Control of the interaction of novel platinum-on-carbon electrocatalysts with fluorinated hydrocarbon resins in the preparation of fuel cell electrodes

• US 4,166,143 A
• Filed: 01/24/1977
• Issued: 08/28/1979
• Est. Priority Date: 01/24/1977
• Status: Expired due to Term

• Current Assignee: WALTER JUDA AND Walter Juda Associates, Inc./OR WALTER JUDA ASSOCIATES
• Original Assignee: Prototech AS
• Inventors: Allen, Robert J., Petrow, Henry G.
• Primary Examiner(s): Konopka, P. E.
• Application Number:
  US05/761,976
• Time in Patent Office: 946 Days
• Field of Search: 252/425.3, 252/430, 252/447, 252/511, 252/182.1, 252/326, 429/42, 427/115, 427/125, 210/51, 210/52, 264/105, 264/122
• US Class Current: 427/115
• CPC Class Codes: H01M 2300/0008 Phosphoric acid-based
• CPC Class Codes: H01M 4/8663 Selection of inactive substances as ingredients for catalytic active masses, e.g. binders, fillers
• CPC Class Codes: H01M 4/8828 Coating with slurry or ink
• CPC Class Codes: H01M 4/92 Metals of platinum group H01M4/94 , H01M4/9058 take precedence
• CPC Class Codes: H01M 4/926 on carbon or graphite
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

In the repeated production of a fuel cell component consisting of a uniform mixture of an electrocatalyst and a wetproofing agent, an aqueous colloidal fluorinated hydrocarbon resin dispersion is rapidly and reproducibly flocculated, preferably in less than 5 minutes, in the presence of an aqueous suspension of a novel platinum-on-carbon electrocatalyst by means of a polycationic salt solution, the salt concentration being preferably between 10^-3 and 10^-6 molar.

Claims

1. In the method of producing reproducibly a fuel cell electrode comprising a substantially uniform mixture of a finely divided 15 A-25 A platinum-on-carbon electrocatalyst comprising platinum particles substantially all in the range of 15 A- 25 A in size, and finely divided fluorinated hydrocarbon resin, the steps of forming an aqueous suspension of the said electrocatalyst with a sufficiently water-soluble ionizable salt of a polyvalent metallic cation in an amount between 10^-3 and 10^-6 gram-moles of salt per liter of suspension and mixing therewith an aqueous colloidal dispersion of said resin, rapidly to coagulate the mix without substantially affecting the finely divided 15 A-25 A platinum-on-carbon electrocatalyst performance, thereby causing said colloidal resin to flocculate substantially completely and at a controlled rapid rate and in substantially uniform admixture with said electrocatalyst in less than five minutes.

2. The method of claim 1, and in which said mixture is separated from the clear substantially resin-free supernatent and then applied to a conducting substrate.

3. The method of claim 1 wherein said polyvalent cation is selected from the group substantially not adsorbed by said mixture during said resin flocculation.

4. The method of claim 1 wherein said polyvalent cation is selected from La⁺⁺⁺, Ce⁺⁺⁺ and trivalent rare earth cations.

5. The method of claim 1 wherein said polyvalent cation is divalent.

6. The method of claim 1 wherein said polyvalent cation is selected from Calcium and Magnesium.