Apparatus and system for producing coal gas

• US 4,137,052 A
• Filed: 08/17/1977
• Issued: 01/30/1979
• Est. Priority Date: 02/07/1977
• Status: Expired due to Term

• Current Assignee: Anthony A Du Pont, Joseph A. Connell
• Original Assignee: Anthony A Du Pont, Joseph A. Connell
• Inventors: Connell, Joseph A., du Pont, Anthony A.
• Primary Examiner(s): Fisher, Richard V.
• Assistant Examiner(s): Yeung, George C.
• Application Number:
  US05/825,271
• Time in Patent Office: 531 Days
• Field of Search: 48/89, 48/99, 48/101, 48/102 A, 48/105, 48/107, 48/113, 48/120, 48/67, 48/73, 48/77, 48/197 R, 48/202, 48/210, 23/277 R, 23/281 R, 110/31, 110/53, 165/140, 165/141, 202/106, 202/126, 202/115, 202/127, 432/210
• US Class Current: 48/89
• CPC Class Codes: C10J 2300/0906 Physical processes, e.g. shredding, comminuting, chopping, sorting
• CPC Class Codes: C10J 2300/093 Coal
• CPC Class Codes: C10J 2300/0956 Air or oxygen enriched air
• CPC Class Codes: C10J 2300/0976 as steam
• CPC Class Codes: C10J 2300/1671 with the production of electricity
• CPC Class Codes: C10J 2300/1807 Recycle loops, e.g. gas, solids, heating medium, water
• CPC Class Codes: C10J 2300/1823 for synthesis gas
• CPC Class Codes: C10J 2300/1884 with one stream being synthesis gas
• CPC Class Codes: C10J 2300/1892 with one stream being water/steam
• CPC Class Codes: C10J 3/10 using external heating
• CPC Class Codes: C10J 3/463 in stationary fluidised beds
• CPC Class Codes: C10J 3/466 Entrained flow processes
• CPC Class Codes: C10J 3/482 Gasifiers with stationary fluidised bed
• CPC Class Codes: C10J 3/485 Entrained flow gasifiers
• CPC Class Codes: C10J 3/56 Apparatus; Plants
• CPC Class Codes: C10J 3/76 Water jackets; Steam boiler-jackets
• CPC Class Codes: C10J 3/78 High-pressure apparatus
• CPC Class Codes: C10J 3/84 with means for removing dust or tar from the gas
• CPC Class Codes: C10J 3/86 combined with waste-heat boilers
• CPC Class Codes: Y02P 20/129 Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines

Abstract

Apparatus and system for producing coal gas from coal, air and water. Pulverized coal is introduced into a rising stream of air and steam in a retort to constitute a fluidized or entrained bed. The coal reacts with the steam and air to form a gas consisting of hydrogen, carbon monoxide, carbon dioxide, nitrogen, methane and higher hydrocarbons. In some cases the air may be eliminated to produce nitrogen-free gas. In other instances, the production of methane and higher hydrocarbons may be suppressed to produce a gas consisting primarily of hydrogen and carbon monoxide. The retort is constructed so that product gas and air may be burned in an annular space surrounding the central reaction column to produce hot flue gas. Steam tubes may be disposed in the annular space so that the steam and air introduced to the central reaction chamber may be super-heated by the hot flue gas. A further annular space or "wet wall" may be provided surrounding the first annular space through which the intake water is passed, so that the intake water may be brought to a boiling point and converted to steam prior to its being introduced into the steam superheating tubes. This construction causes the walls to the retort to be maintained at a higher temperature than the reaction inside the column, so that all the heat radiated from the walls of the reaction column is directed inwardly, and no heat is lost through the walls. The product gas from the retort is then cooled and passed through a water spray which cools the gas to nearly room temperature, and removes all the fly ash and other particulate matter from the gas.

Claims

1. Apparatus for producing coal gas comprising:

a retort having a central reaction column surrounded by a wall and having an outlet for hot coal gas produced by the reaction column;

means for introducing pulverized coal, or the like, into the reaction column;

wall means forming an annular chamber surrounding said first-named column in coaxial relationship therewith;

burner means coupled to said annular chamber;

means for introducing combustible gas and air into the annular chamber to be burned by said burner means so as to produce hot flue gas passing through the annular chamber for maintaining the wall of the reaction column at a temperature higher than the interior temperature of the reaction column so that heat is directed inwardly through the wall into the interior of the reaction column;

further wall means forming a second annular chamber surrounding the firstnamed annular chamber; and

means for introducing water into said second annular chamber to be heated by heat from said first-named annular chamber.

2. The apparatus defined in claim 1, and which includes means for introducing the water from said second annular chamber as steam into said reaction column to react with the pulverized coal.

3. The apparatus defined in claim 1, and which includes tubular members positioned in the first-named annular chamber for carrying steam for introduction into the reaction column, said steam being super-heated in the tubular members by the hot flue gas in the first-named annular chamber.

4. The apparatus defined in claim 1, and which includes waste heat boiler means coupled to said outlet of said retort to receive the hot coal gas from the retort;

means for introducing water into said waste heat boiler means for conversion into steam therein; and

means for introducing the resulting steam into said reaction column.

5. The apparatus defined in claim 4, and which includes water spray means coupled to the outlet of the waste heat boiler for cooling the hot gas introduced in the reaction column so as to condense excess steam therein and so as to remove fly ash and other particular matter therefrom.

6. The apparatus defined in claim 5, and which includes adsorption means coupled to said water spray means for adsorbing hydrogen sulphide and other constituents out of the gas from the spray means.

7. The apparatus defined in claim 6, and which includes further means coupled to said adsorption means for converting the hydrogen sulphide therefrom during a desorption mode into sulphur vapor and water, and for directing the gas effluent from the further means back through said adsorption means to remove the last traces of hydrogen sulphide and water.

8. The apparatus defined in claim 1, and which includes means for introducing air into the lower end of the central reaction chamber.