Fibers, yarns and fabrics of low modulus polymer

• US 4,181,762 A
• Filed: 03/05/1979
• Issued: 01/01/1980
• Est. Priority Date: 03/10/1976
• Status: Expired due to Term

• Current Assignee: Brunswick Corporation
• Original Assignee: Brunswick Corporation
• Inventors: Benedyk, Joseph C.
• Primary Examiner(s): Kendell, Lorraine T.
• Application Number:
  US06/017,465
• Time in Patent Office: 302 Days
• Field of Search: 428/85, 428/92, 428/95, 428/97, 428/87, 428/93, 428/96, 428/921, 428/364, 428/394, 428/401, 428/372, 57/243, 57/246, 526/331
• US Class Current: 428/97
• CPC Class Codes: D01F 6/02 from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
• CPC Class Codes: D01F 6/28 from copolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
• CPC Class Codes: D01F 6/30 comprising olefins as the major constituent
• CPC Class Codes: D01F 6/44 from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds
• CPC Class Codes: D02G 3/445 Yarns or threads for use in floor fabrics floor fabrics A47G27/00; floor coverings on textile basis D06N7/0005
• CPC Class Codes: D10B 2503/04 Floor or wall coverings; Carpets
• CPC Class Codes: Y10S 428/921 Fire or flameproofing
• CPC Class Codes: Y10T 428/23921 With particles
• CPC Class Codes: Y10T 428/23957 Particular shape or structure of pile
• CPC Class Codes: Y10T 428/23964 U-, V-, or W-shaped or continuous strand, filamentary material
• CPC Class Codes: Y10T 428/23979 Particular backing structure or composition
• CPC Class Codes: Y10T 428/23986 With coating, impregnation, or bond
• CPC Class Codes: Y10T 428/23993 Composition of pile or adhesive
• CPC Class Codes: Y10T 428/2913 Rod, strand, filament or fiber
• CPC Class Codes: Y10T 428/2927 including structurally defined particulate matter

Abstract

Fibers, yarns and fabrics are produced from polymers, such as the copolymers of ethylene and vinyl acetate, having an elastic modulus of from 5,000 to 60,000 psi. The fibers are also characterized by an area moment of inertia of from 400×10^-14 to 7,000×10^-14 in⁴ and a stiffness parameter of from 1×10^-5 to 1×10^-8 lb-in². Multiple fibers are spun into yarn, preferably cross-linked either chemically or by irradiation and are formed into pile fabrics for carpeting and similar uses. The pile fabric preferably has a minimum of 4,000 fibers per in² of backing and a minimum pile height of 1/8 inch.

Claims

1. A monofilament fiber of polymeric material characterized by:

(a) an elastic modulus of from 5,000 to 60,000 psi,

(b) an area moment of inertia of from 400×

10^-14 to 7,000×

10^-14 in⁴, and

(c) a stiffness parameter of from 1×

10^-5 to 1×

10^-8 lb-in².

2. The fiber of claim 1 where the polymeric material is a thermoplastic.

3. The fiber of claim 2 where the thermoplastic is (a) plasticized polyvinyl chloride, (b) low density polyethylene, (c) thermoplastic rubber, (d) ethylene-ethyl acrylate copolymer, (e) ethylene-butylene copolymer, (f) polybutylene and copolymers thereof, (g) ethylene-propylene copolymers, (h) chlorinated polypropylene, (i) chlorinated polybutylene, or (j) mixtures of these thermoplastics.

4. The fiber of claim 3 having dispersed therein one or more additives of the group consisting of colorants, fillers, flame retardants, antistatic agents and antisoiling agents.

5. The fiber of claim 4 wherein said thermoplastic is partially cross-linked.

6. The fiber of claim 5 wherein said fibers are partially cross-linked by irradiation and wherein at least one of said additives acts to enhance the radiation cross-linking thereof.

7. The fiber of claim 6 wherein said cross-linking enhancing additive is selected from the group consisting of silicon oxide, titanium dioxide and triallyl cyanurate.

8. The fiber of claim 4 wherein the weight percentage of additives in the fiber ranges from 0.5 to 20 percent.

9. The fiber of claim 8 wherein said colorant additive is a pigment having a particle size ranging from about 1 to about 25 microns.

10. The fiber of claim 8 wherein said flame retardant additive is hydrated magnesia.

11. The fiber of claim 3 having a generally circular cross-section with a diameter ranging from 3 to 6 mils.

12. The fiber of claim 3 further characterized in not permanently deforming in tension more than 10 percent at elongations up to 25 percent at strain rates in the range of 5 to 50 min^-1, said fiber also having an ultimate tensile strength of greater than 5,000 psi.

13. The fiber of claim 1 wherein said polymeric material comprises an ethylene-vinyl acetate copolymer having a vinyl acetate content of 1 to 10 percent and a melt index in the range of 0.5 to 9.

14. The fiber of claim 13 wherein said ethylene-vinyl acetate copolymer is partially cross-linked.

15. The fiber of claim 14 wherein cross-linking is accomplished by incorporating into the polymer a peroxy activator and a cross-linking agent.

16. The fiber of claim 14 wherein cross-linking is accomplished by irradiation.

17. The fiber of claim 16 wherein an additive selected from the group consisting of silicon dioxide, titanium dioxide, triallyl cyanurate and mixtures thereof is dispersed therein, said additive acting to enhance the radiation cross-linking of said copolymer.

18. The fiber of claim 17 cross-linked to the extent of having a gel content greater than 30% but less than 90%.

19. The fiber of claim 14 having dispersed therein one or more additives of the group consisting of colorants, fillers, flame retardants, antistatic agents and antisoiling agents.

20. The fiber of claim 19 wherein the weight percentage of additives in the fiber ranges from 0.5 to 20 percent.

21. The fiber of claim 20 including a flame retardant additive comprising hydrated magnesia.

22. The fiber of claim 20 including a colorant additive comprising a pigment having a particle size ranging from about 1 to about 25 microns.

23. The fiber of claim 20 having a generally circular cross-section with a diameter ranging from 3 to 6 mils.

24. The fiber of claim 20 further characterized in not permanently deforming in tension more than 10 percent at elongations up to 25 percent at strain rates in the range of 5 to 50 min^-1, said fiber also having an ultimate tensile strength in excess of 5,000 psi.

57. The fabric of claim 56 wherein said staple fibers comprise the fiber of claim 1.

25. Yarn comprising a continuous strand of multiple monofilament fibers of polymeric material, said polymeric material characterized by:

(a) an elastic modulus of from 5,000 to 60,000 psi,

(b) an area moment of inertia of from 400×

10^-14 to 7,000×

10^-14 in ⁴, and

(c) a stiffness parameter of from 1×

10^-5 to 1×

10^-8 lb-in².

26. The yarn of claim 25 containing 15 to 50 fibers, said fibers twisted together and bulked to form a carpet yarn.

27. The yarn of claim 26 having from 0.5 to 2.0 twists per linear inch.

28. The yarn of claim 26 having a denier ranging from 1,500 to 4,000.

29. The yarn of claim 26 wherein each fiber has a generally circular cross-section with a diameter ranging from 3 to 6 mils.

30. The yarn of claim 26 wherein said fibers are pigmented.

31. The yarn of claim 26 wherein said fibers have a melting point above 200°

F.

32. The yarn of claim 26 wherein said fibers comprise a partially cross-linked, ethylene-vinyl acetate copolymer having a vinyl acetate content of 1 to 10 percent and a melt index in the range of 0.5 to 9.0.

33. The yarn of claim 26 wherein said yarn is bulked by knitting and thereafter deknitting.

34. A pile fabric comprising a backing and yarns secured to the backing and extending outwardly therefrom, the yarns comprising a strand of multiple monofilament fibers of polymeric material, said polymeric material characterized by an elastic modulus of from 5,000 to 60,000 psi, an area moment of inertia of from 400×

10^-14 to 7,000×

10^-14 in⁴, and a stiffness parameter of from 1×

10^-5 to 1×

10^-8 lb-in².

35. The fabric of claim 34 when said yarn forms a pile which has a minimum height of 1/8 inch and a minimum density of 4,000 monofilaments per square inch of backing.

36. The pile fabric of claim 34 where the monofilaments have an ultimate tensile strength of from about 5,000 to about 50,000 psi.

37. The pile fabric of claim 34 where the molecules of the polymeric material are partially cross-linked.

38. The fabric of claim 34 where said polymeric material contains additives which enhance the radiation cross-linking thereof.

39. The fabric of claim 34 where the polymeric material has dispersed therein one or more additives of the group consisting of colorants, fillers, flame retardants, antistatic agents and antisoiling agents.

40. The fabric of claim 39 where the weight percentage of additives in the yarn based on total yarn weight ranges from 0.5 to 20 percent.

41. The fabric of claim 39 where the polymeric material contains hydrated magnesia therein.

42. The fabric of claim 34 where each filament has a generally circular cross-section whose diameter is from 3 to 6 mils and does not permanently deform in tension more than 10 percent at elongations up to 25 percent at strain rates in the range of from 5 to 50 min^-1, and has an ultimate tensile strength of from about 5,000 to about 50,000 psi.

43. The fabric of claim 34 where the monofilaments are irradiated.

44. The fabric of claim 34 where said polymeric material comprises an ethylene-vinyl acetate copolymer having a vinyl acetate content of from 1 to 10 percent by weight and a melt index of from 0.5 to 9.

45. The fabric of claim 44 where the monofilaments have an ultimate tensile strength of from about 5,000 to about 50,000 psi.

46. The fabric of claim 44 where the copolymer has dispersed therein one or more additives of the group consisting of colorants, fillers, flame retardants, antistatic agents and antisoiling agents.

47. The fabric of claim 44 where the molecules of the ethylene-vinyl acetate polymer are partially cross-linked.

48. The fabric of claim 44 where said ethylene-vinyl acetate copolymer contains an additive which enhances radiation cross-linking.

49. The fabric of claim 48 wherein the additive consists of less than 1% by volume of fine particles of silicon dioxide ranging in size from about 100 angstroms to about 1 micron.

50. The fabric of claim 48 wherein the additive consists of fine particles of titanium dioxide ranging in size from about 100 angstroms to about 1 micron.

51. The fabric of claim 44 where the monofilaments are colored by pigments having a particle size of from about 1 to about 26 microns dispersed throughout the copolymer material.

52. The fabric of claim 51 where the weight percentage of pigments based on total yarn weight ranges from about 0.5 to about 20 percent.

53. The fabric of claim 44 where the copolymer material contains hydrated magnesia.

54. The fabric of claim 44 where each filament has a generally circular cross-section whose diameter is from 3 to 6 mils.

55. The fabric of claim 54 where each filament does not permanently deform in tension more than 10 percent at elongations up to 25 percent at strain rates in the range of from 5 to 50 min^-1 and has an ultimate tensile strength of from about 5,000 to about 50,000 psi.

56. The pile fabric of claim 34 wherein said backing comprises a scrim having needled thereto a web of staple fibers.

58. The fabric of claim 34 wherein said pile is formed by yarn tufts extending at least 1/8 inch from the backing and forming a fabric face.

59. The fabric of claim 58 wherein said tufts are yarn loops.

60. The fabric of claim 59 wherein the spacing of the yarn loops on the backing is uniform.

61. The fabric of claim 34 including a secondary backing layer secured to said fabric.

62. The fabric of claim 58 including a backsizing coating, said coating serving to lock each yarn tuft into the fabric backing.

63. The fabric of claim 62 wherein said backsizing coating comprises a latex adhesive.