Process for putting a hydrophilic coating on a hydrophobic contact lens

• US 4,143,949 A
• Filed: 10/28/1976
• Issued: 03/13/1979
• Est. Priority Date: 10/28/1976
• Status: Expired due to Term

• Current Assignee: Bausch & Lomb Incorporated (Bausch Health Cos., Inc.)
• Original Assignee: Bausch & Lomb Incorporated (Bausch Health Cos., Inc.)
• Inventors: Chen, Richard Y.
• Primary Examiner(s): Corbin, John K.
• Assistant Examiner(s): Sugarman, Scott J.
• Application Number:
  US05/736,612
• Time in Patent Office: 866 Days
• Field of Search: 427/164, 427/41, 427/39, 351/160 H
• US Class Current: 351/160.00H
• CPC Class Codes: B05D 1/62 Plasma-deposition of organic layers plasma deposition in general C23C14/00, C23C16/00
• CPC Class Codes: G02B 1/043 Contact lenses

Abstract

The surface of a contact lens is modified by deposition of an ultrathin coating of a hydrophilic polymer under the influence of plasma glow discharge so as to integrally bond the coating to the surface of the hydrophobic lens thereby effecting a hydrophilic lens.

Claims

1. An electrodeless glow discharge polymerization and coating process for making a hydrophobic contact lens into a hydrophilic contact lens consisting essentially of:

(1) providing a hydrophobic, optically transparent, oxygen permeable contact lens,

(2) placing the hydrophobic contact lens into a glow discharge apparatus containing an atmosphere comprising a polymerizable organic monomer consisting essentially of hydroxyalkylmethacrylates, hydroxyalkylacrylates, glycidylmethacrylate, propylene oxide and N-vinyl-2-pyrrolidone; and

(3) subjecting the monomer to electromagnetic radiation sufficient to produce an electrodeless glow discharge at a pressure of about 100 to about 700 millitorr to cause the polymerizable organic monomer to polymerize and to form hydrohilic polymeric integrally bonded uniform coating from about 50A to about 20,000A thick on the hydrophobic contact lens thereby forming a hydrophilic, optically transparent, oxygen permeable contact lens.

2. The process of claim 1 wherein the electromagnetic energy has a frequency of about 15.6 megahertz.

3. The process of claim 1 wherein the atmosphere is at a pressure of from about 100 millitorr to about 500 millitorr.

4. The process of claim 1 wherein the hydrophobic contact lens is a polysiloxane polymeric material and the polymerized surface coating is selected from the group consisting of poly(2-hydroxyethylmethacrylate) and poly(N-vinyl-pyrrolidone).