Flame-retardant epoxy resin compositions

• US 4,145,369 A
• Filed: 09/19/1977
• Issued: 03/20/1979
• Est. Priority Date: 09/20/1976
• Status: Expired due to Term

• Current Assignee: Hitachi, Ltd.
• Original Assignee: Hitachi, Ltd.
• Inventors: Takemoto, Issei, Hira, Yasuo, Sudo, Ryoichi, Isogai, Tokio
• Primary Examiner(s): Lieberman, Paul
• Application Number:
  US05/834,457
• Time in Patent Office: 547 Days
• Field of Search: 260/831, 260/45.7 DE, 260/834, 260/829, 528/89
• US Class Current: 523/205
• CPC Class Codes: C08G 59/4215 cycloaliphatic
• CPC Class Codes: C08G 59/686 containing nitrogen
• CPC Class Codes: C08K 3/02 Elements
• CPC Class Codes: C08K 3/22 of metals
• CPC Class Codes: C08K 3/32 Phosphorus-containing compounds
• CPC Class Codes: C08K 5/54 Silicon-containing compounds C08K5/0091 takes precedence
• CPC Class Codes: C08L 63/00 Compositions of epoxy resins; Compositions of derivatives of epoxy resins

Abstract

Flame-retardant epoxy resin compositions comprising a polyepoxide, an acid anhydride curing agent, an imidazole curing accelerator, aluminum trihydrate powder and red phosphorus powder or red phosphorus powder coated by a thermo-setting resin have a lower viscosity and therefore show a longer pot life and better workability on casting as compared with prior art resin compositions. Also, a fly-back transformer coil produced by casting of said flame-retardant epoxy resin compositions is flame-retardant. Even if it burns slightly, no toxic gas is produced. Therefore, the coil has advantages in that a magnet wire is not corroded and voids are difficult to be formed and thereby partial discharge is difficult to occur, resulting in a long life and a stable output voltage.

Claims

1. A flame-retardant epoxy resin composition comprising 100 parts by weight of a polyepoxide containing more than one epoxy group in its molecule, 0.8 to 1.2 equivalents of an acid anhydride curing agent per equivalent of the polyepoxide, 0.5 to 5 parts by weight of an imidazole curing agent per 100 parts by weight of said polyepoxide, and amounts of aluminum trihydrate powder and at least one member selected from the group consisting of red phosphorus powder and red phosphorus powder coated by a thermo-setting resin within the range surrounded by connecting the points A, B, C, D, E, F, G, H and I as described below per 100 parts by weight of said polyepoxide, wherein the points A, B, C, D, E, F, G, H and I each represent the following compositions:

space="preserve" listing-type="tabular">______________________________________ Red phosphorus Aluminum powder or red trihydrate phosphorus powder powder coated by a thermo- (parts by setting resin weight) (parts by weight) ______________________________________ A 72 50 B 83 20 C 103 10 D 160 5 E 220 4 F 198 20 G 178 31 H 154 40 I 112 46 ______________________________________

2. A flame-retardant epoxy resin composition according to claim 1, wherein said polyepoxide containing more than one epoxy group in its molecule is at least one polyepoxide selected from the group consisting of diglycidyl ether of bisphenol A, diglycidyl ether of bisphenol F, polyglycidyl esters of polycarboxylic acids and epoxidized cyclohexene derivatives, said acid anhydride curing agent is at least one acid anhydride selected from the group consisting of methyltetrahydrophthalic anhydride, methylendomethylenetetrahydrophthalic anhydride and modified hexahydrophthalic anhydrides, said imidazole curing accelerator is at least one imidazole compound selected from the group consisting of 2-ethyl-4-methylimidazole, 2-phenylimidazole, 2-methylimidazole, 1-benzyl-2-methylimidazole and 1,2-dimethylimidazole, said aluminum trihydrate powder has an average particle size of 1 to 20μ

, and said red phosphorus powder or red phosphorus powder coated by a thermo-setting resin has an average particle size of 4 to 20μ

.

3. A flame-retardant epoxy resin composition according to claim 1, wherein said polyepoxide containing more than one epoxy group in its molecule is a mixture of diglycidyl ether of bisphenol A and diglycidyl tetrahydrophthalate, said acid anhydride curing agent is a mixture of methyltetrahydrophthalic anhydride and methylendomethylenetetrahydrophthalic anhydride, said imidazole curing accelerator is 2-ethyl-4-methylimidazole, said aluminum trihydrate powder has an average particle size of 8μ

, and said red phosphorus powder or red phosphorus powder coated by a thermo-setting resin has an average particle size of 6μ

.

4. A flame-retardant epoxy resin composition according to claim 1, wherein 0.3 to 2.5 parts by weight of a silane coupling agent is added to 100 parts by weight of a polyepoxide in the resin composition.

5. A flame-retardant epoxy resin composition according to claim 4, wherein said silane coupling agent is γ

-glycidoxypropyltrimethoxysilane.

6. A flame-retardant epoxy resin composition according to claim 2, wherein 0.3 to 2.5 parts by weight of γ

-glycidoxypropyltrimethoxysilane is added to 100 parts by weight of a polyepoxide in the resin composition.

7. A flame-retardant epoxy resin composition according to claim 3, wherein 0.3 to 2.5 parts by weight of γ

-glycidoxypropyltrimethoxysilane is added to 100 parts by weight of a polyepoxide in the resin composition.

15. A flame-retardant epoxy resin composition according to claim 1, wherein said at least one member is red phosphorus powder.

16. A flame-retardant epoxy resin composition according to claim 15, wherein said polyepoxide containing more than one epoxy group in its molecule is at least one polyepoxide selected from the group consisting of diglycidyl ether of bisphenol A, diglycidyl ether of bisphenol F, polyglycidyl esters of polycarboxylic acids and epoxidized cyclohexene derivatives, said acid anhydride curing agent is at least one acid anhydride selected from the group consisting of methyltetrahydrophthalic anhydride, methylendomethylene-tetrahydrophthalic anhydride and modified hexahydrophthalic anhydrides, said imidazole curing accelerator is at least one imidazole compound selected from the group consisting of 2-ethyl-4-methylimidazole, 2-phenylimidazole, 2-methylimidazole, 1-benzyl-2-methylimidazole and 1,2-dimethylimidazole, said aluminum trihydrate powder has an average particle size of 1 to 20μ

, and said red phosphorus powder has an average particle size of 4 to 20μ

.

17. A flame-retardant epoxy resin composition according to claim 15, wherein said polyepoxide containing more than one epoxy group in its molecule is a mixture of diglycidyl ether of bisphenol A and diglycidyl tetrahydrophthalate, said acid anhydride curing agent is a mixture of methyltetrahydrophthalic anhydride and methylendomethylenetetrahydrophthalic anhydride, said imidazole curing accelerator is 2-ethyl-4-methylimidazole, said aluminum trihydrate powder has an average particle size of 8μ

, and said red phosphorus powder has an average particle size of 6μ

.

18. A flame-retardant epoxy resin composition according to claim 15, wherein 0.3 to 2.5 parts by weight of a silane coupling agent is added to 100 parts by weight of a polyepoxide in the resin composition.

19. A flame-retardant epoxy resin composition according to claim 18, wherein said silane coupling agent is γ

-glycidoxypropyltrimethoxysilane.

20. A flame-retardant epoxy resin composition according to claim 16, wherein 0.3 to 2.5 parts by weight of γ

-glycidoxypropyltrimethoxysilane is added to 100 parts by weight of a polyepoxide in the resin composition.

21. A flame-retardant epoxy resin composition according to claim 17, wherein 0.3 to 2.5 parts by weight of γ

-glycidoxypropyltrimethoxysilane is added to 100 parts by weight of a polyepoxide in the resin composition.

8. A flame-retardant epoxy resin composition comprising 100 parts by weight of a polyepoxide containing more than one epoxy group in its molecule, 0.8 to 1.2 equivalents of an acid anhydride curing agent per equivalent of the polyepoxide, 0.5 to 5 parts by weight of an imidazole curing agent per 100 parts by weight of said polyepoxide, and amounts of aluminum trihydrate powder and red phosphorus powder coated by a thermo-setting resin within the range surrounded by connecting the points A, B, C, D, E, F, G, H and I as described blow per 100 parts by weight of said polyepoxide, wherein the points A, B, C, D, E, F, G, H and I each represent the following compositions:

space="preserve" listing-type="tabular">______________________________________ Aluminum Red phosphorus trihydrate powder coated powder by a thermo- (parts by setting resin weight) (parts by weight) ______________________________________ A 72 50 B 83 20 C 103 10 D 160 5 E 220 4 F 198 20 G 178 31 H 154 40 I 112 46 ______________________________________

9. A flame-retardant epoxy resin composition according to claim 8, wherein said polyepoxide containing more than one epoxy group in its molecule is at least one polyepoxide selected from the group consisting of diglycidyl ether of bisphenol A, diglycidyl ether of bisphenol F, polyglycidyl esters of polycarboxylic acids and epoxidized cyclohexene derivatives, said acid anhydride curing agent is at least one acid anhydride selected from the group consisting of methyltetrahydrophthalic anhydride, methylendomethylenetetrahydrophthalic anhydride and modified hexahydrophthalic anhydrides, said imidazole curing accelerator is at least one imidazole compound selected from the group consisting of 2-ethyl-4-methylimidazole, 2-phenylimidazole, 2-methylimidazole, 1-benzyl-2-methylimidazole and 1,2-dimethylimidazole, said aluminum trihydrate powder has an average particle size of 1 to 20μ

, and said red phosphorus powder coated by a thermo-setting resin has an average particle size of 4 to 20μ

.

10. A flame-retardant epoxy resin composition according to claim 8, wherein said polyepoxide containing not more than one epoxy group in its molecule is a mixture of diglycidyl ether of bisphenol A and diglycidyl tetrahydrophthalate, said acid anhydride curing agent is a mixture of methyltetrahydrophthalic anhyride and methylendomethylenetetrahydrophthalic anhydride, said imidazole curing accelerator is 2-ethyl-4-methylimidazole, said aluminum trihydrate powder has an average particle size of 8μ

, and said red phosphorus powder coated by a thermo-setting resin has an average particle size of 6μ

.

11. A flame-retardant epoxy resin composition according to claim 8, wherein 0.3 to 2.5 parts by weight of a silane coupling agent is added to 100 parts by weight of a polyepoxide in the resin composition.

12. A flame-retardant epoxy resin composition according to claim 11, wherein said silane coupling agent is γ

-glycidoxypropyltrimethoxysilane.

13. A flame-retardant epoxy resin composition according to claim 9, wherein 0.3 to 2.5 parts by weight of γ

-glycidoxypropyltrimethoxysilane is added to 100 parts by weight of a polyepoxide in the resin composition.

14. A flame-retardant epoxy resin composition according to claim 10, wherein 0.3 to 2.5 parts by weight of γ

-glycidoxypropyltrimethoxysilane is added to 100 parts by weight of a polyepoxide in the resin composition.

22. A flame-retardant epoxy resin composition according to claim 8, wherein the thermosetting resin is a phenol resin.