Process and apparatus to produce synthetic crude oil from tar sands

• US 4,160,720 A
• Filed: 12/15/1977
• Issued: 07/10/1979
• Est. Priority Date: 12/15/1977
• Status: Expired due to Term

• Current Assignee: University of Utah Research Foundation (State of Utah)
• Original Assignee: University of Utah (State of Utah)
• Inventors: Seader, Junior D., Jayakar, Kirshnakumar M.
• Primary Examiner(s): Gantz, Delbert E.
• Assistant Examiner(s): Wright, William G.
• Application Number:
  US05/851,226
• Time in Patent Office: 572 Days
• Field of Search: 208/11 R, 201/31, 202/120
• US Class Current: 208/409
• CPC Class Codes: C10G 1/02 by distillation

Abstract

A process and apparatus for producing synthetic crude oil from bitumen-bearing sands. The apparatus includes a vessel segregated into a pyrolysis zone and a combustion zone, each zone being in the form of a fluidized bed reactor. At least one heat pipe is provided for transferring thermal energy from the combustion zone to the pyrolysis zone where the thermal energy is used to pyrolyze the bitumen. The apparatus may also include additional heat exchange equipment for heating the incoming combustion air for the combustion zone. The combustion air serves as the fluidizing medium for the fluidized bed reactor of the combustion zone while flue gases from the combustion zone serve as the fluidizing medium for the fluidized bed reactor of the pyrolysis zone.

Claims

1. An apparatus for processing bitumen-bearing tar sands for the recovery of bitumen therefrom comprising:

means for maintaining a first fluidized bed for the bitumen-bearing tar sands, the first fluidized bed serving as a pyrolysis zone for bitumen of the bitumen-bearing tar sands, the pyrolysis zone cracking a substantial portion of the bitumen and thereby volatilizing the same while leaving a carbon residue in the form of coke on the tar sands;

means for introducing a comminuted, bitumen-bearing tar sand into the first fluidized bed;

means for introducing coked tar sands from the first fluidized bed into a second fluidized bed;

means for maintaining the second fluidized bed for the coked tar sands from the first fluidized bed, the second fluidized bed serving as a combustion zone for the coke on the coked tar sands to thereby develop thermal energy in the second fluidized bed; and

heat transfer means comprising heat pipe means for conducting the thermal energy from the second fluidized bed to the first fluidized bed.

2. The apparatus defined in claim 1 wherein the first fluidized bed and the second fluidized bed are contained within a single, vertically-oriented vessel to accommodate gravity-assisted movement of solids through the vessel.

3. The apparatus defined in claim 2 wherein the second fluidized bed is below the first fluidized bed, the apparatus further comprising valve means below the first fluidized bed to thereby accommodate controlling the rate at which coked tar sand is introduced into the second fluidized bed from the first fluidized bed.

4. The apparatus defined in claim 1 wherein the fluidized beds are maintained in the fluidized state by combustion air in the second fluidized bed, the combustion air supporting combustion of the carbon on the coked tar sands, the combustion products from said combustion process maintaining the fluidized state of the first fluidized bed.

5. The apparatus defined in claim 4 wherein means are provided for heating the incoming air into the second combustion zone, said means providing heat exchange between sand from the second fluidized bed and the incoming air, thereby heating the incoming air.

6. An apparatus for processing bitumen-bearing tar sands comprising:

a vessel;

a first distributor plate in the vessel, the distributor plate defining a pyrolysis zone for bitumen-bearing tar sand;

means for introducing comminuted tar sand into the pyrolysis zone;

a second distributor plate in the vessel, the distributor plate defining a combustion zone for coked tar sand obtained from the pyrolysis zone;

delivery means for delivering coked tar sand from the pyrolysis zone to the combustion zone;

air inlet means for introducing air into the combustion zone, the air supporting combustion of coke on the coked tar sands to produce thermal energy;

heat transfer means comprising heat pipe means, a first end of the heat pipe means being embedded in the combustion zone and a second end of the heat pipe means being embedded in the pyrolysis zone for conducting thermal energy from the combustion zone to the pyrolysis zone in the vessel; and

removal means for removing burnt sand from the combustion zone.

7. The apparatus claimed in claim 6 wherein the vessel includes a diametrally enlarged area above each of the pyrolysis zone and the combustion zone, the diametrally enlarged area serving as an expansion means for lowering upward gaseous velocity in the vessel thereby reducing the quantity of solids entrained in the upwardly-flowing gaseous stream.

8. The apparatus defined in claim 6 wherein the vessel further includes heat exchange means for heating incoming combustion air by absorbing heat from burnt sand from the combustion zone.

9. The apparatus defined in claim 6 wherein the vessel is vertically oriented with the pyrolysis zone above the combustion zone to thereby accommodate gravity-assisted delivery of coked tar sand from the pyrolysis zone to the combustion zone.

10. An apparatus for processing tar sands comprising:

a vertically oriented vessel;

a pyrolysis zone in the vessel adjacent the upper end of the vessel;

a combustion zone in the vessel below and spaced from the pyrolysis zone;

inlet means for introducing comminuted tar sands into the pyrolysis zone, the tar sand being pyrolyzed to release bitumen from the tar sands while forming coked sand by leaving a coke residue on the sand;

delivery means for depositing the coked sand from the pyrolysis zone into the combustion zone to accommodate the coke being burned therein to form thermal energy;

heat transfer means between the combustion zone and the pyrolysis zone to transfer that portion of the thermal energy not contained in gases leaving the combustion zone to the pyrolysis zone said heat transfer means comprising a heat pipe means, a first end of the heat pipe means in thermal contact with the combustion zone and a second end of the heat pipe means in thermal contact with the pyrolysis zone; and

settling zones above each of the pyrolysis zone and the combustion zone, each settling zone comprising a diametral enlargement of the vessel, the diametral enlargement reducing the velocity of upwardly flowing gases thereby allowing suspended particulate materials to settle from the gases.

11. The apparatus defined in claim 10 wherein the vessel further includes air delivery means for introducing air into the vessel below the combustion zone, the air supplying oxygen for combustion of the coke while accommodating formation of a fluidized bed in the combustion zone, the combustion process producing burnt sand and flue gases.

12. The apparatus defined in claim 11 wherein the air delivery means further comprises heat exchange means for transferring heat from the burnt sand from the combustion zone to the incoming air.

13. The apparatus defined in claim 11 wherein the apparatus further comprises distributor means for distributing flue gases from the combustion zone to the pyrolysis zone, the flue gases accommodating the formation of a fluidized bed in the pyrolysis zone.

14. The apparatus defined in claim 10 wherein the delivery means comprises outlet means below the pyrolysis zone, the outlet means accommodating gravity-assisted delivery of coked sand from the pyrolysis zone to the combustion zone.

15. The apparatus defined in claim 14 wherein the outlet means comprises an elongated pipe having a valve means on lower end of the pipe, the length of the pipe being filled with coked sand thereby inhibiting flue gases from the combustion zone from entering the pyrolysis zone through the outlet means.

16. A process for recovering bitumen products from bitumen-bearing tar sands comprising:

introducing a comminuted tar sand into a first fluidized bed reactor, the first fluidized bed reactor pyrolyzing the bitumen to volatilize the same while leaving a coked sand comprising coke residue on the sand particles from the tar sand;

directing the coked sand from the first fluidized bed reactor into a second fluidized bed reactor, the second fluidized bed reactor combusting the coke to produce thermal energy and a flue gas along with a burnt sand comprising sand particles which are substantially free of coke residue, the flue gas being particularly characterized by the substantial lack of oxygen therein;

fluidizing the second fluidized bed reactor with combustion air having oxygen therein, the oxygen supporting combustion of the coke in the second fluidized bed reactor;

fluidizing the first fluidized bed reactor with said flue gases from the second fluidized bed reactor; and

transferring said thermal energy, other than that portion of the energy that is contained in the flue gases, from the second fluidized bed reactor to the first fluidized bed reactor by embedding a first end of a heat pipe means in the second fluidized bed reactor and a second end of a heat pipe means in the first fluidized bed reactor, the heat pipe means transferring a substantial portion of said thermal energy from the second fluidized bed reactor to the first fluidized bed reactor, said thermal energy pyrolyzing said bitumen.

17. The process defined in claim 16 wherein said directing step further comprises placing the first fluidized bed reactor above the second fluidized bed reactor, the physical orientation of the first fluidized bed reactor accommodating feeding coked sand by gravity from the first fluidized bed reactor to the second fluidized bed reactor.

18. The process defined in claim 17 wherein the placing step further comprises inhibiting fines carryover from each of the first and second fluidized bed reactors by segregating a vessel into said first and said second fluidized bed reactors and forming diametrally enlarged sections in the vessel above each of said first and said second fluidized bed reactors, said diametrally enlarged sections lowering upward gaseous velocity thereby allowing fines to settle from upwardly flowing gases.

19. A single-pass process for producing synthetic cruce oil from tar sand comprising:

vertically orienting an enclosed vessel;

segregating the vessel into an upper, pyrolysis zone and a lower, combustion zone;

introducing a comminuted tar sand into the pyrolysis zone thereby producing vapors of synthetic crude oil and a coked sand comprising a coke residue on particles of sand from the tar sand;

feeding coked sand downwardly under the force of gravity from the pyrolysis zone to the combustion zone;

generating thermal energy in the combustion zone by burning the coke residue on the coked sand while producing flue gases and burnt sand;

removing burnt sand downwardly from the combustion zone under the force of gravity;

injecting combustion air into the vessel below the combustion zone, the combustion air absorbing thermal energy from the burnt sand and fluidizing at least a portion of the coked sand in the combustion zone while supporting combustion of the coke residue, the combustion air becoming flue gases in combination with gaseous combustion products from the combustion zone;

fluidizing at least a portion of the comminuted tar sand in the pyrolysis zone with the flue gases from the combustion zone, the flue gases commingling with and carrying away the vapors of synthetic crude oil from the pyrolysis zone;

removing the commingled flue gases and vapors of synthetic crude oil from the upper end of the vessel;

withdrawing the burnt sand from the lower end of the vessel; and

transferring a substantial portion of the thermal energy not contained in the flue gases but generated in the combustion zone from the combustion zone to the pyrolysis zone by embedding a first end of a heat pipe means in the combustion zone and a second end of the heat pipe means in the pyrolysis zone, the thermal energy pyrolyzing the tar sand thereby producing vapors of synthetic crude oil.