Apparatus for introducing samples into high pressure gas chromatographs or liquid chromatographs

• US 4,165,644 A
• Filed: 03/27/1978
• Issued: 08/28/1979
• Est. Priority Date: 04/09/1977
• Status: Expired due to Term

• Current Assignee: Bayer AG
• Original Assignee: Bayer AG
• Inventors: Muller, Karl-Heinz, Schnabel, Gunter, Brandt, Hans-Walter
• Primary Examiner(s): Swisher, S. Clement
• Application Number:
  US05/890,733
• Time in Patent Office: 519 Days
• Field of Search: 73/422 GC
• US Class Current: 73/864.83
• CPC Class Codes: B01D 15/40 using supercritical fluid as mobile phase or eluent
• CPC Class Codes: G01N 30/02 Column chromatography
• CPC Class Codes: G01N 30/16 Injection G01N30/24 takes precedence
• CPC Class Codes: G01N 30/20 using a sampling valve

Abstract

The combination of valves consists of a double passage cross-over spherical valve with which at least one other single passage spherical valve is connected in series. The passage of the cross-over spherical valve under high pressure is connected to the partition column of a gas chromatograph or liquid chromatograph while the other passage is intended for introducing the sample and is under atmospheric pressure when the sample is injected.

Claims

1. An apparatus for introducing samples into a high pressure fluid chromatograph having a partition column and a high pressure carrier fluid flow passage to the partition, comprising a double passage cross over spherical valve, two single-passage spherical valves connected in series therewith to define a sample passage, wherein one passage of the cross-over spherical valve is alignable with the carrier fluid passage to the partition column while the other passage of the cross-over spherical valve is aligned with the sample passage for introducing the sample under atmospheric pressure when the sample is injected and wherein the one passage is thereafter alignable with the sample passage while the other passage is aligned with the carrier passage to enable the carrier fluid to deliver the sample therein to the partition and a check valve wherein one end of the sample passage communicates via one single-passage spherical valve with the atmosphere and the other end of the sample passage is connected, via the check valve adapted to open at a predetermined pressure and close after pressure compensation and via the other single-passage spherical valve, to a gas under said predetermined pressure for dissolving the sample substance.