Resin-metal-ligand composition

• US 4,179,402 A
• Filed: 05/15/1978
• Issued: 12/18/1979
• Est. Priority Date: 05/15/1978
• Status: Expired due to Term

• Current Assignee: Shell Oil Company (Shell Plc)
• Original Assignee: Shell Oil Company (Shell Plc)
• Inventors: Kim, Leo, Paxson, Timm E., Tang, Sunny C.
• Primary Examiner(s): Garvin, Patrick
• Application Number:
  US05/905,813
• Time in Patent Office: 582 Days
• Field of Search: 252/429 R, 252/431 R, 252/431 C, 252/431 N, 252/431 P
• US Class Current: 502/159
• CPC Class Codes: B01J 2231/20 Olefin oligomerisation or telomerisation
• CPC Class Codes: B01J 2231/321 Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
• CPC Class Codes: B01J 2531/821 Ruthenium
• CPC Class Codes: B01J 2531/822 Rhodium
• CPC Class Codes: B01J 2531/824 Palladium
• CPC Class Codes: B01J 2531/828 Platinum
• CPC Class Codes: B01J 2531/845 Cobalt
• CPC Class Codes: B01J 31/08 Ion-exchange resins
• CPC Class Codes: B01J 31/165 Polymer immobilised coordination complexes, e.g. organometallic complexes
• CPC Class Codes: B01J 31/18 containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms double metal cyanides B01J27/26; N-heterocyclic carbenes B01J31/2265
• CPC Class Codes: C07C 1/063 the organic compound being the catalyst or a part of the catalyst system
• CPC Class Codes: C07C 2531/08 Ion-exchange resins
• CPC Class Codes: C07C 2531/22 Organic complexes
• CPC Class Codes: C07C 45/50 by oxo-reactions
• CPC Class Codes: C07C 47/43 with a seven- to twelve-membered ring
• CPC Class Codes: C07C 6/04 at a carbon-to-carbon double bond

Abstract

A composition comprising an ion exchange resin, a metal selected from the transition group of elements bound to said resin and an organic linking compound which has at least one moiety which is ionically bonded to said resin and which further has at least one moiety which is coordinately bonded to said metal.

Claims

1. A composition comprising:

(a) an ion exchange resin having a strongly acidic, weakly acidic, or mixed acid-base type functional group;

(b) an element, selected from the transition group of elements and which is directly bonded either coordinately or ionically to the ion exchange resin; and

(c) an organic linking compound of from 1 to about 100 carbon atoms which has at least one moiety selected from the group consisting of trivalent nitrogen, trivalent phosphorus, trivalent arsenic, trivalent bismuth and trivalent antimony which is coordinately bonded to said element and further has at least one moiety selected from the group consisting of monohydrocarboyl ammonium, dihydrocarbyl ammonium, trihydrocarbyl ammonium, quaternary ammonium, pyridinium, phosphinium, arsenium and sulfonium ion which is ionically bonded to the ion exchange resin.

3. The composition of claim 1 wherein the functional group of the ion exchange resin is selected from the group consisting of sulfonic acid, fluorinated alkyl sulfonic acid, phosphonic acid, carboxylic acid and aminocarboxylic acid, the ionically bonded moiety is selected from the group consisting of monohydrocarbyl ammonium, dihydrocarbyl ammonium, trihydrocarbyl ammonium, quaternary ammonium, pydridinium and phosphonium, the coordinately bonded moiety contains a heteroatom selected from the group consisting of trivalent nitrogen and trivalent phosphorus and the metal is selected from Group VIB, VIIB, VIII, and IB.

4. The composition of claim 3 wherein the ion exchange resin has a backbone selected from the group consisting of polymerized styrene, styrene-divinylbenzene, phenol-formaldehyde, benzene-formaldehyde, acrylic acid and methacrylic acid.

7. The composition of claim 1 wherein the element is selected from the group consisting of cobalt, ruthenium, molybdenum, tungsten, tin, platinum, palladium and rhodium.

8. The composition of claim 3 wherein the element is selected from the group consisting of cobalt, ruthenium, molybdenum, tungsten, tin, platinum, palladium and rhodium.

2. A composition comprising:

(a) an ion exchange resin having a basic-type functional group,

(b) an element selected from the transition group of elements and which is directly bonded either coordinately or ionically to the ion exchange resin; and

(c) an organic linking compound of from 1 to about 100 carbon atoms which has at least one moiety containing a heteroatom selected from the group consisting of trivalent nitrogen, trivalent phosphorus, trivalent arsenic, trivalent bismuth and trivalent antimony which is coordinately bonded to said element and further has at least one moiety derived from the group consisting of carboxylic acid, phosphonic acid, phosphinic acid, sulfenic acid, sulfinic acid, sulfonic acid, boronic acid and boronous acid which is ionically bonded to the ion exchange resin.

5. The composition of claim 2 wherein the functional group of the ion exchange resin is selected from the group consisting of primary, secondary, tertiary, quaternary amine and pyridinium, the ionically bonded moiety is selected from the group consisting of trivalent nitrogen and trivalent phosphorus and the metal is selected from Group VIB, VIIB, VIII and IB.

6. The composition of claim 5 wherein the ion exchange resin has a backbone selected from the group consisting of polymerized styrene, styrene-divinylbenzene, phenol-formaldehyde, benzene-formaldehyde, epoxypolyamine and phenolic-polyamine.

9. The composition of claim 2 wherein the element is selected from the group consisting of cobalt, ruthenium, molybdenum, tungsten, tin, platinum, palladium and rhodium.