Manufacture of olefin polymers

• US 4,169,925 A
• Filed: 04/28/1978
• Issued: 10/02/1979
• Est. Priority Date: 05/20/1977
• Status: Expired due to Term

• Current Assignee: BASF AG (BASF SE)
• Original Assignee: BASF AG (BASF SE)
• Inventors: Gruber, Wolfgang, Bachl, Robert, Frielingsdorf, Hans, Schweier, Guenther
• Primary Examiner(s): Holler, Alan
• Application Number:
  US05/901,196
• Time in Patent Office: 522 Days
• Field of Search: 526/96, 526/97, 526/99, 526/105, 526/106
• US Class Current: 526/96
• CPC Class Codes: C08F 10/00 Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
• CPC Class Codes: C08F 4/24 Oxides
• CPC Class Codes: C08F 4/26 of manganese, iron group metals or platinum group metals

Abstract

A process for the manufacture of olefin polymers by polymerizing α-monoolefins at relatively low temperatures and relatively low olefin pressures by means of a catalyst obtained from a silicate carrier (component a), an aluminum compound (component b) and a chromium compound (component c). The catalyst is obtained by (1) in a first stage, initially (1.1) charging a particular silicate carrier (component a) with (1.2) a mixture of (1.2.1) an aluminum salt or a mixture of an aluminum salt with up to 80 mole%, based on the salt mixture, of a nickel-II salt (component b) and (1.2.2) a chromium compound (component c), this compound being chromium trioxide or a compound which is converted to chromium trioxide under the conditions of stage (2), by treatment with a solution of the mixture (1.2), and (2), in a second stage then maintaining the product, obtained from stage (1), for a certain time at a high temperature in an anhydrous oxygen-containing gas stream. The process may be used to produce polymers having a relatively broad molecular weight distribution.

Claims

1. A process for the manufacture of an olefin polymer by polymerizing an α

-monoolefin of 2 to 8 carbon atoms at from 60°

to 160°

C. and at an olefin pressure of from 0.5 to 40 bars by means of a catalyst which is obtained from a silicate carrier (component a), an aluminum compound (component b) and a chromium compound (component c), wherein the catalyst employed is obtained by

(1) initially

(1.1) charging a finely divided xerogel (component a) of the formula

space="preserve" listing-type="equation">SiO.sub.2. mAl.sub.2 O.sub.3

where m is a number from 0 to 2, this xerogel having a particle diameter of from 20 to 2,000 μ

m, a pore volume of from 0.7 to 2.6 cm³ /g and a surface area of from 150 to 600 m² /g, with (1.2) a mixture of

(1.2.1) aluminum nitrate or a mixture of aluminum nitrate with up to 80 mole%, based on the mixture, of a nickel-II nitrate (component b) and

(1.2.2) a chromium compound (component c), which compound is chromium trioxide or a compound which is converted to chromium trioxide under the conditions of stage (2),

by thoroughly mixing with a solution of the mixture (1.2) and evaporating off the solvent and

(2) then maintaining the product obtained from stage (1) for from 10 to 400 minutes at from 600°

to 1,000°

C. in an anhydrous gas stream containing oxygen at a concentration of more than 10 percent by volume,

with the proviso that the catalyst contains from 0.1 to 10 parts by weight of component (b) (calculated as aluminum or aluminum plus nickel) and from 0.3 to 10 parts by weight of component (c) (calculated as chromium trioxide) per 100 parts by weight of component (a) (calculated as silica).

2. The process of claim 1, wherein the xerogel has a particle diameter of from 40 to 300 μ

m, a pore volume of from 1 to 2.5 cm³ /g and a surface area of from 300 to 600 m² /g.

3. The process of claim 1, wherein m in the formula of the xerogel is a number from 0 to 0.5.

4. The process of claim 1, wherein the conditions in stage (2) include a temperature of from 700°

to 950°

C. and the product from stage (1) is maintained in step (2) for from 60 to 300 minutes.

5. The process of claim 1, wherein the catalyst contains from 0.5 to 5 parts by weight of component (b) and from 1 to 5 parts by weight of component (c) per 100 parts by weight of component (a).