Method for forming tubesheets on hollow fiber tows and forming hollow fiber bundle assemblies containing same

• US 4,138,460 A
• Filed: 06/10/1977
• Issued: 02/06/1979
• Est. Priority Date: 06/10/1977
• Status: Expired due to Term

• Current Assignee: Cordis Dow Corp. (Baxter International Inc.)
• Original Assignee: Cordis Dow Corp. (Baxter International Inc.)
• Inventors: Tigner, Reuben A.
• Primary Examiner(s): Hoag, W.E.
• Application Number:
  US05/805,602
• Time in Patent Office: 606 Days
• Field of Search: 210/321 R, 210/22 R, 210/500 R, 210/506, 210/503-505, 210/508, 264/157, 264/159, 264/146, 264/271, 264/328, 264/259, 264/261, 264/263, 264/271, 264/258
• US Class Current: 264/159
• CPC Class Codes: B01D 63/0223 by fixing the hollow fibres prior to encapsulation
• CPC Class Codes: B29C 45/14385 Coating a portion of a bundle of inserts, e.g. making brushes
• CPC Class Codes: B29C 70/845 by moulding material on a relative small portion of the preformed parts

Abstract

A method of potting in a single or multi-cavity mold a plurality of fibers in continuous tow form to encapsulate the fibers, fill the interstices and form a solid tubesheet of selected shape and length. After transversely cutting through the thus formed tubesheet and the fibers therein a pair of tubesheets are formed each attached to and forming the end portion of a length of fibers. Potting at spaced longitudinal locations on the continuous tow, and transverse cutting, produces fiber bundle assemblies having a length of the tow of hollow fibers between a pair of axially spaced tubesheets. The process is semi-continuous or continuous, as desired.

Claims

1. A method for forming a tubesheet encapsulating a multiplicity of fibers in linearly arranged continuous tow form which comprises the steps of

(1) positioning a tow of fibers in a mold, said tow comprising a multiplicity of linearly arranged fibers,

(2) flowing a polymeric composition into said mold and through the interstices between said fibers in a direction substantially at a right angle to the longitudinal axis of said linearly arranged fibers and in a quantity and for a time sufficient to fill the interstices between said fibers and to fill said mold,

(3) causing said polymeric composition to solidify adjacent to the axial ends of said mold while said polymeric composition continues to flow across said fibers and to solidify and encapsulate said fibers therein to thereby form a tubesheet having the external configuration of the cavity of said mold, and

(4) removing said tubesheet from said mold.

2. A method in accordance with claim 1 wherein said fibers are hollow.

3. A method in accordance with claim 2 wherein said flowing polymeric composition is a low viscosity liquid.

4. A method in accordance with claim 2 wherein said polymeric composition is substantially prevented from flowing out of said mold axially along said hollow fibers.

5. A method in accordance with claim 2 wherein said polymeric composition is thermosetting.

6. A method in accordance with claim 2 wherein said polymeric composition is thermoplastic.

7. A method in accordance with claim 6 wherein said thermoplastic composition is a low viscosity liquid which is caused to flow upwardly through the interstices between said fibers in a quantity in excess of the amount required ot fill the interstices between said fibers and to fill said mold.

8. A method in accordance with claim 7 wherein said upward flow of said low viscosity thermoplastic liquid is continued for a time sufficient to eliminate voids in the interstices between said fibers and in said polymeric composition filling said mold.

9. A method for forming a tubesheet encapsulating a multiplicity of hollow fibers in linearly arranged continuous tow form which comprises the steps of

(1) providing a mold assembly comprising a mold portion having a preselected internal configuration and inlet means in a first portion thereof for introducing a liquid polymeric composition into said mold and outlet means in a second portion thereof for flow of said polymeric composition out of said mold, and combination fiber-clamping and cooling portions contiguous to each of the axial surfaces of said mold,

(2) positioning a tow of hollow semi-permeable fibers in said mold assembly and clamping said tow therein,

(3) while concurrently heating said mold portion and cooling said combination fiber-clamping and cooling portions of said mold assembly flowing a polymeric composition into said mold and through the interstices between said fibers in a direction substantially at a right angle to the longitudinal axis of said linearly arranged fibers and in a quantity and for a time sufficient to fill the interstices between said fibers and to fill said mold,

(4) causing said polymeric composition to solidify adjacent to the axial ends of said mold while said polymeric compositions continues to flow across said fibers and to solidify and encapsulate said fibers therein to thereby form a tubesheet having the external configuration of the cavity of said mold, and

(5) removing said tubesheet from said mold.

10. A method in accordance with claim 9 wherein said composition is a low viscosity thermoplastic liquid which is caused to flow through the interstices between said fibers in a quantity in excess of the amount required to fill the interstices between said fibers and to fill said mold.

11. A method in accordance with claim 9 wherein said polymeric composition is substantially prevented from flowing out of said mold axially along said fibers in said tow.

12. A method for forming a pair of tubesheets on a tow of semi-permeable hollow fibers and encapsulating the multiplicity of fibers in said tow which comprises the steps of:

(1) positioning a tow of hollow semi-permeable fibers in a mold, said tow comprising a multiplicity of semi-permeable, linearly arranged hollow fibers,

(2) flowing a polymeric composition into said mold and through the interstices between said fibers in a direction substantially at a right angle to the longitudinal axis of said linearly arranged fibers and in a quantity and for a time sufficient to fill the interstices between said fibers and to fill said mold,

(3) causing said polymeric composition to solidify adjacent to the axial ends of said mold while said polymeric composition continues to flow across said fibers and to solidify and encapsulate said fibers therein to thereby form a tubesheet having the external configuration of the cavity of said mold,

(4) removing said tubesheet from said mold, and

(5) transversely cutting through said tubesheet and the hollow fibers therein at a location between the axial end surfaces of said tubesheet which provides surfaces on the plane of said cut that are substantially free of voids to thereby form a pair of cut tubesheets defining the end portions of hollow fibers encapsulated by each said cut tubesheet.

13. A method in accordance with claim 12 wherein said solidified tubesheet formed in step 3 has an axial dimension greater than twice the sum of the axial dimensions of each of said pair of cut tubesheets formed in step 5.

14. A method for forming an improved hollow fiber bundle assembly comprising a tow of semi-permeable hollow fibers and a pair of spaced apart tubesheets thereon forming the end portions thereof, said tubesheets encapsulating and sealing therewithin the multiplicity of hollow fibers in said tow which comprises the steps of

(1) positioning a tow of hollow semi-permeable fibers in a mold, said tow comprising a multiplicity of semi-permeable, linearly arranged hollow fibers,

(2) flowing a polymeric composition into said mold and through the interstices between said fibers in a direction substantially at a right angle to the longitudinal axis of said linearly arranged fibers and in a quantity and for a time sufficient to fill the interstices between said fibers and to fill said mold,

(3) Causing said polymeric composition to solidify adjacent to the axial ends of said mold while said polymeric composition continues to flow across said fibers and to solidify and encapsulate said fibers therein to thereby form a first tubesheet having the external configuration of the cavity of said mold,

(4) removing said tubesheet from said mold and repositioning said tow in said mold at a location axially spaced along said tow from the said first tubesheet,

(5) repeating steps 2 and 3 to thereby form a second tubesheet, and

(6) transversely cutting through said first and said second tubesheets and the hollow fibers therein at a location between the axial end surfaces of each said first and said second tubesheets that are substantially free of voids in the planes of said cuts to thereby form said hollow fiber bundle assembly.

15. A method in accordance with claim 14 wherein said first and said second tubesheet each has an axial dimension greater than twice the sum of the axial dimension of the two tubesheets which are formed by the said transverse cuts in step 6.

16. An assembly line method for forming hollow fiber bundle assemblies, each assembly comprising a tow containing a multiplicity of linearly arranged fibers and a pair of tubesheets longitudinally spaced apart on said tow encapsulating the fibers therein and forming the end portions thereof which comprises the steps of

(1) providing a continuous tow of fibers comprising a multiplicity of fibers linearly arranged in substantially parallel array,

(2) providing a mold assembly comprising a plurality of tubesheet mold portions adapted to form tubesheets therein encapsulating said fiber tow, adjacent mold portions being axially spaced apart by an intervening cooling portion and having a cooling portion contiguous to each axial surface thereof, inlet and outlet means in each said mold portion for feeding a liquid polymeric composition into and from said mold,

(3) positioning said tow in said mold assembly and clamping said tow therein,

(4) flowing a heated liquid polymeric composition through said inlet means into said mold portions in a direction substantially at a right angle to the longitudinal axis of said linearly arranged fibers and in a quantity and for a time sufficient to fill the interstices between said fibers and to fill the cavities in said mold portions,

(5) causing said polymeric composition to solidify adjacent to the axial ends of said mold while said polymeric composition continues to flow across said fibers and to solidify and encapsulate said fibers therein to thereby form a tubesheet in each said mold portion,

(6) removing said tubesheets from said mold assembly, and

(7) transversely cutting through each said tubesheet and said fibers encapsulated therein on a plane adjacent to each of the axial end surfaces of each said tubesheet to thereby form a plurality of said fiber bundle assemblies.

17. A method in accordance with claim 16 wherein said mold assembly consists of two mold portions.

18. A method in accordance with claim 16 wherein said polymeric composition is thermoplastic.