Reference electrode

• US 4,177,126 A
• Filed: 06/20/1978
• Issued: 12/04/1979
• Est. Priority Date: 06/20/1977
• Status: Expired due to Term

• Current Assignee: Horiba Limited
• Original Assignee: Horiba Limited
• Inventors: Usui, Seiji, Hagiwara, Hidehiko, Imaki, Masakatu
• Primary Examiner(s): Tung, T.
• Application Number:
  US05/917,352
• Time in Patent Office: 532 Days
• Field of Search: 204/195 F
• US Class Current: 204/435
• CPC Class Codes: G01N 27/301 Reference electrodes
• CPC Class Codes: G01N 27/401 Salt-bridge leaks; Liquid junctions

Abstract

A reference electrode includes a holder member having therein a chamber. An inner electrode is positioned within the chamber, the inner electrode being connected to an electric lead extending through an upper end of the holder member. The holder member has a lower end which is closed by a liquid junction in the form of a hydrophilic polypropylene membrane coated with a surface active agent. The membrane has an integral flange which fits around the lower end of the holder member, and the membrane is readily selectively removable from the lower end of the holder member.

Claims

1. A reference electrode for use in testing or measuring serum or blood samples, said reference electrode comprising:

a cylindrical holder member including a cylindrical upper holder having upper and lower ends and a cylindrical lower holder having upper and lower ends, said lower end of said upper holder and said upper end of said lower holder being joined by meshing screw threads;

said lower holder having an interior forming a chamber for containing a reference liquid;

an inner electrode positioned within said chamber, said inner electrode being connected to an electric lead extending through said upper end of said upper holder;

means for spporting said inner electrode within said chamber and for sealing said chamber adjacent said upper end of said lower holder;

a liquid junction comprising a hydrophilic polypropylene membrane coated with a surface active agent, said membrane including a flat portion abutted against and closing said lower end of said lower holder and a tubular flange portion integral with and extending from said flat portion, said tubular flange portion fitting about an exterior surface adjacent said lower end of said lower holder; and

a removable push ring surrounding said tubular flange portion and pressing said tubular flange portion tightly against said exterior surface.

2. A reference electrode as claimed in claim 1, further comprising a cap removably attached to an exterior portion of said lower holder adjacent said lower end thereof, said cap having therein an opening confronting that portion of said flat portion of said membrane which forms said liquid junction.

3. A reference electrode as claimed in claim 1, wherein said lower holder has formed therein adjacent said upper end thereof, an inner seat, and said supporting and sealing means comprises a resilient bushing supported on said seat, a ring mounted on said bushing, and an electrode tube extending through said bushing and said ring, said electrode being positioned within said electrode tube, said electrode tube having embedded therein a portion of said electric lead, and said lower end of said upper holder pressing said ring against said bushing, such that said bushing presses against said seat and said electrode tube.