Nonionic shampoo

• US 4,154,706 A
• Filed: 07/07/1977
• Issued: 05/15/1979
• Est. Priority Date: 07/23/1976
• Status: Expired due to Term

• Current Assignee: Colgate-Palmolive Company
• Original Assignee: Colgate-Palmolive Company
• Inventors: Robbins, Clarence R., Kenkare, Divaker B.
• Primary Examiner(s): Weinblatt, Mayer
• Application Number:
  US05/813,569
• Time in Patent Office: 677 Days
• Field of Search: 252/89, 252/95, 252/102, 252/544, 252/547, 252/DIG. 1, 252/DIG. 2, 252/DIG. 13, 252/DIG. 14, 424/70
• US Class Current: 510/123
• CPC Class Codes: A61K 8/39 Derivatives containing from 2 to 10 oxyalkylene groups
• CPC Class Codes: A61K 8/40 containing nitrogen quinones containing nitrogen A61K8/355
• CPC Class Codes: A61K 8/42 Amides
• CPC Class Codes: A61K 8/8158 Homopolymers or copolymers of amides or imides, e.g. (meth) acrylamide; Compositions of derivatives of such polymers
• CPC Class Codes: A61K 8/86 Polyethers
• CPC Class Codes: A61Q 5/02 Preparations for cleaning the hair
• CPC Class Codes: C11D 1/66 Non-ionic compounds C11D1/002, C11D1/004, C11D1/008 take precedence
• CPC Class Codes: C11D 1/662 Carbohydrates or derivatives
• CPC Class Codes: C11D 1/74 Carboxylates or sulfonates esters of polyoxyalkylene glycols
• CPC Class Codes: C11D 1/75 Amino oxides

Abstract

An all nonionic liquid shampoo which includes an amine oxide, a polyoxyethylene hexitan mono-higher fatty acid ester, and at least one of a higher alkoxy polyoxyethylene ethanol, an alkyl glycoside and a mixture of glycoside, a higher fatty acid lower alkanolamide and polyacrylamide. Optionally, the mixture of higher fatty acid lower alkanolamide and polyacrylamide may be present in the liquid shampoo containing amine oxide, polyoxyethylene hexitan mono-higher fatty acid ester and the higher alkoxy polyoxyethylene ethanol and/or alkyl glycoside. Another optional constituent is a polyethylene glycol higher fatty acid ester. The shampoos are essentially free of ions and are desirably completely free of ionic materials with the pH essentially neutral.

Claims

1. A nonionic shampoo suitable for leaving washed hair in a manageable state consisting essentially of, by weight 3 to 30% of an amine oxide having two short chain and one long chain substituents on the nitrogen thereof wherein the short chain substituents are selected from the group consisting of lower alkyls and lower hydroxyalkyls of 1 to 4 carbon atoms and the long chain substituent is selected from the group consisting of higher alkyls and higher acylamido lower alkyls in which the higher alkyls are of 10 to 20 carbon atoms and the lower alkyls are of 1 to 4 carbon atoms;

2 to 30% of a polyoxyethylene hexitan mono-higher fatty acid ester having from 10 to 20 carbon atoms in the higher fatty acyl thereof and from 10 to 100 moles of ethylene oxide per moles;

a nonionic detergent selected from the group consisting of 6 to 30% of higher alkoxy polyoxyethylene ethanols wherein the higher alkoxy is of 10 to 20 carbon atoms and the ethylene oxide content including the CH₂ CH₂ O--of the ethanol, is from 6 to 20 mols per moles, 6 to 30% of C₁₀ -C₂₀ alkyl glycosides, 6 to 30% of mixtures of said polyoxyethylene ethanols and said alkyl glycosides, and a mixture of 1 to 6% of a C₁₀ -C₂₀ acyl C₂ -C₃ mono- or di- alkanolamide and 0.05% to 1% of a polyacrylamide having a weight average molecular weight in the range of 100,000 to 3,000,000; and

25 to 89% water;

said shampoo being essentially free of ions and having a conductivity below 2,000 microhmos/cm., having a pH in the range of 5 to 10 and exhibiting good foaming power in the presence of sebum soil at use concentration.

2. A nonionic shampoo according to claim 1 which contains, in addition, 0.01% to 0.05% by weight of formaldehyde and 0.01% to 0.05% by weight of benzophenone.

3. A nonionic shampoo according to claim 1 wherein said pH is in the range of 6.5 to 7.5, said amine oxide is present in an amount of 4% to 15% by weight, said hexitan fatty acid ester is present in an amount of 10% to 30% by weight, and said nonionic detergent is a mixture of said fatty acid alkanolamide and said polyacrylamide.

4. A nonionic shampoo according to claim 3 wherein said pH is in the range of 6.8 to 7.3, said amine oxide is present in an amount of 5% to 10% by weight, said hexitan fatty acid ester is present in an amount of 15% to 25% by weight, said fatty acid alkanolamide is present in an amount of 1.5% to 4% by weight, said polyacrylamide is present in an amount of 0.1% to 0.5% by weight and deionized water is present in an amount of 60% to 75% by weight.

5. A nonionic shampoo according to claim 4 wherein said amine oxide has lower alkyls of 1 to 2 carbon atoms and a higher alkyl of 12 to 18 carbon atoms, said hexitan fatty acid ester is a polyoxyethylene sorbitan fatty acid ester having 12 to 18 carbon atoms in the fatty acyl and containing about 15 to 25 mols of ethylene oxide and said fatty acid alkanolamide is a monoalkanolamide.

6. A nonionic shampoo according to claim 5 which contains, in addition, 0.5% to 5% by weight of a polyethylene glycol higher fatty acid diester of an average molecular weight in the range of 2,000 to 8,000 and wherein the fatty acid moieties are each of 12 to 20 carbon atoms.

7. A nonionic shampoo according to claim 6 wherein said amine oxide is myristyl dimethyl amine oxide, said hexitan fatty acid ester is a polyoxyethylene sorbitan monolaurate, said fatty acid alkanolamide is a monoethanolamide and said diester is a polyethylene glycol distearate and is present in an amount of 1% to 4% by weight.

8. A nonionic shampoo according to claim 1 wherein said pH is in the range of about 6.5 to 7.5, said amine oxide is present in an amount of 5% to 10% by weight, said polyoxyethylene hexitan fatty acid ester is present in an amount of 5% to 10% by weight and said nonionic detergent is present in an amount of 15% to 20% by weight and is selected from the group consisting of said polyoxyethylene ethanols, said alkyl glycosides and mixtures thereof.

9. A nonionic shampoo according to claim 8 wherein said pH is in the range of 6.8 to 7.3, said amine oxide is myristyl dimethyl amine oxide, said hexitan fatty acid ester is a polyoxyethylene sorbitan monolaurate containing 20 moles of ethylene oxide, said nonionic detergent is tridecyl polyoxyethylene ethanol containing 10 moles of ethylene oxide and water is present in an amount of 60% to 75% by weight.

10. A nonionic shampoo according to claim 9 which contains, in addition, about 1.5% to 4% by weight of C₁₀ -C₂₀ acyl monoethanolamide and 0.1% to 0.5% by weight of polyacrylamide having an average molecular weight in the range of 100,000 to 3,000,000.

11. A nonionic shampoo according to claim 8 wherein said pH is in the range of 6.8 to 7.3, said amine oxide is myristyl dimethyl amine oxide, said hexitan fatty acid ester is a polyoxyethylene monolaurate containing 20 moles of ethylene oxide, said nonionic detergent is a higher alkyl glycoside having 10 to 14 carbon atoms in the alkyl group and deionized water is present in an amount of 60% to 75% by weight.

12. A nonionic shampoo according to claim 11 which contains, in addition, about 1.5% to 4% by weight of C₁₀ -C₂₀ acyl monoethanolamide and 0.1% to 0.5% by weight of polyacrylamide having an average molecular weight in the range of 100,000 to 3,000,000.