Method for decontaminating and sealing the interior spaces of an insulated electrical device utilizing mineral oil-extended polyurethanes

• US 4,171,998 A
• Filed: 09/30/1976
• Issued: 10/23/1979
• Est. Priority Date: 01/11/1974
• Status: Expired due to Term

• Current Assignee: CasChem, Inc.
• Original Assignee: NL Industries Incorporated (Valhi Holding Company)
• Inventors: Brauer, Melvin, Kroplinski, Thaddeus F.
• Primary Examiner(s): Pitlick, Harris A.
• Application Number:
  US05/728,665
• Time in Patent Office: 1,118 Days
• Field of Search: 427/120, 427/117, 260/33.6 UB, 260/31.2 N, 260/31.6, 260/31.8 C, 260/32.8 N, 156/48, 174/23 C, 252/63.2, 252/63, 252/63.7
• US Class Current: 34/282
• CPC Class Codes: C08G 18/69 Polymers of conjugated dienes hydrogenated polymers of conjugated dienes C08G18/6208
• CPC Class Codes: C08G 18/755 and at least one isocyanate or isothiocyanate group linked to a secondary carbon atom of the cycloaliphatic ring, e.g. isophorone diisocyanate
• CPC Class Codes: H01B 3/302 Polyurethanes or polythiourethanes; Polyurea or polythiourea

Abstract

This invention provides a method of sealing and purging contaminants from the internal free spaces of an insulated electrical device by forcing into said free spaces a low viscosity material that acts to displace fluid contaminants from within said free spaces. The material later cures in situ to form a hydrophobic seal with good electrical properties. Also disclosed herein is a method for rehabilitating waterlogged plastic insulated multiconductor communications cables of the type employed in telephone systems.

Claims

1. A process for removing aqueous contaminants from the interior free spaces of an insulated electrical device and for subsequently sealing said device against further water penetration comprising the steps of pumping into said device a composition comprising mineral oil, polyurethane precursor and coupling agent, said precursor comprising

(a) a polyol selected from the group consisting of castor oil, polyether polyols, hydroxyl bearing homopolymers of butadiene, hydroxyl bearing copolymers of butadiene and styrene, and combinations thereof, and

(b) a polyisocyanate prepolymer prepared by reacting

(i) polyisocyanate with

(ii) a polyol selected from the group consisting of castor oil, polyether polyols, hydroxyl bearing homopolymers of butadiene, hydroxyl bearing copolymers of butadiene and styrene, and combinations thereof,

wherein at least a portion of the polyol used in (a) and/or at least a portion of the polyol used in (b) (ii) is selected from the group consisting of hydroxyl bearing homopolymers of butadiene and hydroxyl bearing copolymers of butadiene and styrene, said coupling agent being characterized by:

(a) being miscible in all proportions with said mineral oil;

(b) having a solubility parameter between 7.0 and 9.5;

(c) having a hydrogen bonding index number in the range of from 6.0 to 12.0; and

(d) being non-reactive with said polyurethane precursor, and

reacting said polyol with said polyisocyanate prepolymer in the presence of said mineral oil and said coupling agent to obtain a cured, cross-linked, mineral oil extended polyurethane which is non-spewing and gel-like in consistency and which comprises from about 8 to about 45 parts of polyurethane, from about 25 to about 75 parts of mineral oil and from about 10 to about 35 parts of coupling agent, all parts expressed on a weight basis.

2. The process of claim 1, wherein said coupling agent is selected from the group consisting of a ketone and an ester.

3. The process of claim 2 wherein said polyisocyanate is selected from the group consisting of cycloaliphatic diisocyanate, aliphatic diisocyanate and aromatic diisocyanate.

4. The process of claim 3 wherein said coupling agent is further characterized by having a boiling temperature above 220°

F.

5. The process of claim 4 wherein said coupling agent is further characterized by having a hydrogen bonding index number in the range of from 8.2 to 8.8.

6. The process of claim 5 wherein said mineral oil comprises paraffin oil.

7. The process of claim 1 wherein said cured, cross-linked, mineral oil extended polyurethane comprises from about 8 to about 20 parts of polyurethane, from about 60 to about 75 parts of mineral oil and from about 10 to about 25 parts of coupling agent, all parts expressed on a weight basis.

8. The process of claim 1 wherein said cured, cross-linked, mineral oil extended polyurethane comprises from about 20 to about 45 parts of polyurethane, from about 25 to about 60 parts of mineral oil and from about 25 to about 35 parts of coupling agent, all parts expressed on a weight basis.

9. A process for removing aqueous contaminants from the interior free spaces of an insulated electrical device and for subsequently sealing said device against further water penetration comprising the steps of pumping into said device a mineral oil extended polyurethane precursor in admixture with a coupling agent and reacting the polyurethane precursor to obtain a cured, cross-linked, mineral oil extended polyurethane which is non-spewing and gel-like in consistency and which comprises from about 8 to about 45 parts of polyurethane, from about 25 to about 75 parts of mineral oil and from about 10 to about 35 parts of coupling agent, all parts expressed on a weight basis, the cured, cross-linked polyurethane being characterized by the presence of a polybutadiene moiety in the polyurethane structure and said coupling agent being characterized by:

(a) having a solubility parameter between 7.0 and 9.5;

(b) having a hydrogen bonding index number in the range of from 6.0 to 12.0;

being miscible in all proportions with said mineral oil; and

(d) being non-reactive with said polyurethane precursor.

10. The process of claim 9 wherein the polybutadiene moiety is derived from at least one member selected from the group consisting of hydroxyl bearing homopolymers of butadiene and hydroxyl bearing copolymers of butadiene and styrene.

11. The process of claim 10 wherein said coupling agent is further characterized by having a boiling temperature above 220°

F.