Method for enhancing membrane separation

• US 4,157,960 A
• Filed: 11/30/1977
• Issued: 06/12/1979
• Est. Priority Date: 11/30/1977
• Status: Expired due to Term

• Current Assignee: Permea Incorporated (Linde Plc)
• Original Assignee: Monsanto Company (Bayer AG)
• Inventors: Ward, Robert R., Chang, Richard C.
• Primary Examiner(s): Lander, Ferris H.
• Application Number:
  US05/855,852
• Time in Patent Office: 559 Days
• Field of Search: 264/41, 210/22, 210/23 R, 210/23 F, 210/321, 210/500 M, 210/2, 210/7, 210/12, 210/15, 210/17, 55/16, 55/158
• US Class Current: 210/644
• CPC Class Codes: B01D 67/0016 Coagulation
• CPC Class Codes: B01D 67/0097 Storing or preservation
• CPC Class Codes: B01D 69/02 characterised by their properties
• CPC Class Codes: B01D 71/68 Polysulfones; Polyethersulfones

Abstract

The selectivities of fluid separations of membranes having pores, in which the material of the membranes significantly effects the fluid separations, can be enhanced by the storage of the membranes in water. Suitable materials of the membranes for improvement in accordance with this invention are those which are not unduly susceptible to biodegradation. The membranes for improvement in accordance with this invention preferably have structures which are not unduly affected by drying and thus maintain beneficial mechanical and fluid separation properties after drying.

Claims

1. A method for enhancing the selectivity for fluid separation of a membrane in which the material of the membrane significantly effects the fluid separation, said membrane having a barrier layer with pores therethrough which adversely affect the selectivity of fluid separation and said membrane being resistant to biodegradation, comprising storing the membrane in an aqueous medium having an essential absence of a bacteriostat for a time sufficient to provide growths of microorganisms and thus enhance the selectivity of fluid separation of the membrane.

2. The method of claim 1 wherein the aqueous medium is at a temperature of about 10°

to 40°

C. and the membrane is stored for at least about one day.

3. The method of claim 2 wherein the aqueous medium has been used for storing membranes.

4. The method of claim 2 wherein the aqueous medium is aerated.

5. The method of claim 2 wherein the growth of microorganisms on the membrane is arrested after the storage of the membrane.

6. The method of claim 2 wherein the membrane is dried after the storage.

7. The method of claim 2 wherein the aqueous medium is inoculated with microorganisms suitable for enhancing the selectivity of separation of the membrane.

8. The method of claim 7 wherein the aqueous medium has been used for storing membranes.

9. The method of claim 7 wherein the aqueous medium is aerated.

10. The method of claim 7 wherein the growth of microorganisms on the membrane is arrested after the storage of the membrane.

11. The method of claim 7 wherein the membrane is dried after the storage.

12. The method of claim 2 wherein the membrane is anisotropic and the barrier layer of the anisotropic membrane is thin.

13. The method of claim 12 wherein the membrane is an anisotropic membrane which is formed by coagulation from a solvent solution.

14. The method of claim 13 wherein the anisotropic membrane comprises polysulfone.

15. The method of claim 14 wherein the polysulfone has the repeating structural unit ##STR9## wherein R and R'"'"' can be the same or different and are aliphatic or aromatic hydrocarbyl-containing moieties of 1 to about 40 carbon atoms, and the polysulfone has an average molecular weight of at least about 10,000.

16. The method of claim 15 wherein the solvent for the polymer solution for coagulation comprises at least one of dimethylformamide, dimethylacetamide, dimethylpropionamide, and N-methylpyrrolidone.

17. The method of claim 16 wherein the membrane exhibits selectivities of fluid separation characteristic of fluid separation by Knudsen diffusion or by a combination of Knudsen diffusion and separation by interaction with the material of the membrane.

18. The method of claim 16 wherein the aqueous medium is inoculated with microorganisms suitable for enhancing the selectivity of separation of the membrane.

19. The method of claim 18 wherein the aqueous medium has been used for storing membranes.

20. The method of claim 18 wherein the aqueous medium is aerated.

21. The method of claim 18 wherein the growth of microorganisms on the membrane is arrested after the storage of the membrane.

22. The method of claim 18 wherein the membrane is dried after the storage.

23. The method of claim 12 wherein the membrane comprises polysulfone.

24. The method of claim 12 wherein the ratio of total surface area of the membrane to total pore cross-sectional area through the barrier layer is at least about 10³ :

1 and the average pore cross-sectional diameter is less than about 1000 angstroms.

25. The method of claim 24 wherein the membrane exhibits selectivities of fluid separation characteristic of fluid separation by Knudsen diffusion or by a combination of Knudsen diffusion and separation by interaction with the material of the membrane.