Method for the manufacture of caffeine free black tea

• US 4,167,589 A
• Filed: 04/26/1977
• Issued: 09/11/1979
• Est. Priority Date: 06/03/1971
• Status: Expired due to Term

• Current Assignee: Otto Vitzthum, Peter Hubert
• Original Assignee: Otto Vitzthum, Peter Hubert
• Inventors: Hubert, Peter, Vitzthum, Otto
• Primary Examiner(s): Golian, Joseph M.
• Application Number:
  US05/791,097
• Time in Patent Office: 868 Days
• Field of Search: 426/427, 426/428, 426/386, 426/424, 426/478, 426/312, 426/318, 426/319
• US Class Current: 426/312
• CPC Class Codes: A23F 3/366 by extraction of the leaves with selective solvents
• CPC Class Codes: A23F 3/423 by solvent extraction; Tea flavour from tea oil
• CPC Class Codes: B01D 11/0203 with a supercritical fluid

Abstract

A caffeine free black tea product is produced by an extraction procedure with a supercritical gas such as carbon dioxide in which first the aromatic content of the tea is extracted with dry gas, then the caffeine content is extracted with wet gas, and finally the decaffeinated tea is reimpregnated with the aromatic content.

Claims

1. A process for the production of caffeine free black tea which comprises the steps of:

a. Extracting tea leaves with a dry extraction solvent gas having selective dissolving capacity for the aromatic component, and which is maintained in the supercritical state with respect to temperature and presure to extract the aromatic content of the tea and leave a tea residue,

b. Separating the aromatic content from the extraction solvent,

c. Extracting the tea residue with a moist extraction solvent gas having selective dissolving capacity for the caffeine, and which is supercritical with respect to temperature and pressure to remove the caffeine,

d. Redissolving the aromatics separated in Step (b) utilizing an extraction solvent gas which is supercritical with respect to temperature and pressure and separating the aromatics from the gas in the presence of the substantially caffeine free tea residue, thereby to impregnate the residue with the original aromatic content.

2. A process according to claim 1 wherein the substantially caffeine free tea residue is extracted with water prior to impregnation with the aromatics;

the aqueous extract is spray dried to produce a dry powder which is thereafter impregnated with the aromatics in accordance with step (d).

3. A process as in claim 1 wherein the temperature in Step (b) is above the critical temperature of the extraction gas and the separation is effected by reducing the pressure.

4. A process as in claim 1 wherein the temperature in Step (b) is below the critical temperature of the extraction gas.

5. A process as in claim 1 wherein the selected gas in each of steps (a), (c), and (d) is carbon dioxide.

6. A process as in claim 1 wherein the selected gas in each of steps (a), (c) and (d) is carbon dioxide and Step (a) is carried out at a temperature of from about 40°

C. to 60°

C. at a pressure of from about 200 to 400 atmospheres absolute.

7. A process as in claim 1 wherein the selected gas in each of steps (a), (c), and (d) is carbon dioxide and Step (c) is carried out at a temperature of from about 40°

C. to 60°

C. and a pressure of from about 200 to 250 atmospheres absolute.

8. A process as in claim 1 wherein the selected gas in each of steps (a), (c), and (d) is carbon dioxide and the aromatics are impregnated at a temperature of from about -10°

C. to 20°

C.

9. A process as in claim 1 wherein the solvent gases are selected from the group consisting of carbon dioxide;

saturated and unsaturated hydrocarbons containing up to about three carbon atoms;

nitrous oxide;

saturated and unsaturated halogenated hydrocarbons containing up to about three carbon atoms;

sulfur hexafluoride; and

mixtures thereof.

16. A process as in claim 1, the separation in step (b) being effected by reducing the pressure, the gas in each of steps (a), (c), and (d) being carbon dioxide, the temperature in step (a) being about 40°

to 60°

C. and the pressure in step (a) being about 200 to 400 atms., the temperature in step (c) being about 40°

to 60°

C. and the pressure in step (c) being about 200 to 250 atms., and the aromatics are impregnated at about -10°

to 20°

C.

17. A process as in claim 1, wherein the separation in step (b) is effected by reducing the pressure to below the critical pressure.

10. A process for the production of caffeine free black tea, which comprises the steps of:

(a) extracting tea leaves with dry extraction solvent gas having selective dissolving capacity for the aromatic content, and which is maintained in the supercritical state with respect to temperature and pressure to extract aromatic content of the tea and leave a dearomatized tea residue.

(b) extracting the tea residue with a moist extraction solvent gas having selective dissolving capacity for the caffeine, and which is in the supercritical state with respect to temperature and pressure to remove caffeine and leave a dearomatized and decaffeinated tea residue,

(c) impregnating a dearomatized and decaffeinated tea residue with aromatic component extracted in step (a).

11. A process as in claim 10, wherein the solvent gas used in step (b) is moist carbon dioxide.

12. A process as in claim 11, wherein the solvent gas used in step (a) is dry carbon dioxide.

13. A process as in claim 12, wherein the temperature in step (a) and step (b) are 40°

-100°

C. and the pressures in step (a) and step (b) are above 100 atms.

14. Process as in claim 10, wherein a tea extract is produced from the dearomatized and decaffeinated tea residue produced in step (b), and aromatic component produced in step (a) is added to a dearomatized and decaffeinated tea extract.

15. A process as in claim 10, wherein the solvent gases are selected from the group consisting of carbon dioxide;

saturated and unsaturated hydrocarbons containing up to about 3 carbon atoms;

nitrous oxide;

saturated and unsaturated halogenated hydrocarbons containing up to about 3 carbon atoms;

sulfur hexafluoride; and

mixtures thereof.

18. A process for extracting aromatic constituents and caffeine from tea, which comprises extracting tea leaves with a dry extraction solvent gas having selective dissolving capability for the aromatic component, and which is maintained in the supercritical state with respect to temperature and pressure to extract the aromatic content of the tea and leave the dearomatized residue;

recovering the aromatic content; and

extracting the tea residue with a moist extraction solvent gas having selective dissolving capacity for the caffeine, and which is in the supercritical state with respect to temperature and pressure to remove caffeine.

19. Process according to claim 18, in which said dry extraction solvent gas is dry carbon dioxide and said moist extraction solvent gas is moist carbon dioxide.