Insulated electrical cable containing an agent for decontaminating and sealing the interior space thereof

• US 4,176,239 A
• Filed: 03/09/1978
• Issued: 11/27/1979
• Est. Priority Date: 09/30/1976
• Status: Expired due to Term

• Current Assignee: CasChem, Inc.
• Original Assignee: NL Industries Incorporated (Valhi Holding Company)
• Inventors: Brauer, Melvin, Kroplinski, Thaddeus F.
• Primary Examiner(s): Grimley, Arthur T.
• Application Number:
  US05/884,976
• Time in Patent Office: 628 Days
• Field of Search: 174/23 R, 174/23 C, 174/116, 174/25 R, 174/25 C, 174/110 R, 174/17 LF, 156/48, 260/33.6 UB, 260/33.8 UB, 260/33.4 UR, 260/18 TN, 260/2.5
• US Class Current: 174/23.00C
• CPC Class Codes: H01B 3/20 liquids, e.g. oils silicone oils H01B3/46
• CPC Class Codes: H01B 3/302 Polyurethanes or polythiourethanes; Polyurea or polythiourea
• CPC Class Codes: H01B 7/288 using hygroscopic material or material swelling in the presence of liquid

Abstract

This invention provides a method of sealing and purging contaminants from the internal free spaces of an insulated electrical device by forcing into said free spaces a low viscosity material that acts to displace fluid contaminants from within said free spaces. The material later cures in situ to form a hydrophobic seal with good electrical properties. Also disclosed herein is a method for rehabilitating waterlogged plastic insulated multiconductor communications cables of the type employed in telephone system.

Claims

1. An insulated electrical device containing a plurality of insulated wire conductors, said device having interior spaces between the insulated wire conductors which contain a cured, cross-liked, mineral oil extended polyurethane which is non-spewing, comprising:

(a) from about 8 to about 45 parts by weight, of polyurethane, said polyurethane being prepared by reacting,

(i) a polyol selected from the group consisting of castor oil, polyether polyols, hydroxyl bearing homopolymers of butadiene, hydroxyl bearing copolymers of butadiene and styrene, and combinations thereof, with

(ii) a polyisocyanate prepolymer prepared by reacting a polyisocyanate with a polyol selected from the group consisting of castor oil, polyether polyols, hydroxyl bearing homopolymers of butadiene, hydroxyl bearing copolymers of butadiene and styrene, and combinations thereof,

(b) from about 25 to about 75 parts, by weight, of mineral oil, and

(c) from about 10 to about 35 parts, by weight, of coupling agent, said coupling agent being characterized by

(i) being miscible in all proportions with said mineral oil,

(ii) having a solubility parameter between 7.0 and 9.5,

(iii) having a hydrogen bonding index number in the range of from 6.0 to 12.0, and

(iv) being non-reactive with the polyurethane percursor, and

wherein the cured, cross-linked, mineral oil extended polyurethane is further characterized by the presence of a polybutadiene moiety in the polyurethane structure.

2. The insulated electrical device of claim 1 wherein said coupling agent is selected from the group consisting of a ketone and an ester.

3. The insulated electrical device of claim 2 wherein said polyisocyanate is selected from the group consisting of cycloaliphatic diisocyanate, aliphatic diisocyanate and aromatic diisocyanate.

4. The insulated electrical device of claim 3 wherein said coupling agent is further characterized by having a boiling temperature above 220°

F.

5. The insulated electrical device of claim 4 wherein said coupling agent is further characterized by having a hydrogen bonding index number in the range of from 8.2 to 8.8.

6. The insulated electrical device of claim 5 wherein said mineral oil comprises paraffin oil.

7. The insulated electrical device of claim 4 wherein said coupling agent is 2,2,4 trimethyl 1,3 pentanediol diisobutyrate.

8. The insulated electrical device of claim 4 wherein said coupling agent is dioctyl adipate.

9. The insulated electrical device of claim 1 wherein said cured, cross-linked, mineral oil extended polyurethane comprises from about 8 to about 20 parts of polyurethane, from about 60 to about 75 parts of mineral oil and from about 10 to about 25 parts of coupling agent, all parts expressed on a weight basis.

10. The insulated electrical device of claim 1 wherein said cured, cross-linked, mineral oil extended polyurethane comprises from about 20 to about 45 parts of polyurethane, from about 25 to about 60 parts of mineral oil and from about 25 to about 35 parts of coupling agent, all parts expressed on a weight basis.

11. An insulated electrical device containing a plurality of insulated wire conductors, said device having interior spaces between the insulated wire conductors which contain a cured, cross-linked, mineral oil extended polyurethane which is non-spewing and which comprises from about 8 to about 45 parts of polyurethane, from about 25 to about 75 parts of mineral oil and from about 10 to about 35 parts of coupling agent, all parts expressed on a weight basis, wherein the cured, cross-linked, mineral oil extended polyurethane is characterized by the presence of a polybutadiene moiety in the polyurethane structure and is prepared from a mineral oil extended polyurethane precursor in admixture with a coupling agent and wherein said coupling agent is characterized by:

(a) having a solubility parameter between 7.9 and 9.5;

(b) having a hydrogen bonding index number in the range of from 6.0 to 12.0;

(c) being miscible in all proportions with said mineral oil; and

(d) being non-reactive with said polyurethane precursor.

12. The insulated electrical device of claim 11 wherein the polybutadiene moiety is derived from at least one member selected from the group consisting of hydroxyl bearing homopolymers of butadiene and hydroxyl bearing copolymers of butadiene and styrene.

13. The insulated electrical device of claim 11 wherein said coupling agent is further characterized by having a boiling temperature above 220°

F.