Flame retardant compositions

• US 4,185,008 A
• Filed: 10/10/1978
• Issued: 01/22/1980
• Est. Priority Date: 10/10/1978
• Status: Expired due to Term

• Current Assignee: Standard Oil Company (BP PLC)
• Original Assignee: Standard Oil Company (BP PLC)
• Inventors: Poppe, Wassily, Caspari, Gunter
• Primary Examiner(s): Hoke, V. P.
• Application Number:
  US05/949,654
• Time in Patent Office: 469 Days
• Field of Search: 260/45.9 E, 260/45.7 RL, 260/45.8 A, 260/45.75 W
• US Class Current: 524/429
• CPC Class Codes: C08K 3/28 Nitrogen-containing compounds
• CPC Class Codes: C08K 5/02 Halogenated hydrocarbons C08K5/0091 takes precedence
• CPC Class Codes: C08K 5/09 Carboxylic acids; Metal salts thereof; Anhydrides thereof
• CPC Class Codes: C08L 67/02 Polyesters derived from dicarboxylic acids and dihydroxy compounds C08L67/06 takes precedence

Abstract

This invention relates to thermoplastic resin compositions having improved oxygen index values comprising a thermoplastic resin, a nitrate containing compound and a halogenated organic compound.

Claims

1. A composition comprising:

(a) a thermoplastic polymer and at least one primary flame retardant consisting of a chlorine or bromine containing organic compound;

(b) a secondary flame retardant agent in an amount sufficient to give an improved oxygen index, said agent comprising;

about 0.05 to about 15 weight percent of one or more nitrate containing compounds selected from the group consisting of sodium nitrate, ammonium nitrate, metal ammine nitrates and guanidine nitrates.

2. The composition of claim 1 wherein said thermoplastic polymer is an addition polymer.

3. The composition of claim 2 wherein said addition polymer is a resinous polymer of propylene.

4. The composition of claim 2 wherein said nitrate is sodium nitrate or ammonium nitrate.

5. The composition of claim 1 wherein said thermoplastic polymer is a poly(alkylene terephthalate).

6. The composition of claim 5 wherein said poly(alkylene terephthalate) contains up to 20 weight percent isophthalic acid.

7. The composition of claim 5 wherein said poly(alkylene terephthalate) is poly(ethylene terephthalate) or poly(butylene terephthalate).

8. The composition of claim 5 wherein said nitrate is sodium nitrate or ammonium nitrate.

9. A composition comprising a resinous polymer of propylene, 2.0 to 20 parts by weight tetrabromophthalic anhydride, and 0.1 to 3.0 parts by weight ammonium nitrate.

10. A composition comprising a resinous polymer of styrene, 2 to 20 parts by weight tetrabromophthalic anhydride, and 0.1 to 3 parts by weight ammonium nitrate.

11. A composition comprising a resinous homopoly(butylene terephthalate), 2 to 20 parts by weight tetrabromophthalic anhydride and 0.1 to 3 parts by weight ammonium nitrate.