Low energy ammonia synthesis process

• US 4,153,673 A
• Filed: 10/03/1977
• Issued: 05/08/1979
• Est. Priority Date: 10/04/1976
• Status: Expired due to Term

• Current Assignee: MW Kellogg Limited (KBR Incorporated)
• Original Assignee: Pullman Inc.
• Inventors: Becker, Colman L.
• Primary Examiner(s): Meros, Edward J.
• Application Number:
  US05/838,797
• Time in Patent Office: 582 Days
• Field of Search: 423/359-363, 23/260, 23/263, 23/288, 23/289, 23/281, 23/282
• US Class Current: 423/359
• CPC Class Codes: C01C 1/0405 from N2 and H2 in presence of a catalyst
• CPC Class Codes: C01C 1/0464 by absorption in liquids, e.g. water
• CPC Class Codes: Y02P 20/10 Process efficiency
• CPC Class Codes: Y02P 20/52 using catalysts, e.g. selective catalysts

Abstract

An improved synthesis loop for the production of ammonia has a low pressure, i.e. less than 100 atmospheres, a water absorption recovery system which utilizes low level heat recovered from the process for producing the synthesis gas to distill the ammonia-water mixture and an ammonia absorption refrigeration system which utilizes the same distillation column for both the water absorption system and the refrigeration system.

Claims

1. In an ammonia synthesis process wherein hydrogen and nitrogen are reacted at elevated pressure in an ammonia synthesis converter to produce ammonia, the improvement which comprises:

recovering the ammonia from the ammonia synthesis converter by water absorption which forms a water-ammonia mixture;

distilling said water-ammonia mixture in a distillation column to recover anhydrous ammonia;

flashing said ammonia by reducing the pressure of said ammonia recovered from said distillation column in stages whereby in each stage vapor is formed and the liquid ammonia cooled,

absorbing said vapor with water to form an aqua-ammonia mixture, and

distilling said aqua-ammonia mixture in the same distillation column as said water-ammonia mixture.

2. A process according to claim 1 wherein there are six flashing stages.

3. A process according to claim 1 wherein the synthesis pressure is from 20-70 atmospheres and the ammonia is recovered at substantially ambient pressure.

4. An ammonia synthesis loop wherein hydrogen and nitrogen are reacted at elevated pressure which comprises:

an ammonia synthesis converter wherein said hydrogen and nitrogen are reacted to form ammonia;

water absorption means for recovering the ammonia produced in said ammonia synthesis converter as a water-ammonia mixture;

distillation means for distilling said water-ammonia mixture to recover anhydrous ammonia;

flashing means for reducing the pressure of said ammonia recovered from said distillation means in stages whereby in each stage ammonia vapor is formed and the liquid ammonia cooled; and

means for recovering the ammonia vapor as a water-ammonia mixture and returning said mixture to said distillation means.

5. An ammonia synthesis loop according to claim 4 wherein there are six flashing stages.

6. In an ammonia synthesis process wherein hydrogen and nitrogen are reacted at elevated pressure in an ammonia synthesis converter to produce ammonia, the improvement which comprises:

recovering the ammonia from the ammonia synthesis converter by water absorption which forms a water-ammonia mixture;

distilling said water-ammonia mixture in a distillation column to recover anhydrous ammonia;

flashing said ammonia by reducing the pressure of said ammonia recovered from said distillation column in stages whereby in each stage vapor is formed and the liquid ammonia cooled;

absorbing said vapor from the last flashing stage with water to form an aqua-ammonia mixture, and

absorbing said vapor from each preceding flashing stage with water said water being provided by the aqua-ammonia mixture formed in the subsequent absorption stage.

7. A process according to claim 6 wherein there are six absorption stages.