Method of and apparatus for the analysis of gases

• US 4,170,892 A
• Filed: 05/05/1978
• Issued: 10/16/1979
• Est. Priority Date: 05/06/1977
• Status: Expired due to Term

• Current Assignee: Kernforschungsanlage Julich GmbH
• Original Assignee: Kernforschungsanlage Julich GmbH
• Inventors: Bailitis, Eduard
• Primary Examiner(s): Kreitman, Stephen A.
• Application Number:
  US05/903,066
• Time in Patent Office: 529 Days
• Field of Search: 73/23, 73/30, 250/281, 250/288, 250/289, 250/457, 23/232 R, 23/254 R
• US Class Current: 73/23.2
• CPC Class Codes: G01N 9/00 Investigating density or specific gravity of materials; Analysing materials by determining density or specific gravity

Abstract

The mean molecular velocity or molecular weight of an unknown gas is determined by admitting the gas at a constant flow rate into an evacuated chamber of known volume, the gas being permitted to escape through a first flow cross section in a Knudsen flow. After a first steady state is reached, the gas density is measured and then a second flow cross section is opened between the evacuated chamber and a low-pressure zone. The measurement is repeated and the difference between the two values obtained and the gradient of the measurement is used to calculate the mean molecular velocity and the molecular weight.

Claims

1. A method of analyzing a gas comprising the steps of:

(a) feeding the gas to be analyzed into a first zone of known volume and permitting the gas in said zone to escape in a Knudsen flow through a first cross section into a second zone at a predetermined pressure;

(b) permitting the gas flow into and from the first zone in step (a) to reach a first steady state;

(c) measuring a parameter of the gas in said first zone at said first steady state;

(d) spontaneously changing the flow cross section through which said gas escapes from said first zone upon attainment of said first steady state and permitting the gas flow into said first zone and through the changed cross section to reach a second steady state;

(e) measuring said parameter of the gas at said second steady state; and

(f) deriving from said measurements values of the difference between the measurements at said steady states and the gradient of the measured value upon the spontaneous change in the cross section, the molecular weight of the gas and the mean molecular velocity thereof being functions of said difference and gradient.

2. The method defined in claim 1 wherein the spontaneous change in the flow cross section in step (d) is an increase in the flow cross section.

3. The method defined in claim 2 wherein the volume of the first zone, the pressure in said second zone and the feed rate of the gas to the first zone are held constant.

4. The method defined in claim 2 wherein the volume of the first zone, the pressure in said second zone or the feed rate of the gas to the first zone are held constant.

5. The method defined in claim 2 wherein steps (a) through (e) are repeated for a succession of cross sectional changes with the gradient and the difference between each new and previous steady state being determined in step (f) for each repetition.

6. The method defined in claim 5 wherein each change in cross section is by the same amount.

7. The method defined in claim 2 wherein said parameter is the gas density.

8. The method defined in claim 2 wherein said parameter is a parameter proportional to gas density.

9. The method defined in claim 2 wherein said first zone is evacuated to a pressure of 10^-5 to 10^-9 torr.

10. The method defined in claim 9 wherein said pressure is of the order of 10^-7 torr.

11. The method defined in claim 1 wherein steps (c), (e) and (f) are carried out automatically.

12. The method defined in claim 1 wherein step (f) is carried out at least in part by plotting the change in the measurement of said parameter as a function of time upon spontaneous change in the flow cross section in step (d).

13. The method defined in claim 1 wherein said parameters are measured and an electric signal representing same is generated, said difference being the difference in the magnitude of the electrical signals from the measurements at said first and second steady states.

14. An apparatus for analyzing a gas, comprising:

a vacuum chamber having a defined volume;

means for feeding said chamber with a gas to be analyzed at a constant flow rate;

means for evacuating said chamber;

valve means defining a first flow cross section and a second flow cross section and connecting same selectively between said evacuating means and said chamber whereby a first Knudsen flow is established through at least one of said cross sections and the other cross section is selectively openable and closable to change the Knudsen cross-section at which gas escapes from said chamber; and

a sensor for gas density in said chamber.

15. The apparatus defined in claim 14 wherein said valve means includes a pair of valves each defining one of said cross sections and having the same effective cross section in the open state.

16. The apparatus defined in claim 14 wherein said feeding means includes a source of said gas and a control valve between said source and said chamber for maintaining the feed rate constant.

17. The apparatus defined in claim 16 wherein said valve means further comprises a valve formed with a large cross section and openable for evacuation of said chamber prior to the feed of said gas thereto.

18. The apparatus defined in claim 17 which is constituted as an ultra-high vacuum apparatus.

19. The apparatus defined in claim 17 wherein said sensor is the ion source of a mass spectrometer connected to said chamber.

20. The apparatus defined in claim 19 wherein said sensor is disposed in a measuring chamber connected to said vacuum chamber by a window with a small effective flow cross section, said ion source being disposed downstream of said window.

21. The apparatus defined in claim 20 wherein said mass spectrometer is disposed axially of the molecular flow through said window.

22. The apparatus defined in claim 20 wherein said mass spectrometer extends normal to the molecular flow through said window.

23. The apparatus defined in claim 20, further comprising means for evacuating said measuring chamber to a pressure at least one to two powers of ten below that of said vacuum chamber.