Aqueous cleanser compositions

• US 4,175,062 A
• Filed: 03/06/1978
• Issued: 11/20/1979
• Est. Priority Date: 03/05/1977
• Status: Expired due to Term

• Current Assignee: Henkel KGaA (Henkel AG & Co KGaA)
• Original Assignee: Henkel KGaA (Henkel AG & Co KGaA)
• Inventors: Kiewert, Eva, Disch, Karlheinz
• Primary Examiner(s): Weinblatt, Mayer
• Application Number:
  US05/883,685
• Time in Patent Office: 624 Days
• Field of Search: 252/121, 252/173, 252/535, 252/540, 252/554, 252/559
• US Class Current: 510/424
• CPC Class Codes: C11D 1/143 Sulfonic acid esters
• CPC Class Codes: C11D 1/22 derived from aromatic compounds
• CPC Class Codes: C11D 1/72 Ethers of polyoxyalkylene glycols
• CPC Class Codes: C11D 1/83 Mixtures of non-ionic with anionic compounds
• CPC Class Codes: C11D 10/04 based on mixtures of surface-active non-soap compounds and soap

Abstract

Liquid cleanser compositions for cleaning hard surfaces comprising an aqueous solution containing from 2 to 30% by weight of a mixture consisting of:

(a) adducts of 3 to 30 mols of ethylene oxide onto vicinal alkanediols having 10 to 20 carbon atoms or monoalkyl ethers of said alkanediols with 1 to 4 carbon atoms in the alkyl, and

(b) linear alkylbenzene sulfonic acids and/or linear alkane sulfonic acids, each with 8 to 20 carbon atoms in the alkyl or alkane, and their water-soluble salts, in a weight ratio of a:b of from 1:1 to 1:20.

Claims

1. Liquid cleanser compositions for cleaning hard surfaces consisting essentially of an aqueous solution containing

(1) from 2% to 30% by weight of a tenside mixture consisting of:

(a) adducts of 3 to 30 mols of ethylene oxide onto alcohols selected from the group consisting of aliphatic-vicinal alkanediols having 10 to 20 carbon atoms and monoalkyl ethers of said alkanediols having 1 to 4 carbon atoms in the alkyl, and

(b) anionic sulfonic compounds selected from the group consisting of linear alkylbenzene sulfonic acids having 8 to 20 carbon atoms in the alkyl, linear alkane sulfonic acids having 8 to 20 carbon atoms, mixtures of said acids, and water-soluble salts of said acids selected from the group consisting of alkali metal salts, alkaline earth metal salts and ammonium salts, where the ratio of a;

b is from 1;

1 to 1;

20,

(2) from 0 to 3% by weight of a water-soluble salt of a fatty acid having from 12 to 18 carbon atoms, and having a pH in the range of 7.0 to 10.5 as a 2% solution.

2. The liquid cleanser composition of claim 1 wherein said ethylene oxide adduct has from 4 to 20 mols of ethylene oxide adducted thereon.

3. The liquid cleanser composition of claim 1 wherein said ethylene oxide adduct has from 5 to 10 mols of ethylene oxide adducted thereon.

4. The liquid cleanser composition of claim 1 wherein said adduct component (a) is the adduct of 5 to 10 mols of ethylene oxide onto alcohols selected from the group consisting of aliphatic, non-terminal vicinal alkanediols having 11 to 18 carbon atoms and monoalkyl ethers of said alkanediols having 1 to 2 carbon atoms in the alkyl.

5. The liquid cleanser composition of claim 1 wherein the ratio of a:

b is from 1;

2 to 1;

10.

6. The liquid cleanser composition of claim 1 wherein said tenside mixture component (1) is present in an amount of from 5% to 15% by weight.

7. The liquid cleanser composition of claim 1 wherein said pH is from 7.5 to 9.5 as a 2% solution.

8. The liquid cleanser composition of claim 1 having a further content of up to 30% by weight of other customary liquid cleanser ingredients selected from the group consisting of polymeric phosphates, organic sequestering agents, wash alkalis, sodium sulfate, soil suspension agents, hydrotropic agents, organic solvents, dyes, odorants and antimicrobial agents.

9. The liquid cleanser composition of claim 1 wherein said anionic sulfonic compounds are selected from the group consisting of linear alkylbenzene sulfonic acids having 10 to 18 carbon atoms in the alkyl, linear alkane sulfonic acids having 12 to 18 carbon atoms, mixtures of said acids and water-soluble alkali metal and ammonium salts thereof.

10. The liquid cleanser compositions of claim 9 wherein said alkylbenzene sulfonic acids have from 11 to 14 carbon atoms in the alkyl.

11. A liquid cleanser composition for cleaning hard surfaces consisting essentially of an aqueous solution containing:

6% to 9% by weight of a sulfonate selected from the group consisting of alkali metal C₁₁ -C₁₄ -alkylbenzene sulfonates and alkali metal C₁₂ -C₁₈ -alkane sulfonates,

0.5% to 3% by weight of a C₁₀ -C₂₀ -alkanediol+10-11 mols of ethylene oxide,

0 to 3% by weight of an alkali metal or ammonium soap of a C₁₂ -C₁₈ -fatty acid,

2.5% to 6% by weight of sodium tripolyphosphates,

0 to 6% by weight of ethylene glycol monobutyl ether,

0 to 2% by weight of pine oil,

2% to 3% by weight of alkali metal cumene sulfonate,

0.2% to 0.6% by weight of perfume oil,

0.0005% to 0.005% by weight of dyes, and

0 to 6% by weight of ethanol, and the remainder water.