Matrix addressed electrochromic display

• US 4,146,876 A
• Filed: 06/29/1977
• Issued: 03/27/1979
• Est. Priority Date: 06/29/1977
• Status: Expired due to Term

• Current Assignee: International Business Machines Corporation
• Original Assignee: International Business Machines Corporation
• Inventors: Wilbur, Clayton V., Melz, Peter J., Arellano, Angel G.
• Primary Examiner(s): Trafton, David L.
• Application Number:
  US05/811,328
• Time in Patent Office: 636 Days
• Field of Search: 340/324 EC, 340/324 M, 340/336, 350/160 R, 350/333, 350/357, 58/50 R
• US Class Current: 345/105
• CPC Class Codes: C09K 9/02 Organic tenebrescent materials
• CPC Class Codes: G02F 1/1503 caused by oxidation-reduction reactions in organic liquid solutions, e.g. viologen solutions
• CPC Class Codes: G02F 1/163 Operation of electrochromic cells, e.g. electrodeposition cells; Circuit arrangements therefor
• CPC Class Codes: G09G 3/38 using electrochromic devices

Abstract

A matrix addressed electrochromic display includes first and second spaced apart opposed planar panels, a dielectric spacer peripherally sealing the panels to provide an interior cavity therebetween to define a display region, an electrochromic fluid filling the interior cavity, a plurality of parallel rows and columns of electrodes disposed in the mating surfaces of the first and second panels respectively and a low output impedance electrical refresh circuit coupled to electrically energize the electrodes in a repetitive matrix selection pattern to provide a selected dot matrix display.

Claims

1. An electrochromic display device comprising:

a panel including a pair of dielectric plates disposed in closely spaced parallel opposed relationship, each plate of the pair having a conductive pattern formed on a facing surface thereof to form a cross bar pattern of conductive electrodes within a selected surface area of the plates which includes a plurality of cross points, each cross point being selectable for imposition of a given voltage difference thereat by generation of a voltage on one electrode on each plate which passes through the cross point, the panel further including an electrochromic redox composition disposed within the space between the plates within the selected surface area without dielectric isolation between portions of the electrochromic redox composition at different cross points; and

drive circuitry coupled to electrically energize the conductive electrodes in a sequential pattern to periodically refresh a display appearing on the panel by periodically applying the given voltage difference at cross points selected to provide a desired display pattern, the given voltage difference being thereby substantially maintained at the cross points so long as they are to provide the desired display pattern.

2. The display device according to claim 1 above, wherein the input impedance of the drive circuitry is sufficiently low relative to the resistance through the electrochromic redox composition at the various cross points such that there is no substantial discharge from the electrochromic redox composition at a cross point to which the given voltage difference is applied into adjacent areas of the electrochromic redox composition.

3. The display device according to claim 1 above, wherein the space between the pair of plates is between 0.0005 inch and 0.005 inch.

4. The display device according to claim 3 above, wherein the space between the pair of plates is 0.0015 inch.

5. The display device according to claim 1 above, wherein the electrochromic redox composition has a threshold voltage conductance characteristic.

6. The display device according to claim 1 above, wherein the amplitude of the voltage on a first electrode passing through the cross point is at or below the threshold and the amplitude of the voltage on a second electrode passing through the cross point is at least twice the amplitude of the first voltage.

7. The display device according to claim 6 above, wherein the first electrode is a column electrode and the second electrode is a row electrode.

8. The display device according to claim 1 in which the electrochromic redox material comprises a first redox couple which reacts reversibly at an anode, a second redox couple which reacts reversibly at a cathode, a salt which is electrochemically inert and a solvent having the first and second redox couples and the salt dissolved therein.

9. The display device according to claim 1 above, wherein the solvent is a nonaqueous solvent.

10. The display device according to claim 1 above, wherein the resistivity of the electrochromic redox composition is between 5000 and 50 ohm-centimeters.

11. The display device according to claim 8 above, wherein one of the redox couples is a pyrazoline material.

12. The display device according to claim 8 above, wherein the electrochromic redox composition is methyl ethyl ketone solvent containing 0.09 mole 1-p-methoxyphenyl-3-p diethylamino styryl-5-diethylamino phenyl-Δ

² -pyrazoline, 0.2 mole phenyl-p-benzoquinone, and 0.4 mole tetrabutyl ammonium fluoroborate.

13. The display device according to claim 8 above, wherein the electrochromic redox composition is methyl ethyl ketone solvent containing 0.2 mole 1-p-methoxyphenyl-3-p-dipropylamino styrl-5-dipropylamino phenyl-Δ

² -pyrazoline, 0.4 mole phenyl-p-benzoquinone, and 0.8 mole tetrabutyl ammonium fluoroborate.

14. The display device according to claim 1, wherein the response time of the panel during which the color characteristic of the display at a selected cross point decays 50% after refresh is between 0.1 and 0.4 second.

15. The display device according to claim 1, wherein the electrochromic redox solution has a high rate of increase in coloration upon selection.

16. The display device according to claim 1 above, wherein drive circuitry is coupled to the electrodes as a low impedance source to control the voltage thereof at all times during operation of the display device.

17. An electrochromic display comprising:

an electrochromic liquid having a known threshold voltage and a known decay time, spaced apart row and column conductor sets addressably refreshing the electrochromic liquid by applying differing voltages to individual conductors in the spaced apart row and column conductor sets;

refresh means for pulse energizing selected conductors in the row and column conductor sets in cycles whose total period is less than the decay time of the liquid, the applied voltage exceeding and being maintained at a value exceeding the threshold of the liquid at intersections of the conductors at which the liquid is to be colored.

18. The display according to claim 17 above, wherein the refresh means maintains an equal time average voltage across all intersection of the conductors during a refresh period irrespective of the information being displayed.

19. A matrix character display device comprising:

a pair of insulative panels in parallel spaced apart relationship, one of said panels being transparent;

first and second sets of orthogonally disposed conductors, each set being on a different panel and the set on the transparent panel being at least substantially transparent, the sets of conductors defining the rows and columns of a matrix;

electrochromic means filling the space between said panels in the region of the matrix;

means coupled to address the conductor sets with signals establishing electrical potential differences between selected conductors in the rows and columns to color the electrochromic material in the intersectional volume at a chosen row and column conductor intersection, said address means further comprising means to repeatedly apply said electrical potentials in cyclic sequences having total periods less than the decay time of the electrochromic material, each cycle including in least one reversal of the signal polarity on at least one conductor, such that diffusion of the reduction process at the intersection is limited to the volume coextensive with both conductors.

20. A matrix character display device comprising:

a pair of insulative panels in parallel spaced apart relationship, one of said panels being transparent;

first and second sets of orthogonally disposed conductors, each set being on a different panel and the set on the transparent panel being at least substantially transparent, the sets of conductors defining the rows and columns of a matrix;

electrochromic means filling the space between said panels in the region of the matrix;

means coupled to address the conductor sets with signals establishing electrical potential differences between selected conductors in the rows and columns to color the electrochromic material in the intersectional volume at a chosen row and column conductor intersection, said address means further comprising means to repeatedly apply said electrical potentials in cyclic sequences having total periods less than the decay time of the electrochromic material, each cycle including at least one reversal of the signal polarity on at least one conductor, such that the time average voltage at a given cross point is independent of the state of coloration of the remaining cross points on the same column.

21. The display device according to claim 20 above, wherein the addressing means is always in a state of low output impedance.

22. The display device according to claim 21 above, wherein the spacing between the panels is much less than the width of the conductors of the first and second sets.

23. A variable reflectance cell display device comprising:

an electrochromic liquid that is energizable by a voltage, comprising;

a pair of planar non-conductive substrates spaced apart by a spacing in the range of 0.5 to 5 mils and at least one of said substrates being transparent, the electrochromic liquid being contained between the substrates;

a transparent conductor disposed on the inner face of the transparent substrate and having a width in the range of 5 to 50 mils;

a narrow high conductivity element disposed on the transparent conductor;

and a diffusely reflective conductor disposed on the inner face of the second substrate and having a width in the range of 5 to 50 mils.

24. An electrochromic display device comprising:

(a) a front and back plate, with the inner surfaces of said plates equipped with electrode segment strips such that the superposition of the strips on the front and back panels form a matrix of cross-points;

(b) a color-forming electrochromic redox composition contained between said plates and in contact with the electrodes, therein, said composition having high impedance parallel to the electrodes; and

(c) drive circuitry for applying and maintaining selected potential differences across the electrode strips in a matrix addressed manner to effect the coloration of selected cross-points, said circuitry maintaining sufficiently low output impedance at all times that the potentials of the electrode strips are controlled by the drive circuitry rather than by the redox state of the electrochromic composition present at the electrode cross-points.

25. An electrochromic display device comprising:

a first plate having a plurality of closely spaced row conductors formed on one surface thereof, the width of the row conductors defining a first dimension of dots in a dot display matrix;

a second plate having a plurality of closely spaced column conductors formed on one surface thereof, the one surface of the second plate being disposed in facing, parallel, closely spaced relationship to the one surface of the first plate with the column conductors of the second plate crossing the row conductors of the first plate with each crossover of a row conductor by a column conductor forming a dot in a dot display matrix, the width of the column conductors defining a second dimension of dots in the dot display matrix; and

an electrochromic material disposed between the row and column conductors in electrical communication therewith; and

a refresh driver connected to provide coincident selection refresh of selected individual dots in the dot matrix to maintain a desired voltage at the selected individual dots to display a desired information pattern, each refresh of a selected individual dot consisting of the application of different voltages to the row and column conductors the crossover of which forms the dot so as to provide a potential difference of desired polarity across the electrochromic material, the refresh driver having outputs that drive the row and column conductors with a low impedance at all times and which is substantially lower than the impedance through the electrochromic material at each of the dots.