Metallic glasses having a combination of high permeability, low magnetostriction, low ac core loss and high thermal stability

• US 4,152,144 A
• Filed: 12/29/1976
• Issued: 05/01/1979
• Est. Priority Date: 12/29/1976
• Status: Expired due to Term

• Current Assignee: Allied Chemical Corporation (Honeywell International Inc.)
• Original Assignee: Allied Chemical Corporation (Honeywell International Inc.)
• Inventors: Hasegawa, Ryusuke, Chou, Chong-Ping
• Primary Examiner(s): Steiner, Arthur J.
• Application Number:
  US05/755,386
• Time in Patent Office: 853 Days
• Field of Search: 75/122, 75/170, 75/134 F, 75/123 B, 75/123 D, 75/123 J, 75/123 M, 75/123 R
• US Class Current: 148/304
• CPC Class Codes: C22C 45/008 with Fe, Co or Ni as the major constituent C22C45/02, C22C45/04 take precedence
• CPC Class Codes: H01F 1/153 Amorphous metallic alloys, e.g. glassy metals making ferrous amorphous alloys C22C33/003

Abstract

Metallic glasses having high permeability, low magnetostriction, low ac core loss and high thermal stability are disclosed. In contrast to the prior art in which one, or at most two, of these properties are attained in one metallic glass, all those outstanding properties are achieved in a single metallic glass selected from one of the compositions of the invention. The metallic glasses consist essentially of about 63 to 83 atom percent of at least one metal selected from the group consisting of iron and cobalt, from 0 to about 60% of which metal may be replaced with nickel, about 2 to 12 atom percent of at least one element selected from the group consisting of molybdenum, tungsten, niobium and titanium, and about 15 to 25 atom percent of at least one metalloid element selected from the group consisting of boron, phosphorus and carbon plus incidental impurities.

Claims

1. A metallic glass that is substantially completely glassy having a combination of high permeability, low magnetostriction, low ac core loss and high thermal stability consisting of (a) about 53 to 83 atom percent iron and 0 to about 10 atom percent cobalt, the total of iron and cobalt in the metal alloy ranging from about 63 to 83 atom percent, up to about 60% of the total of which metal may be replaced with nickel, (b) about 2 to 12 atom percent of at least one element selected from the group consisting of molybdenum, tungsten, niobium and titanium and (c) about 15 to 25 atom percent of a metalloid selected from the group consisting of substantially boron only, substantially phosphorus only and carbon plus boron plus incidental impurities.

2. The metallic glass of claim 1 in which the metalloid content ranges from about 17 to 20 atom percent.

3. The metallic glass of claim 2 having the nominal composition Fe₈₁ Mo₂ B₁₇.

4. The metallic glass of claim 1 consisting of about 70 to 78 atom percent of at least one metal selected from the group of iron and iron plus cobalt, about 2 to 10 atom percent molybdenum and about 20 atom percent boron.

5. The metallic glass of claim 4 consisting of about 70 to 78 atom percent iron, about 2 to 10 atom percent molybdenum and about 20 atom percent boron.

6. The metallic glass of claim 5 consisting of about 74 to 78 atom percent iron, about 2 to 6 atom percent molybdenum and about 20 atom percent boron.

7. The metallic glass of claim 6 selected from the group of nominal compositions consisting of Fe₇₈ Mo₂ B₂₀ and Fe₇₆ Mo₄ B₂₀.

8. The metallic glass of claim 1 consisting of about 68 to 78 atom percent iron, up to about 60% of which is replaced with nickel, about 2 to 12 atom percent molybdenum and about 20 atom percent boron.

9. The metallic glass of claim 8 consisting of about 40 atom percent iron, about 28 to 38 atom percent nickel, about 2 to 12 atom percent molybdenum and about 20 atom percent boron.

10. The metallic glass of claim 9 consisting of about 40 atom percent iron, about 34 to 38 atom percent nickel, about 2 to 6 atom percent molybdenum and about 20 atom percent boron.

11. The metallic glass of claim 10 having the nominal composition Fe₄₀ Ni₃₆ Mo₄ B₂₀.

12. The metallic glass of claim 1 consisting of about 68 to 76 atom percent of at least one metal selected from the group consisting of iron and iron plus cobalt, about 4 to 12 atom percent molybdenum, about 16 atom percent carbon and about 2 atom percent boron.

13. The metallic glass of claim 12 having the nominal composition Fe₇₀ Co₆ Mo₄ C₁₈ B₂.

14. The metallic glass of claim 12 consisting of about 68 to 76 atom percent iron, about 4 to 12 atom percent molybdenum, about 18 atom percent carbon and about 2 atom percent boron.

15. The metallic glass of claim 14 consisting of about 72 to 76 atom percent iron, about 4 to 8 atom percent molybdenum, about 18 atom percent carbon and about 2 atom percent boron.

16. The metallic glass of claim 15 having the nominal composition Fe₇₂ Mo₈ C₁₈ B₂.

17. The metallic glass of claim 1 consisting of about 68 to 76 atom percent iron, up to about 60% of which is replaced with nickel, about 4 to 12 atom percent molybdenum, about 18 atom percent carbon and about 2 atom percent boron.

18. The metallic glass of claim 17 consisting of about 67 to 76 atom percent iron, 0 to about 9 atom percent nickel, about 4 atom percent molybdenum, about 18 atom percent carbon and about 2 atom percent boron.

19. The metallic glass of claim 18 having the nominal composition Fe₇₂ Ni₆ Mo₄ C₁₈ B₂.

20. The metallic glass of claim 1 consisting of about 75 to 78 atom percent iron, about 2 to 5 atom percent of at least one element selected from the group consisting of tungsten, niobium and titanium and about 20 atom percent boron.