Nitrogen dioxide sensing element and method of sensing the presence of nitrogen dioxide

• US 4,142,400 A
• Filed: 03/07/1977
• Issued: 03/06/1979
• Est. Priority Date: 03/07/1977
• Status: Expired due to Term

• Current Assignee: Johnson Service Company
• Original Assignee: Johnson Controls, Inc. (Johnson Controls International plc)
• Inventors: Thoma, Paul E., Colla, Jeannine O.
• Primary Examiner(s): Ruehl, Charles A.
• Application Number:
  US05/774,765
• Time in Patent Office: 729 Days
• Field of Search: 73/23, 73/27 R, 338/34, 338/35, 23/254 E
• US Class Current: 73/31.06
• CPC Class Codes: G01N 27/12 of a solid body in dependence upon absorption of a fluid; of a solid body in dependence upon reaction with a fluid , for detecting components in the fluid
• CPC Class Codes: H01C 17/20 by pyrolytic processes

Abstract

An element for sensing the presence of nitrogen dioxide gas in the environment. The element comprises a film of a pyrolyzed polyaromatic polymer having semi-conductive properties which is mounted on an electrically non-conductive base. Electrical leads are attached at spaced locations to the film and are connected in an electrical circuit with a signalling or control mechanism. The presence of nitrogen dioxide gas will cause a change in the electrical characteristics of the film to thereby activate the mechanism. A heating element can be associated with the base to insure constant temperature and humidity conditions.

Claims

1. An element capable of sensing the presence of nitrogen dioxide in the environment, comprising a film of a pyrolyzed polyaromatic polymer, and electrical leads connected to said film at spaced locations, the presence of nitrogen dioxide in the environment causing a change in the electrical characteristics of the film.

2. The element of claim 1, wherein said polymer is selected from the group consisting of polyamides, polyamideimides, polyimides and polybenzimidazoles.

3. The element of claim 1, and including an electrically non-conductive base to support the film.

4. The element of claim 3, wherein said film has a thickness in the range of 0.3 to 5 mils.

5. The element of claim 3, and including heating means connected to said base for maintaining the base at a temperature substantially above ambient temperature to thereby minimize the effect of ambient temperature and humidity variations.

6. The element of claim 1, and including non-corroding metal layers disposed on a surface of said film at spaced locations, said leads being connected to said layers.

7. An element capable of sensing the presence of nitrogen dioxide in the environment, comprising a film of pyrolyzed polyaromatic polymer having nitrogen as a part of the ring structure and being electrically responsive to nitrogen dioxide, an electrically non-conductive base to support the film, and electrical leads connected to said film at spaced locations, the presence of nitrogen dioxide in the environment causing a change in the electrical characteristics of the film.

8. An element capable of sensing the presence of nitrogen dioxide gas in the environment, comprising an electrically non-conductive base, a film of pyrolyzed polyaromatic polymer secured to a surface of said base and having semi-conductor characteristics, electrical leads connected to the film at spaced locations thereon, the presence of nitrogen dioxide gas causing a change in the electrical characteristics of said film, and heating means connected to the opposite surface of the base for heating the base to a temperature substantially above ambient temperature.

9. A system for sensing the presence of nitrogen dioxide gas in the environment, comprising a sensing element including an electrically non-conductive base, and a film of a pyrolyzed polyaromatic polymer secured to a surface of said base, said element also including a pair of electrical terminals connected to the film at spaced locations thereon, a source of electrical power, signalling means, and an electrical circuit connecting said terminals, said source of power and said signaling means, the presence of nitrogen dioxide gas in the atmosphere causing a change in the electrical characteristics of said film to thereby actuate said signaling means.

10. The system of claim 9, wherein said polymer is selected from the group consisting of polyamides, polyamideimides, polyimides and polybenzimidazoles.

11. The system of claim 9, and including heating means connected to the base for heating the base to a temperature substantially above ambient temperature.

12. A method of sensing the presence of nitrogen dioxide in the environment, comprising the steps of exposing a film composed of a pyrolyzed polyaromatic polymer to a gaseous environment containing nitrogen dioxide gas, and measuring the change in electrical characteristics of said film caused by adsorption and/or absorption of said nitrogen dioxide gas.

13. The method of claim 12, wherein said polymer is selected from the group consisting of polyamides, polyamideimides, polyimides and polybenzimidazoles.