Pressure responsive fractionation control

• US 4,164,452 A
• Filed: 06/05/1978
• Issued: 08/14/1979
• Est. Priority Date: 06/05/1978
• Status: Expired due to Term

• Current Assignee: Applied Automation, Inc. (Applied Industrial Technologies Incorporated)
• Original Assignee: Phillips Petroleum Company (ConocoPhillips)
• Inventors: Funk, Gary L., Smith, Dexter E.
• Primary Examiner(s): Serwin, R. E.
• Application Number:
  US05/912,701
• Time in Patent Office: 435 Days
• Field of Search: 23/230 A, 422/62, 422/105, 422/108, 422/112, 203/1, 203/2, 364/501
• US Class Current: 203/2
• CPC Class Codes: F25J 2200/02 in a single pressure main column system
• CPC Class Codes: F25J 2200/70 Refluxing the column with a condensed part of the feed stream, i.e. fractionator top is stripped or self-rectified
• CPC Class Codes: F25J 2205/04 in the feed line, i.e. upstream of the fractionation step
• CPC Class Codes: F25J 2280/50 Advanced process control, e.g. adaptive or multivariable control
• CPC Class Codes: F25J 3/0209 Natural gas or substitute natural gas
• CPC Class Codes: F25J 3/0233 separation of CnHm with 1 carbon atom or more
• CPC Class Codes: F25J 3/0238 separation of CnHm with 2 carbon atoms or more
• CPC Class Codes: F25J 3/0295 Start-up or control of the process; Details of the apparatus used, e.g. sieve plates, packings
• CPC Class Codes: Y10T 436/12 Condition responsive control

Abstract

In a fractionation system in which pressure fluctuations within the fractionation vessel can result in alteration of the fractionator product composition, fractionation column pressure is monitored and converted to a temperature requirement signal representative of the temperature required within a preselected portion of the fractionation column in order to provide the desired product constituent distribution. The temperature requirement signal is utilized to provide a required heat signal which is representative of the direction and magnitude of any change necessary in the heat input to the fractionation column to maintain the required temperature. The required heat signal is utilized to provide fast changes in the heat input to the fractionation column in response to pressure fluctuations in the fractionation column. The required heat signal is biased or trimmed by a comparison of the temperature requirement signal, corrected as necessary by actual analysis of the product, with the actual temperature in the fractionation column.

Claims

1. Apparatus comprising:

fractionation column means for receiving at least one feed material stream and delivering an overhead product stream from the top portion thereof and a bottom product stream from the bottom portion thereof;

heating means for providing heat to said bottom portion of said fractionation column means;

pressure transducer means for sensing the pressure at a preselected location within said fractionation column means and delivering a column pressure signal representative of the thus sensed pressure;

a first signal conversion means for accepting said column pressure signal and delivering in response thereto a temperature requirement signal representative of the value of a column bottom temperature for said fractionation column means required to provide a preselected value of a constituent ratio in said bottom product stream at the column pressure represented by said column pressure signal;

a second signal conversion means for accepting said temperature requirement signal and delivering in response thereto a required heat signal representative of the direction and magnitude of the change in heat input to said fractionation column means required to provide the column bottom temperature required to provide said preselected value of said constituent ratio in said bottom product stream at the column pressure represented by said column pressure signal;

temperature transducer means for sensing a column bottom temperature within said fractionation column means adjacent the bottom thereof and delivering a bottom temperature signal representative of the thus sensed temperature;

temperature controller means for delivering a required heat correction signal in response to a comparison of said bottom temperature signal with a bottom temperature set point signal;

analyzer means for analyzing said bottom product stream and delivering an analysis signal representative of the analyzed value of said constituent ratio within said bottom product stream;

analysis controller means for delivering, in response to comparison of said analysis signal with a constituent ratio set point signal, a temperature requirement adjustment signal representative of the adjustment of said temperature requirement signal necessary to compensate for the difference between said preselected value of said constituent ratio and the analyzed value of said constituent ratio;

a first correction means for applying said temperature requirement adjustment signal to said temperature requirement signal to produce said bottom temperature set point signal;

a second correction means for applying said required heat correction signal to said required heat signal to produce a corrected required heat signal; and

means for controlling the amount of heat flow delivered to said bottom portion of said fractionation column means by said heating means in response to said corrected required heat signal.

2. Apparatus in accordance with claim 1 wherein said first signal conversion means comprises means for simulating the relationship between said column pressure signal and said temperature requirement signal for said preselected value of said constituent ratio in said bottom product stream.

3. Apparatus in accordance with claim 2 wherein said second signal conversion means comprises means for simulating the relationship between said temperature requirement signal and said heat requirement signal for said preselected value of said constituent ratio in said bottom product stream.

4. Apparatus in accordance with claim 3 wherein said first signal conversion means and said second signal conversion means comprise diode function generators.

5. Apparatus in accordance with claim 2 wherein said first signal conversion means is adapted to provide a temperature requirement signal which fulfills the general condition:

space="preserve" listing-type="equation">T.sub.R =A+BP.sub.c

where T_R is said temperature requirement signal, P_c is said column pressure signal, and A and B are constants.

6. Apparatus in accordance with claim 3 wherein said second signal conversion means is adapted to provide a required heat signal which fulfills the general condition:

space="preserve" listing-type="equation">H.sub.R =C+DT.sub.R

where H_R is said required heat signal, T_R is said temperature requirement signal, and C and D are constants.

7. Apparatus in accordance with claim 1 wherein said first correction means comprises means for adding said temperature requirement adjustment signal to said temperature requirement signal to produce said bottom temperature set point signal.

8. Apparatus in accordance with claim 1 wherein said second correction means comprises means for adding said required heat signal and said required heat correction signal to produce said corrected required heat signal.

9. Apparatus in accordance with claim 1 wherein said fractionation column means comprises a demethanizer column of a cryogenic natural gas separation plant.

10. Apparatus in accordance with claim 9 wherein said constituent ratio in said bottom product stream comprises the methane to ethane ratio of said bottom product stream, wherein said constituent ratio set point signal comprises a signal representative of a desired methane to ethane ratio, and wherein said analyzer means is adapted to deliver an analysis signal representative of the actual methane to ethane ratio of said bottom product stream.

11. Apparatus in accordance with claim 10 wherein said first signal conversion means comprises means for simulating the relationship between said column pressure signal and said temperature requirement signal for said preselected value of said methane to ethane ratio in said bottom product stream.

12. Apparatus in accordance with claim 11 wherein said second signal conversion means comprises means for simulating the relationship between said temperature requirement signal and said heat requirement signal for said preselected value of said methane to ethane ratio in said bottom product stream.

13. Apparatus in accordance with claim 12 wherein said first correction means comprises means for adding said temperature requirement adjustment signal to said temperature requirement signal to produce said bottom temperature set point signal.

14. Apparatus in accordance with claim 13 wherein said second correction means comprises means for adding said required heat signal and said required heat correction signal to produce said corrected required heat signal.

15. Apparatus in accordance with claim 14 wherein said first signal conversion means is adapted to provide a temperature requirement signal which fulfills the general condition:

space="preserve" listing-type="equation">T.sub.R =A+BP.sub.c

where T_R is said temperature requirement signal, P_c is said column pressure signal, and A and B are constants.

16. Apparatus in accordance with claim 15 wherein said second signal conversion means is adapted to provide a required heat signal which fulfills the general condition:

space="preserve" listing-type="equation">H.sub.R =C+DT.sub.R

where H_R is said required heat signal, T_R is said temperature requirement signal, and C and D are constants.

17. A method for operating a fractionation column, said method comprising the steps of:

providing at least one feed material stream to said fractionation column;

recovering an overhead product stream from the top portion of said fractionation column;

recovering a bottom product stream from the bottom portion of said fractionation column;

generating a column pressure signal representative of the pressure at a preselected location within said fractionation column;

generating, in response to said column pressure signal, a temperature requirement signal representative of the value of said column bottom temperature required to provide a preselected value of a constituent ratio in said bottom product stream at the column pressure represented by said column pressure signal;

generating, in response to said temperature requirement signal, a required heat signal representative of the direction and magnitude of the change in heat input to said fractionation column required to provide the column bottom temperature required to provide said preselected value of said constituent ratio in said bottom product stream at the column pressure represented by said column pressure signal;

generating a column bottom temperature signal representative of the temperature within said fractionation column adjacent the bottom thereof;

generating an analysis signal representative of said constituent ratio in said bottom product stream;

generating, in response to said column pressure signal and said analysis signal, a column bottom temperature set point signal representative of the fractionation column bottom temperature required to provide a preselected bottom product composition;

generating, in response to said column bottom temperature signal and said column bottom temperature set point signal, a required heat correction signal;

generating, in response to said required heat signal and said required heat correction signal, a corrected required heat signal; and

manipulating the flow of heat to the bottom portion of said fractionation column in response to said corrected required heat signal.

18. A method in accordance with claim 17 wherein said step of generating said column bottom temperature set point signal comprises:

generating, in response to said analysis signal, a temperature requirement adjustment signal representative of the adjustment of said temperature requirement signal necessary to compensate for the difference between the analyzed constituent ratio in said bottom product stream and said preselected bottom product constituent ratio; and

combining said temperature requirement signal and said temperature requirement adjustment signal to generate said column bottom temperature set point signal.

19. A method in accordance with claim 18 wherein said step of combining said temperature requirement signal and said temperature requirement adjustment signal comprises adding said temperature requirement signal and said temperature requirement adjustment signal.

20. A method in accordance with claim 17 wherein said temperature requirement signal fulfills the general condition:

space="preserve" listing-type="equation">T.sub.R =A+BP.sub.c

where T_R is said temperature requirement signal, P_c is said column pressure signal, and A and B are constants.

21. A method in accordance with claim 17 wherein said required heat signal fulfills the general condition:

space="preserve" listing-type="equation">H.sub.R =C+DT.sub.R

where H_R is said required heat signal, T_R is said temperature requirement signal, and C and D are constants.

22. A method in accordance with claim 17 wherein said step of generating said required heat correction signal comprises comparing said column bottom temperature signal and said column bottom temperature set point signal and generating said required heat correction signal in response to the comparison.

23. A method in accordance with claim 17 wherein said step of generating said corrected required heat signal comprises adding said required heat signal and said required heat correction signal to produce said corrected required heat signal.

24. A method in accordance with claim 17 wherein said analysis signal comprises a methane to ethane ratio signal and wherein said preselected bottom product composition comprises a composition characterized by a preselected methane to ethane ratio.

25. A method in accordance with claim 18 wherein said analysis signal comprises a methane to ethane ratio signal and wherein said preselected bottom product composition comprises a composition characterized by a preselected methane to ethane ratio.

26. A method in accordance with claim 25 wherein generating said temperature requirement adjustment signal comprises comparing said analysis signal with an analysis set point signal representative of a desired methane to ethane ratio in said bottom product stream and generating said temperature requirement adjustment signal in response to said comparison.

27. A method in accordance with claim 26 wherein the methane to ethane ratio represented by said analysis set point signal is the same as said preselected methane to ethane ratio.

28. A method in accordance with claim 17 wherein said step of manipulating the flow of heat to the bottom of said fractionation column comprises:

combining said corrected required heat signal with a feed flow rate signal representative of the total flow rate of feed material to said fractionation column to produce a heat flow set point signal representative of the desired flow rate of heat to the bottom of said fractionation column;

generating a heat delivery signal representative of the measured rate of heat flow to the bottom of said fractionation column; and

manipulating the flow rate of a heat-containing fluid to heat exchanger means associated with the bottom of said fractionation column in response to a comparison of said heat flow set point signal with said heat delivery signal to provide a flow of heat to the bottom portion of said fractionation column represented by said heat flow set point signal.

29. A method in accordance with claim 28 wherein said heat-containing fluid comprises at least a portion of the total feed material provided to said fractionation column.