Acid hydrolysis of cellulose to yield glucose

• US 4,174,976 A
• Filed: 03/08/1978
• Issued: 11/20/1979
• Est. Priority Date: 03/08/1978
• Status: Expired due to Term

• Current Assignee: Purdue Research Foundation (The Trustees of Purdue University (d/b/a Purdue University))
• Original Assignee: Purdue Research Foundation (The Trustees of Purdue University (d/b/a Purdue University))
• Inventors: Ladisch, Michael R., Tsao, George T., Bose, Arindam
• Primary Examiner(s): Marantz, Sidney
• Application Number:
  US05/884,478
• Time in Patent Office: 622 Days
• Field of Search: 127/37
• US Class Current: 127/37
• CPC Class Codes: C13K 1/02 obtained by saccharification of cellulosic materials manufacture of fodder A23K10/32

Abstract

A process to yield glucose from cellulose through acid hydrolysis. Cellulose is recovered from cellulosic materials, preferably by pretreating the cellulosic materials by dissolving the cellulosic materials in Cadoxen or a chelating metal caustic swelling solvent and then precipitating the cellulose therefrom. Hydrolysis is accomplished using an acid, preferably dilute sulfuric acid, and the glucose is yielded substantially without side products. Lignin may be removed either before or after hydrolysis.

Claims

1. A process for hydrolyzing the cellulose in a cellulosic material to obtain glucose therefrom comprising:

contacting the cellulosic material either with a solvent comprising ethylenediamine, cadmium hydroxide and water or with a solvent comprising a chelating metal caustic swelling agent whereby the solvent dissolves the cellulose to form a solution,

precipitating the cellulose from the solution; and

hydrolyzing the precipitated cellulose with acid to obtain glucose.

2. The process of claim 1 wherein the solution is separated from any non-soluble non-cellulosic portion of the cellulosic material before precipitating the cellulose.

3. The process of claim 1 wherein said acid is selected from the group consisting of mineral and organic acids.

4. The process of claim 1 wherein said acid is selected from the group of mineral acids consisting of sulfuric acid, hydrochloric acid, and phosphoric acid.

5. The process of claim 1 wherein said acid hydrolysis is practiced at a temperature range of ambient to about 200°

C.

6. The process of claim 1 wherein said acid hydrolysis is carried out in a closed vessel at a temperature of between 100°

C. and 200°

C.

7. The process of claim 1 wherein lignin is separated from said glucose by filtration or centrifugation.

8. The process of claim 1 wherein lignin is separated from said precipitated cellulose before hydrolysis to yield glucose.