Hetero-macrocyclic compound coated on the surface of solid

• US 4,142,020 A
• Filed: 07/05/1977
• Issued: 02/27/1979
• Est. Priority Date: 07/08/1976
• Status: Expired due to Term

• Current Assignee: Nippon Soda Company Limited
• Original Assignee: Nippon Soda Company Limited
• Inventors: Okamura, Hiromichi, Kato, Iwao, Torium, Kinuko, Hiraoka, Michio
• Primary Examiner(s): Ives, P. C.
• Application Number:
  US05/812,446
• Time in Patent Office: 602 Days
• Field of Search: 428/403, 428/411, 428/406, 428/412, 428/407, 428/417, 428/418, 428/408, 428/441, 428/451, 428/461, 428/474, 428/483, 428/454, 428/507, 428/516, 428/520
• US Class Current: 428/403
• CPC Class Codes: B01D 15/362 Cation-exchange
• CPC Class Codes: B01J 20/08 comprising aluminium oxide or hydroxide; comprising bauxite
• CPC Class Codes: B01J 20/103 comprising silica
• CPC Class Codes: B01J 20/14 Diatomaceous earth
• CPC Class Codes: B01J 20/262 obtained otherwise than by reactions only involving carbon to carbon unsaturated bonds, e.g. obtained by polycondensation macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds per se C08G
• CPC Class Codes: B01J 20/267 Cross-linked polymers
• CPC Class Codes: B01J 20/28004 Sorbent size or size distribution, e.g. particle size
• CPC Class Codes: B01J 20/28016 Particle form
• CPC Class Codes: B01J 20/3078 Thermal treatment, e.g. calcining or pyrolizing
• CPC Class Codes: B01J 20/3092 Packing of a container, e.g. packing a cartridge or column of chromatography columns B01D15/206
• CPC Class Codes: B01J 20/3204 Inorganic carriers, supports or substrates
• CPC Class Codes: B01J 20/321 consisting of a polymer obtained by reactions involving only carbon to carbon unsaturated bonds
• CPC Class Codes: B01J 20/3282 Crosslinked polymers
• CPC Class Codes: B01J 2220/58 Use in a single column
• CPC Class Codes: C02F 1/288 using composite sorbents, e.g. coated, impregnated, multi-layered
• CPC Class Codes: C08G 18/3243 containing two or more aromatic rings
• CPC Class Codes: C08G 18/3246 heterocyclic, the heteroatom being oxygen or nitrogen in the form of an amino group
• CPC Class Codes: C08G 18/38 having heteroatoms other than oxygen C08G18/32 takes precedence
• CPC Class Codes: C08G 59/504 containing an atom other than nitrogen belonging to the amine group, carbon and hydrogen
• CPC Class Codes: C08J 2325/06 Polystyrene
• CPC Class Codes: C08J 2327/06 : Homopolymers or copolymers of vinyl chloride
• CPC Class Codes: C08J 3/005 : Processes for mixing polymers
• CPC Class Codes: C08J 9/36 : After-treatment C08J9/22 takes precedence
• CPC Class Codes: C22B 3/24 : by adsorption on solid substances, e.g. by extraction with solid resins
• CPC Class Codes: Y02P 10/20 : Recycling
• CPC Class Codes: Y10T 428/2991 : Coated
• CPC Class Codes: Y10T 428/2996 : Glass particles or spheres
• CPC Class Codes: Y10T 428/2998 : including synthetic resin or polymer
• CPC Class Codes: Y10T 428/30 : Self-sustaining carbon mass or layer with impregnant or other layer
• CPC Class Codes: Y10T 428/31507 : Of polycarbonate
• CPC Class Codes: Y10T 428/31525 : Next to glass or quartz
• CPC Class Codes: Y10T 428/31529 : Next to metal
• CPC Class Codes: Y10T 428/31645 : Next to addition polymer from unsaturated monomers
• CPC Class Codes: Y10T 428/31667 : Next to addition polymer from unsaturated monomers, or aldehyde or ketone condensation product
• CPC Class Codes: Y10T 428/31692 : Next to addition polymer from unsaturated monomers
• CPC Class Codes: Y10T 428/31725 : Of polyamide
• CPC Class Codes: Y10T 428/31797 : Next to addition polymer from unsaturated monomers
• CPC Class Codes: Y10T 428/3188 : Next to cellulosic
• CPC Class Codes: Y10T 428/31913 : Monoolefin polymer
• CPC Class Codes: Y10T 428/31928 : Ester, halide or nitrile of addition polymer

Abstract

Hetero-macrocyclic compound coated on the surface of a solid comprising a reaction mixture of (a) hetero-macrocylic compound having at least one amino group in the molecule and (b) a compound selected from the group consisting of an epoxy compound and a isocyanate compound.

Claims

1. A hetero-macrocyclic compound coated on the surface of a solid useful for the selective capture of a cation, comprising a reaction mixture of:

(a) a hetero-macrocyclic compound having at least one amino group in the molecule having the following structural formula;

##STR13## wherein X is an amino- or alkylamino-substituted divalent aromatic or alicyclic hydrocarbon radical, or hetero-cyclic radical or --NH--;

Y is an amino- or alkylamino-substituted aromatic or alicyclic hydrocarbon radical or heterocyclic radical, --CH₂ --CH₂ --, ##STR14## L₁, L₂, L₃ and L₄ are independently --O--, --S--, or ##STR15## (and R is a hydrocarbon radical having 1 to 10 carbon atoms);

p and q are independently 2 or 3;

r is 1, 2 or 3; and

m and n are independently from 1 to 7; and

, (b) a compound selected from the group consisting of an epoxy compound and an isocyanate compound.

2. A hetero macrocyclic compound coated on the surface of the solid of claim 1, wherein the solid is selected from the group consisting of metal, glass, ceramic, alumina, silica, diatomaceous earth, carbon, sand, clay, cellulose, polyamide, polystyrene, polyester and polyacrylonitrile.