Isocyanurate specific electrode and method of analysis and quaternary ammonium isocyanuric acid salts therefore

• US 4,134,798 A
• Filed: 03/13/1978
• Issued: 01/16/1979
• Est. Priority Date: 03/13/1978
• Status: Expired due to Term

• Current Assignee: Clearon Corp. (Innovative Water Care, LLC)
• Original Assignee: FMC Corporation
• Inventors: Pinsky, Michael L.
• Primary Examiner(s): Kaplan, G. L.
• Application Number:
  US05/885,499
• Time in Patent Office: 309 Days
• Field of Search: 544/223, 204/195 M, 204/1 N, 204/1 K
• US Class Current: 205/780.5
• CPC Class Codes: C07D 251/32 Cyanuric acid; Isocyanuric acid
• CPC Class Codes: G01N 27/3335 the membrane containing at least one organic component G01N27/3271 takes precedence; aspects concerning the enzyme reagent in enzyme electrodes C12Q1/001

Abstract

An electrode that is specific for the isocyanurate ion, and capable of rapid determination of the free isocyanurate ion activity directly in solution uses as its sensing element a platinum wire covered with a polyvinyl chloride membrane. The membrane is plasticized with a solution of a quaternary ammonium salt of isocyanuric acid. When this electrode and a commercial reference electrode are immersed in a solution containing the isocyanurate ion, a differential voltage proportional to the isocyanurate ion concentration is generated which is detected by a pH meter.

Claims

1. An electrode specific for the isocyanurate ion and capable of determining isocyanurate ion activity in solutions comprising:

(a) a platinum conductor covered with a plasticized polyvinyl chloride composition containing a quaternary ammonium isocyanurate salt;

(b) means for electrically connecting the platinum conductor to a pH meter, and

(c) means for insulating said platinum conductor from said solution.

2. An electrode specific for the isocyanurate ion and capable of determining isocyanurate ion activity in solutions comprising a platinum surface, portion of which is covered with a plasticized polyvinyl chloride composition containing a quaternary ammonium isocyanurate salt, said surface which is not covered with said composition being covered by a substance that is impermeable to water and electrical conducting means attached to said electrode.

3. The electrode of claim 2 wherein said platinum is electrically connected to a shielded coaxial cable.

4. An electrode specific for the isocyanurate ion and capable of determining isocyanurate ion activity in solutions comprising a centrally located platinum wire one end of which is coated with a plasticized polyvinyl chloride composition containing a quaternary ammonium isocyanurate salt, said wire being surrounded from the coated end for a distance along the length of the wire by a substance that is impermeable to water.

5. The electrode of claim 4 wherein the other end of said platinum wire is electrically connected to a shielded coaxial cable.

6. A platinum redox electrode that has been modified by covering that part of the platinum that is exposed with a plasticized polyvinyl chloride composition containing a quaternary ammonium isocyanurate salt.

7. An electrochemical method of analyzing an aqueous solution for isocyanurate ion which comprises:

(a) immersing a reference electrode and a platinum electrode covered with a plasticized polyvinyl chloride resin containing a quaternary ammonium isocyanurate salt in a series of aqueous solutions containing known molar concentrations of isocyanurate ions;

(b) measuring the difference in potential between the reference electrode and covered platinum electrode when immersed in each of said solutions;

(c) preparing a calibration curve by plotting a function of the molar isocyanurate concentration of each solution against the differential potential developed in that solution;

(d) immersing said reference electrode and said platinum electrode in an unknown aqueous solution to be analyzed for isocyanurate activity and measuring the differential voltage developed; and

(e) determining from the measured differential voltage and the calibration curve the concentration of isocyanurate ion in said unknown aqueous solution.

8. The method of claim 7 wherein the quaternary ammonium salt is tricaprylylmethyl ammonium isocyanurate.

9. The method of claim 7 wherein the quaternary ammonium salt is tetrabutyl ammonium isocyanurate.

10. The method of claim 7 wherein the plasticizer is decanol.

11. A quaternary isocyanuric acid salt having the formula:

##STR2## wherein R₁, R₂, R₃ and R₄ are alkyl radicals of 1 to 18 carbon atoms and the total number of carbon atoms in all of the alkyl radicals is such that the quaternary ammonium salt is soluble in decanol.

12. The quaternary isocyanuric acid salt of claim 11 wherein R₁, R₂, R₃ and R₄ are butyl radicals.

13. The quaternary isocyanuric acid salt of claim 11 wherein R₁, R₂ and R₃ are caprylyl radicals and R₄ is a methyl radical.