Process of making high-temperature magnetic tape

• US 4,189,514 A
• Filed: 03/17/1978
• Issued: 02/19/1980
• Est. Priority Date: 03/17/1978
• Status: Expired due to Term

• Current Assignee: Emag, LLC
• Original Assignee: Graham Magnetics, Inc.
• Inventors: Johnson, Robert A.
• Primary Examiner(s): Robinson, Ellis P.
• Application Number:
  US05/887,545
• Time in Patent Office: 704 Days
• Field of Search: 428/539, 428/900, 428/906, 428/922, 428/331, 428/425, 428/447, 428/411, 428/538, 360/134, 427/131, 427/128
• US Class Current: 428/331
• CPC Class Codes: G11B 5/7358 specially adapted for achieving a specific property, e.g. average roughness [Ra]
• CPC Class Codes: Y10S 428/90 Magnetic feature
• CPC Class Codes: Y10S 428/906 Roll or coil
• CPC Class Codes: Y10S 428/922 Static electricity metal bleed-off metallic stock
• CPC Class Codes: Y10T 428/259 Silicic material
• CPC Class Codes: Y10T 428/31504 Composite [nonstructural laminate]
• CPC Class Codes: Y10T 428/31609 Particulate metal or metal compound-containing
• CPC Class Codes: Y10T 428/31663 As siloxane, silicone or silane

Abstract

An improved, conventionally-spoolable, magnetic tape which can be unspooled and read after exposure to very high temperatures. The improvement is largely in a thermally resistant, non-adhering, anti-static backing system, used in conjunction with magnetic face coatings.

Claims

1. In a helically-spoolable magnetic tape comprising a substrate, a magnetic recording medium of the type comprising magnetic particles in an organic resin matrix on one face of the said substrate, and anti-static coating on the reverse side of said substrate, the improvement wherein said anti-static coating is formed with a thoroughly crosslinked organic resin binder system containing at least 50% prepolymerized polyester-type polyurethane, and comprising dispersed within said binder an effective quantity of a conductive filler from about 10 to 30% by weight of pyrogenic silica and from about 0.5 to about 3% of a silicone-oil based lubricant such weights based on the weight of organic resin binder, said anti-static coating forming an interface with said magnetic recording medium, said interface providing a means to allow unspooling of the spooled tape without any substantial damage thereto after exposure of the tape to elevated temperature.

2. A magnetic tape as defined in claim 1 wherein the resin component of said organic binder in said anti-static coating comprises about 5 to 15% of phenoxy resin.

5. A magnetic tape as defined in claim 1 wherein said tape is characterized by resistance to high temperature degradation, remains unwindable and readable after subjection, in spooled form, to an environment of 400°

F. for one hour.

3. In a magnetic tape of the type comprising a substrate, an anti-static backing coat, and a face coat comprising ferromagnetic particles in an prepolymerized polyesterurethane resin coating, the improvement wherein said anti-static backing comprises, in addition to a pre-polymerized polyurethane based binder system and a primary filler forming means to dissipate static electricity, (1) a silicone-oil based lubricant and (2) an effective quantity of pyrogenic silica forming means to absorb any excessive lubricant and limit the migration thereof to the surface of said coating said anti-static backing coat forming an interface with said face coat, said interface providing means to allow release of said backing coat from said face coat after exposure to elevated temperatures.

4. A magnetic tape as defined in claim 3 wherein said primary filler is a carbon black and said pyrogenic silica forms means to aid spatial distribution of said carbon black within said anti-static coating.

6. A magnetic tape as defined in claim 3 wherein said tape is characterized by resistance to high temperature degradation, remains unwindable and magnetically readable after being subject, in spooled form, to an environment of 400°

F. for one hour.