Polycrystalline alumina material

• US 4,150,317 A
• Filed: 06/30/1978
• Issued: 04/17/1979
• Est. Priority Date: 03/11/1977
• Status: Expired due to Term

• Current Assignee: General Electric Company
• Original Assignee: General Electric Company
• Inventors: Laska, Harry M., Grimm, Nelson
• Primary Examiner(s): Vertiz, O. R.
• Assistant Examiner(s): Bell, Mark
• Application Number:
  US05/920,649
• Time in Patent Office: 291 Days
• Field of Search: 106/73.4, 423/628, 423/625, 313/220, 313/221
• US Class Current: 313/631
• CPC Class Codes: C04B 35/115 Translucent or transparent products
• CPC Class Codes: H01J 61/302 characterised by the material of the vessel

Abstract

Increased optical transmission is provided for a body of light transmissive polycrystalline alumina having relatively uniform size equiaxed grains of alumina and which is essentially free of porosity and secondary phase material. A tube of the improved optical material can be used as the light transmissive envelope for high intensity discharge lamps especially sodium and other metal vapor lamps exhibiting increased light output as a result of said improved optical transmission. A method of producing the improved optical material is also disclosed.

Claims

1. A sintered body of polycrystalline alumina consisting essentially of relatively uniform size equiaxed grains of alumina which contains no more than about 150 ppm magnesium and essentially no porosity and secondary phase, said body exhibiting improved optical transmission including especially improved in-line transmission, said polycrystalline alumina being further characterized by a substantial absence of grain-growth promoting impurities and a pore volume fraction no greater than about 10^-2.

2. A sintered body of polycrystalline alumina as in claim 1 having a total optical transmission over the entire visible wavelength range of at least 93 percent at approximately 0.75 mm sample thickness.

3. A sintered body of polycrystalline alumina as in claim 1 having the major exterior surfaces flux polished so as to reduce the high spots on the individual alumina grains without materially etching grain boundaries for greater in-line transmission improvement.

4. A sintered body of polycrystalline alumina as in claim 1 having an average grain size of approximately 26 microns diameter.

5. A sintered body of polycrystalline alumina as in claim 1 wherein substantially all grains have an average diameter in the range extending from about 20 microns diameter up to about 35 microns diameter.

6. A sintered body of polycrystalline alumina as in claim 3 wherein substantially all grains have an average diameter in the range extending from about 20 microns diameter up to about 35 microns diameter.

7. A sintered body of polycrystalline alumina as in claim 1 having a tubular form.

8. A sintered body of polycrystalline alumina as in claim 3 having a tubular form.

9. A sintered tube of polycrystalline alumina consisting essentially of equiaxed grains of alumina having an average grain size of approximately 26 microns diameter which contains no more than about 150 ppm magnesium and essentially no pores and secondary phase, and said tube exhibiting improved optical transmission characterized by especially improved in-line transmission and a total optical transmission over the entire visible wavelength range of at least 93 percent at approximately 0.75 mm sample thickness, said polycrystalline alumina being further characterized by a substantial absence of grain growth promoting impurities and a pore volume fraction no greater than about 10^-2.

10. A sintered tube of polycrystalline alumina as in claim 9 having the major exterior surfaces flux polished so as to reduce the high spots on the individual alumina grains without materially etching grain boundaries for greater in-line transmission improvement.

11. An improved high intensity electric discharge lamp comprising a light transmissive envelope having electrodes sealed into its ends and containing an ionizable medium for carrying the discharge, wherein the improvement comprises utilizing as the light transmissive envelope a tube of sintered polycrystalline alumina consisting essentially of relatively uniform size equiaxed grains of alumina which contains no more than about 150 ppm magnesium and essentially no secondary phase and pores, said tube exhibiting improved optical transmission characterized by especially improved in-line transmission, said polycrystalline alumina being further characterized by a substantial absence of grain-growth promoting impurities and a pore volume fraction no greater than about 10^-2.

12. An electric discharge lamp as in claim 11 further the major exterior surfaces of said sintered alumina tube flux polished so as to reduce the high spots on the individual alumina grains without materially etching grain boundaries for greater in-line transmission improvement.

13. An electric discharge lamp as in claim 11 wherein the electrodes are coated with electron emission material.

14. An electric discharge lamp as in claim 11 wherein the sintered alumina has an average grain size of approximately 26 microns diameter.