Polymer composition and method of using same to produce thermostable insulating materials

• US 4,151,158 A
• Filed: 01/17/1977
• Issued: 04/24/1979
• Est. Priority Date: 01/17/1977
• Status: Expired due to Term

• Current Assignee: Albert G. Kabirov, Alexandr K. Breger, Alexandr T. Sanzharovsky, Elena Z. Branzburg, Isaak Y. Poddubny, Jury N. Svatikov, Lidia A. Averyanova, Mark P. Grinblat, Nadezhda M. Stepanova, Rinat R. Safin, Sergei V. Averyanov, Valeria B. Shtukareva, Viktor S. Kondratovsky, Vladimir A. Goldin
• Original Assignee: Albert G. Kabirov, Alexandr K. Breger, Alexandr T. Sanzharovsky, Elena Z. Branzburg, Isaak Y. Poddubny, Jury N. Svatikov, Lidia A. Averyanova, Mark P. Grinblat, Nadezhda M. Stepanova, Rinat R. Safin, Sergei V. Averyanov, Valeria B. Shtukareva, Viktor S. Kondratovsky, Vladimir A. Goldin
• Inventors: Averyanov, Sergei V., Grinblat, Mark P., Kondratovsky, Viktor S., Goldin, Vladimir A., Svatikov, Jury N., Breger, Alexandr K., Kabirov, Albert G., Shtukareva, Valeria B., Stepanova, Nadezhda M., Branzburg, Elena Z., Poddubny, Isaak Y., Averyanova, Lidia A., Sanzharovsky, Alexandr T., Safin, Rinat R.
• Primary Examiner(s): Derrington, James H.
• Application Number:
  US05/760,027
• Time in Patent Office: 827 Days
• Field of Search: 260/42.26, 252/63.2
• US Class Current: 524/407
• CPC Class Codes: C08L 23/00 Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
• CPC Class Codes: C08L 2666/04 Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
• CPC Class Codes: C08L 2666/14 Macromolecular compounds according to C08L59/00 - C08L87/00; Derivatives thereof
• CPC Class Codes: C08L 57/00 Compositions of unspecified polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
• CPC Class Codes: C08L 83/04 Polysiloxanes
• CPC Class Codes: C08L 83/14 in which at least two but not all the silicon atoms are connected by linkages other than oxygen atoms C08L83/10 takes precedence

Abstract

According to the invention, the polymer composition comprises 8 to 20 parts by weight of polyborsiloxane having a molecular weight of 2,000 to 5,000 and including structural units [BOSi] [(CH₃)₂ SiO] with a B:Si molar ratio of 1:4 to 5, 40 to 90 parts by weight of polysiloxane rubber, 10 to 60 parts by weight of an organic polymer which may be polyolefins, copolymers of olefins and dienes, halogenated polyolefins, and halogenated copolymers of olefins and dienes, taken separately or in combination with one another, 2 to 10 parts by weight of branched polyorganosiloxane having a molecular weight of 2,000 to 5,000, of the general formula: ##STR1## WHEREIN: R=CH₃, C₆ H₅, a=43 to 50 mole %, b=0 to 2 mole %, c=50 to 55 mole %, as well as 10 to 25 parts by weight of silicon dioxide, and 5 to 10 parts by weight of a variable valency metal oxide.

The proposed method of producing thermostable insulating materials from said polymer composition comprises molding said polymer composition on a substrate so as to obtain a blank which is then exposed to ionizing radiation until the absorbed radiation dose reaches 6 to 35 megarads.

Thus, on the basis of the proposed polymer composition there are produced thermostable insulating materials which at room temperature have an adhesion to organic polymers of 3 to 6 kgf/cm² and to metals, 3 to 7 kgf/cm². Such materials are self-adhesive at room temperatures. They also possess satisfactory physico-mechanical and dielectric properties, as well as high thermal, cold and ozone resistance.

The proposed method of producing thermostable insulating materials is quite simple technologically.

Claims

1. A polymer composition comprising 8 to 20 parts by weight of polyborsiloxane having a molecular weight of 2,000 to 5,000 and containing structural units [BoSi] [(CH₃)₂ SiO] with a B:

Si molar ratio of 1;

4 to 5, 40 to 90 parts by weight of polysiloxane rubber, 10 to 60 parts by weight of an organic polymer selected from the group consisting of polyolefine, copolymers of olefins and dienes, halogenated polyolefins and halogenated copolymers of olefins and dienes, 2 to 10 parts by weight of branched polyorganosiloxane having a molecular weight of 2,000 to 5,000 of the general formula;

##STR6## wherein;

R is a radical selected from the group of radicals composed of CH₃, C₆ H₅ ;

a=43 to 50 mole %, b=0 to 2 mole %, c=50 to 55 mole %, 10 to 25 parts by weight of silicon dioxide, and 5 to 10 parts by weight of a variable valency metal oxide.

2. A polymer composition as claimed in claim 1, wherein the polyolefin is polyisobutylene taken in an amount of 20 to 60 parts by weight.

3. A polymer composition as claimed in claim 1, wherein the polyolefin is polyethylene taken in an amount of 10 to 15 parts by weight.

4. A polymer composition as claimed in claim 1, wherein the polyolefin is a copolymer of ethylene and propylene having a propylene content of 35 to 40 mole % and taken in an amount of 5 to 20 parts by weight.

5. A polymer composition as claimed in claim 1, wherein the copolymer of olefin and diene is a copolymer of isobutylene and isoprene containing 0.6 to 3 mole % of isoprene and taken in an amount of 20 to 60 parts by weight.

6. A polymer composition as claimed in claim 1, wherein the copolymer of olefin and diene is a copolymer of ethylene, propylene and ethylidene norbornane taken in an amount of 5 to 20 parts by weight and having a propylene content of 35 to 40 mole % and ethylidene norbornane content of 1 to 3 mole %.

7. A polymer composition as claimed in claim 1, wherein the halogenated polyolefin is bromated polyisobutylene taken in an amount of 20 to 60 parts by weight.

8. A polymer composition as claimed in claim 1, wherein the halogenated copolymer of olefin and diene is a bromated copolymer of isobutylene and isoprene taken in an amount of 20 to 60 parts by weight and having an isoprene content of 0.6 to 3 mole %.

9. A polymer composition as claimed in claim 1, which includes N-bromosuccinimide in an amount of 2 to 6 parts by weight.