Photovoltaic cell comprising metal-free phthalocyanine

• US 4,175,981 A
• Filed: 07/03/1978
• Issued: 11/27/1979
• Est. Priority Date: 07/03/1978
• Status: Expired due to Term

• Current Assignee: Xerox Corporation (Xerox Holdings Corp.)
• Original Assignee: Xerox Corporation (Xerox Holdings Corp.)
• Inventors: Loutfy, Rafik O., Sharp, James H., McIntyre, Lloyd F.
• Primary Examiner(s): Weisstuch, Aaron
• Application Number:
  US05/921,302
• Time in Patent Office: 512 Days
• Field of Search: 136/89 NB, 136/89 SJ, 250/211 J, 250/212, 250/211 R, 357/8, 357/30, 357/15
• US Class Current: 136/255
• CPC Class Codes: H10K 30/451 comprising a metal-semiconductor-metal [m-s-m] structure
• CPC Class Codes: H10K 30/50 Photovoltaic [PV] devices
• CPC Class Codes: H10K 85/311 Phthalocyanine
• CPC Class Codes: Y02E 10/549 Organic PV cells

Abstract

A photovoltaic cell wherein the photoactive layer comprises a thin layer of metal-free phthalocyanine dispersed in a binder. The electrical output is greatly in excess of that obtained from prior art organic semiconductor photovoltaic cells of the same surface area.

Claims

1. A photovoltaic apparatus comprising a device having a first, ohmic electrode and a second, barrier electrode having sandwiched therebetween a photoactive layer comprising metal-free phthalocyanine dispersed in an electrically insulating binder and leads connecting each of said electrodes to an electrical circuit forming a load circuit wherein said device is the power source.

2. The apparatus of claim 1 wherein the layer has a thickness of from about 1 to about 3 microns.

3. The apparatus of claim 1 wherein the metal-free phthalocyanine is in the x-form.

4. The apparatus of claim 3 wherein the x-form metal-free phthalocyanine is present in the binder in the range of from about 15 to about 95 percent by weight.

5. The apparatus of claim 3 wherein the x-form metal-free phthalocyanine is present in the binder in the range of from about 55 to about 65 percent by weight.

6. The apparatus of claim 3 wherein the binder is a polymer selected from the group consisting of polystyrenes, polyacrylonitriles, polyvinylacetates, polycarbonates, copolymers of polystyrene and acrylonitrile, and polyvinylcarbazoles.

7. The apparatus of claim 1 wherein the barrier electrode comprises a vapor deposited layer of aluminum.

8. The apparatus of claim 1 wherein a light transparent protective layer resides on said barrier electrode.

9. The apparatus of claim 1 wherein said protective layer is dye sensitized.

10. The apparatus of claim 9 wherein the sensitizing dye commprises coumarine.

11. The apparatus of claim 1 wherein the metal-free phthalocyanine is in the alpha form.

12. The apparatus of claim 1 wherein the metal-free phthalocyanine is in the beta form.

13. The apparatus of claim 1 wherein an electrically insulating layer is provided between said photoactive layer and said barrier electrode.

14. The apparatus of claim 1 wherein the photoactive layer comprises a stabilizer.

15. The apparatus of claim 14 wherein the stabilizer is selected from the group consisting of tetrabutylammonium perchlorate and di-m-tolyl-diphenyl-biphenyldiamine.

16. The apparatus of claim 1 wherein the photoactive layer contains an electron acceptor material.

17. The apparatus of claim 16 wherein the electron acceptor material is selected from the group consisting of chloranil, ortho-benzoquinone, tetracyano-quindomethane, tetracyanoethylene and trinitrofluorenone.

18. A photovoltaic apparatus comprising a device having a first electrode having coated thereon a photoactive layer comprising from about 55 percent to about 65 percent, by weight, x-form metal-free phthalocyanine dispersed in an electrically insulating binder comprising polyvinyl acetate, a second, barrier electrode residing on said photoactive layer and leads connecting each of said electrodes to an electrical circuit forming a load circuit wherein said device is the power source.

19. The apparatus of claim 18 wherein said photoactive layer is dye sensitized.

20. The apparatus of claim 19 wherein said sensitizer is coumarine.

21. The apparatus of claim 19 wherein the dye is diffused into the photoactive layer to a depth of about 400 Angstroms at the barrier electrode interface.

22. The apparatus of claim 18 wherein said photoactive layer has a thickness of from about 1 to about 3 microns.

23. The apparatus of claim 18 wherein said barrier electrode is aluminum.

24. The method of converting light energy into electrical energy which comprises providing a device comprising a first, ohmic electrode and a second, barrier electrode and sandwiched therebetween a photoactive layer comprising metal-free phthalocyanine dispersed in an electrically insulating binder, and exposing said photoactive layer to light through said barrier electrode.

25. The method of claim 24 wherein the photoactive layer has a thickness of from about 1 to about 3 microns.

26. The method of claim 24 wherein the metal-free phthalocyanine is in the x-form.

27. The method of claim 26 wherein the x-form metal-free phthalocyanine is present in the binder in the range of from about 15 percent to about 95 percent, by weight.

28. The method of claim 26 wherein the x-form metal-free phthalocyanine is present in the binder in the range of from about 55 percent to about 65 percent, by weight.

29. The method of claim 24 wherein the binder is a polymer selected from the group consisting of polystyrenes, polyacrylonitriles, polyvinylacetates, polycarbonates, copolymers of polystyrene and acrylonitrile, and polyvinylcarbazoles.

30. The method of claim 24 wherein the barrier electrode comprises a vapor deposited layer of aluminum.