Tire protection composition

• US 4,137,206 A
• Filed: 02/14/1977
• Issued: 01/30/1979
• Est. Priority Date: 02/14/1977
• Status: Expired due to Term

• Current Assignee: New World Products Incorporated, Tri-Texas Incorporated
• Original Assignee: Tri-Texas Incorporated, World Products Pty Limited
• Inventors: Kent, Jerry B.
• Primary Examiner(s): Jacobs, Lewis T.
• Application Number:
  US05/768,024
• Time in Patent Office: 715 Days
• Field of Search: 252/72, 252/390, 106/33, 106/186, 260/29.6 N, 260/29.6 B, 260/29.6 BE, 260/29.6 BM, 260/42.51, 152/347
• US Class Current: 523/166
• CPC Class Codes: B29C 73/163 Sealing compositions or agents, e.g. combined with propellant agents
• CPC Class Codes: B29D 30/0633 After-treatment specially adapted for vulcanising tyres
• CPC Class Codes: B29L 2030/00 Pneumatic or solid tyres or parts thereof conveyor belts B29L2031/7092; drive belts B29L2031/7094; fourdrinier belts B29L2031/733
• CPC Class Codes: B60C 5/004 filled at least partially with liquid B60C19/12 takes precedence
• CPC Class Codes: C08K 5/17 Amines; Quaternary ammonium compounds
• CPC Class Codes: C08K 7/12 Asbestos
• CPC Class Codes: C08K 7/14 Glass
• CPC Class Codes: C08K 7/20 Glass
• CPC Class Codes: C08L 29/04 Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids

Abstract

A liquid tire sealing and/or tire balancing composition containing an organic volatile amine or amine salt soluble therein, which is effective to impart corrosion resistance to the metallic belts of a belted tire is disclosed. The organic volatile amine or amine salt component is selected from the group consisting of lower alkylamines, lower cycloalkylamines, naphthylamines, morpholines, benzothiazoles, and benzoate, carbonate and nitrite salts thereof. The composition is introduced into the metallic-belted tire cavity, and the volatile amine penetrates through the rubber and lays down a protective coating on the metallic belt without harming the metal to rubber bonding.

Claims

1. An aqueous liquid tire sealing and balancing composition capable of imparting corrosion resistance to metallic wire belts of belted elastomeric tires comprising:

(a) an aqueous solution of polyvinyl alcohol, the ratio of polyvinyl alcohol to water being from about 0.5;

100 to about 1;

100;

(b) a fibrous component of asbestos and fiberglass fibers, said fibrous component being present in an amount of from about 4% to about 10% by weight of said liquid tire sealing and balancing composition; and

,

(c) an organic volatile amine or amine salt capable of volatilizing within said tire, migrating to said elastomer, permeating the said elastomer and reaching the metallic wire belts thereof, said organic volatile amine or amine salt being selected from the group consisting of isopropylamine, dibutylamine, diisopropylamine, cyclohexylamine, dicyclohexylamine, isopropylhexylamine, ethylmorpholine, naphthylamine, the benzoate, carbonate or nitrite salts thereof and mixtures thereof, said amine or amine salt being present in an amount of from about 0.01% to about 0.5% by weight of said liquid tire sealing and balancing composition, said liquid tire sealing and balancing composition having a viscosity of from about 1000 to about 2200 cps. at 100°

F.

2. The liquid tire sealing and balancing composition of claim 1, further characterized in that the ratio of asbestos to fiberglass fibers is from about 20:

1 to about 100;

1, said asbestos fibers are from about 0.01 to about 3.0 inches in length and the fiberglass fibers are about 0.25 inches ±

0.125 inches in length.

3. The liquid tire sealing and balancing composition of claim 1 further characterized in that said nitrite salt of lower cycloalkylamine is cyclohexylamine nitrite.

4. An aqueous liquid tire sealing and balancing composition capable of imparting corrosion resistance to metallic belts of belted tire comprising:

(a) about 0.1% to about 5% by weight methylcellulose;

(b) about 12% to about 60% by weight ethylene glycol;

(c) about 40% to about 85% by weight water;

(d) a fibrous component of fiberglass and asbestos fibers, said fibrous component being present in an amount of from about 2% to about 4% by weight of said liquid tire sealing and balancing composition;

(e) an organic volatile amine or amine salt capable of volatilizing within said tire, migrating to said elastomer, permeating the said elastomer and reaching the metallic wire belts thereof, said organic volatile amine or amine salt selected from the group consisting of isopropylamine, dibutylamine, diisopropylamine, cyclohexylamine, dicyclohexylamine, isopropylhexylamine, ethylmorpholine, naphthylamine, the benzoate, carbonate or nitrite salts thereof and mixtures thereof, said amine or amine salt being present in an amount of from about 0.01% to about 0.5% by weight of said liquid tire sealing and balancing composition, said liquid tire sealing and balancing composition having a viscosity of from about 1000 to about 3000 cps. at 84°

F.

5. A method of imparting corrosion resistance to the metallic tire reinforcement elements within the elastomeric carcass of a tire which comprises introducing within said tire an aqueous tire balancing and/or sealing composition containing an organic volatile amine or amine salt capable of volatilizing within said tire, migrating to said elastomer, permeating said elastomer and reaching the metallic tire reinforcement elements, said organic volatile amine or amine salt being selected from the group consisting of isopropylamine, dibutylamine, diisopropylamine, cyclohexylamine, dicyclohexylamine, isopropylhexylamine, ethylmorpholine, naphthylamine, the benzoate, carbonate or nitrite salts thereof and mixtures thereof.

6. The method of claim 5 further characterized in that said amine salt is cyclohexylamine nitrite.