, Maciej, Kolt, Jozef, Terelak, Kazimierz, Czyz, Jerzy, Niezgoda, Anna
• Primary Examiner(s): Mars, Howard T.
• Assistant Examiner(s): Lone, Werren B.
• Application Number:
  US05/827,780
• Time in Patent Office: 488 Days
• Field of Search: 260/621 L, 260/621 A, 260/621 R, 260/624 H, 260/626 T, 568/781, 568/806
• US Class Current: 568/781
• CPC Class Codes: C07C 37/20 using aldehydes or ketones
• CPC Class Codes: C07C 37/52 by splitting polyaromatic compounds, e.g. polyphenolalkanes
• CPC Class Codes: C07C 39/04 Phenol
• CPC Class Codes: C07C 39/16 Bis-(hydroxyphenyl) alkanes; Tris-(hydroxyphenyl)alkanes
• CPC Class Codes: C07C 39/19 containing carbon-to-carbon double bonds but no carbon-to-carbon triple bonds

Abstract

The essence of the invention consists in heating the dian waste in the presence of sodium hypophosphite as a catalyst in amount of 0.01 - 0.5% by weight at a temperature of 150 to 250° C and under reduced pressure in the range of 5 to 50 mm Hg. As a result a destillate is obtained containing as main components phenol, o- and p-isopropenyl-phenol and their dimers at yield of about 40-74% by weight calculated in relation to the initial amount of dian waste. The distillate obtained was made up with fresh phenol or with phenol and acetone and brought into contact with strongly acid cation exchanger, such as Wofatit KPS, Zerolit 225, Wofatit OK-80, in consequence the o- and p-isopropenylphenol and their dimers reacted with phenol to obtain the dian, the latter being then separated by known methods.

Claims

1. A method for processing the waste products obtained in the production of diphenylolpropane by condensation of acetone with phenol in the presence of acid catalysts, which comprises catalytic pyrolysis of said waste products in the presence of sodium hypophosphite as catalyst in the amount of 0.01% to 0.5% by weight, at a temperature of 150°

to 250°

C. and under reduced pressure in the range of 5.50 mm Hg and recovering the resulting phenol, o-, and p- isopropenylphenol.