Gas monitoring method and apparatus therefor

• US 4,170,455 A
• Filed: 03/11/1976
• Issued: 10/09/1979
• Est. Priority Date: 03/11/1976
• Status: Expired due to Term

• Current Assignee: Rockwell International Corporation
• Original Assignee: Rockwell International Corporation
• Inventors: Henrie, James O.
• Primary Examiner(s): Scovronek, Joseph
• Application Number:
  US05/665,738
• Time in Patent Office: 1,307 Days
• Field of Search: 23/232 R, 23/254 R, 23/232 E, 23/254 E, 23/255 R, 23/255 E, 73/23, 73/25, 73/26, 73/27 R, 422/83, 422/94, 422/95, 422/98
• US Class Current: 436/144
• CPC Class Codes: G01N 25/32 using thermoelectric elements
• CPC Class Codes: G01N 33/0013 by a chemical reaction G01N33/0024 takes precedence
• CPC Class Codes: Y10T 436/22 Hydrogen, per se

Abstract

A method and apparatus for monitoring the concentration of a component of a gas stream. The gas stream to be monitored is heated to a desired temperature and passed through an insulated gas passageway of a conduit member. The heated gas passes sequentially through a perforate metal shield and a body of a particulate catalyst. The temperature of the heated gas entering and leaving the conduit member is monitored and any increase in temperature is correlatable with the component concentration in the gas stream. The method and apparatus are particularly suitable for monitoring the concentration of hydrogen or oxygen in a gas stream.

Claims

1. An apparatus for monitoring a gas stream comprising:

(a) a conduit member defining a single gas passageway extending therethrough and having opposite ends, a gas inlet means adjacent one of the ends, and a gas outlet means adjacent the other of the ends, said gas passageway defining the sole means of fluid communication between said gas inlet and gas outlet means;

(b) at least two temperature sensors, one located adjacent the gas inlet means and the other located adjacent the gas outlet means of said conduit member for sensing the temperature of a gas passing therethrough;

(c) a body of a particulate catalyst located in the gas passageway of said conduit member intermediate the two temperature sensors;

(d) at least one perforate heat shield located in the gas passageway of said conduit member between the body of particulate catalyst and the gas inlet temperature sensor for reducing the transfer of radiant thermal energy from the body of particulate catalyst material to the gas inlet temperature sensor; and

(e) heater means for heating the gas stream to be monitored to a desired temperature prior to its entry into contact with the gas inlet temperature sensor.

2. The apparatus of claim 1 wherein the catalyst material is selected from the group consisting of platinum, palladium, and combinations thereof.

3. The apparatus of claim 1 wherein said conduit member is surrounded by a metal housing.

4. The apparatus of claim 1 wherein said conduit member is formed from a thermal insulating material.

5. The apparatus of claim 3 wherein said conduit member is thermally insulated from said metal housing.

6. The apparatus of claim 1 wherein at least one of said gas inlet and gas outlet means are in axial alignment with the gas passageway of the conduit member.

7. An apparatus for monitoring the hydrogen or oxygen content of a gas stream in which one of said hydrogen or oxygen is present in an excess over the other, which apparatus comprises:

(a) an elongated conduit member defining a single gas passageway extending axially therethrough and having opposite ends, a gas inlet adjacent one of the ends and a gas outlet adjacent the other of the ends, said single gas passageway defining the sole means of fluid communication between said gas inlet and outlet;

(b) a gas inlet temperature sensor located in the gas passageway adjacent the inlet end of the conduit member for sensing the temperature of a gas passing therethrough;

(c) a gas outlet temperature sensor located in the gas passageway adjacent the gas outlet end of the conduit member for sensing the temperature of a gas passing therethrough;

(d) a body of particulate catalyst material located in the gas passageway intermediate the gas inlet and gas outlet temperature sensors, said body of particulate catalyst material being located in the proximity of the gas outlet end of the conduit member, and having an exposed surface selected from the group of materials consisting of palladium, platinum and combinations thereof;

(e) a perforate metal heat shield, located in the passageway of the conduit member between the body of particulate catalyst material and the gas inlet temperature sensor, for shielding the gas inlet temperature sensor from radiant thermal energy from the body of particulate catalyst material; and

(f) means associated with the conduit member for heating the gas stream to a desired temperature prior to its entry into the gas inlet, said temperature being substantially above ambient temperature.

8. The apparatus of claim 7 wherein said conduit member is surrounded by a metal housing.

9. The apparatus of claim 8 wherein said conduit member is formed from a thermal insulating material.

10. The apparatus of claim 8 wherein said housing is in a spaced relation from said conduit member and a thermal barrier means is located in the space between them.

11. A method for monitoring a component of a gas stream comprising the sequential steps of:

(a) heating the gas stream to a desired temperature,

(b) introducing the gas stream into a single, axially extending, thermally insulated gas passageway,

(c) sensing the temperature of the heated gas stream,

(d) passing the gas stream through at least one perforate heat shield,

(e) passing the gas through a bed of particulate catalyst, which is spaced from said perforate metal shield,

(f) sensing the temperature of the gas exiting the catalyst bed,

(g) determining the concentration of the component of the gas stream as a function of the difference between the temperatures in steps (c) and (f), and

(h) discharging the gas stream from the thermally insulated gas passageway.

12. A method of monitoring the hydrogen content of a gas stream containing the same in an excess of oxygen comprising the sequential steps of:

(a) heating the gas stream to a temperature substantially above ambient temperature,

(b) introducing the heated gas stream into a single, axially extending thermally insulated gas passageway,

(c) sensing the temperature of the heated gas stream,

(d) passing the gas stream through a perforate metal heat shield,

(e) passing the gas stream through a bed of a particulate catalyst, said catalyst being selected from a group consisting of platinum, palladium, and combinations thereof,

(f) sensing the temperature of the gas exiting the catalyst bed,

(g) determining the hydrogen content as a function of the difference between the temperatures in steps (c) and (f), and

(h) discharging the gas stream from the thermally insulated gas passageway.