Fire protective mastic and fire stop

• US 4,189,619 A
• Filed: 01/27/1978
• Issued: 02/19/1980
• Est. Priority Date: 01/27/1978
• Status: Expired due to Term

• Current Assignee: International Protective Coatings Corp. (WR Grace & Company)
• Original Assignee: Pedlow J. Watson
• Inventors: Pedlow, J. Watson
• Primary Examiner(s): Dixon, Jr., William R.
• Application Number:
  US05/872,820
• Time in Patent Office: 753 Days
• Field of Search: 169/48, 106/15 FP, 106/18.11, 106/18.12, 106/18.27, 106/18.28, 106/18.36, 252/5, 260/DIG. 24, 521/84, 521/85, 521/91, 521/907, 174/48, 174/121 A, 428/325, 428/494, 428/500, 428/538, 428/539, 428/921
• US Class Current: 174/505
• CPC Class Codes: C09D 5/185 Intumescent paints
• CPC Class Codes: C09D 5/34 Filling pastes materials for sealing or packing joints or covers C09K3/10; materials for stopping leaks C09K3/12
• CPC Class Codes: H02G 3/0412 Heat or fire protective means for fire in electric circuits A62C3/16
• CPC Class Codes: H02G 3/22 Installations of cables or lines through walls, floors or ceilings, e.g. into buildings
• CPC Class Codes: Y10S 260/24 Flameproof
• CPC Class Codes: Y10S 428/921 Fire or flameproofing
• CPC Class Codes: Y10S 521/907 Nonurethane flameproofed cellular product
• CPC Class Codes: Y10T 428/252 Glass or ceramic [i.e., fired or glazed clay, cement, etc.] [porcelain, quartz, etc.]
• CPC Class Codes: Y10T 428/31833 Next to aldehyde or ketone condensation product or addition polymer from unsaturated monomers
• CPC Class Codes: Y10T 428/31855 Of addition polymer from unsaturated monomers

Abstract

A fire protective mastic is provided, whose essential components are solids including a low fusing ceramic frit, hydrated solids having chemically bonded water which is released as a fire protective water vapor when heated, solids which expand or intumesce during the same heat application to form a porous, expanded or foamy insulating body, solids which have a fire break effect, such as antimony oxide and zinc tetraborate, and binder solids which are thermoplastic resins and serve to bind the solids into a flexible coating when applied, the binder solids being dispersed as an emulsion in water and mixed with the other solids to form a mastic. With further addition of water it is converted to a selected viscosity for application by troweling, coating or spraying. The mastic is applied as a coating or a precast boot upon single or grouped electric power and control cables to restrict fire propagation and to prevent self ignition of cables from fires due to overloading or other electrical faults, or from oil, waste or trash fire sources. The mastic is further usefully shaped into fire protective panels the latter of which, when dried, can be mounted as a protective wall insulating a section of cables passing from area to area as a fire stop. The total panel can be formed of the dried mastic, or the mastic can be coated upon one or both sides of insulating panels such as ceramic fiber boards, to further reduce the temperature gradient through the panel upon fire exposure and thus appreciably reduce the temperature on the cold side by 50°-70° F., thereby minimizing the danger of self ignition of gases or combustible materials such as cable jacketing, insulation or other flammable materials.

Claims

1. Fire protective heat insulating mastic for coating upon electrical cables and for forming or coating upon fire protective panels to be mounted in neighboring structures near electrical cables, said mastic comprising an essentially halogen-free mixture of solids and thermoplastic binder resins dispersed as an emulsion in water, said solids including heat intumescing and expanding substances in approximate quantity of 4 to 25% to expand the mastic to porous heat insulating form, ceramic frits in approximate quantity of 5 to 40% to provide a ceramic glaze upon the surface of the dry expanded mastic when exposed to high temperatures developed by fire, hydrated substances in approximate quantity of 10 to 40% and having bonded water evolvable only by application of sufficient heat to decompose and evolve water vapors, fire protective solids of the character of antimony oxide and zinc borate activated by the heat of a fire to a fire protective form in approximate quantity of each of about 2 to 15%, and a resinous thermoplastic binder in approximate quantity of 5 to 40% to bind said solids to a flexible film in coated form of the mastic, said binder being dispersed as an emulsion in water, there being sufficient water in the emulsion to convert said solids into a fluidized form for application as a coating upon said cables and panels, said percentages being by weight, the said solids quantity being based on the total solids of the composition.

2. The mastic composition as defined in claim 1, said mastic further containing a small quantity, less than about 5% of organic fiber said composition further containing from about 1 to 10% of emulsifying agents, rust inhibitors, fungicides, viscosity controlling and thickening agents.

3. The fire retardant mastic as defined in claim 1, wherein the binder resin solids are in the range of 20 to 30%, dispersed in water, being substantially 45 to 65% resin solids and 55 to 35% water, the low fusible solids are ceramic frits in quantity of 10 to 25%, the hydrated substances are hydrous oxides in the range of 15 to 30%, the intumescing and expanding substances are cenospheres in the range of 7-25%, said mastic further containing a small quantity of about 0.5 to 2.0% of organic fiber, and the fire retardant antimony oxide and zinc tetraborate are each present in quantity of 4 to 10% and 5 to 10% respectively.

4. The mastic composition of claim 1, wherein said resin binder is an emulsion of a member of the group consisting of polyvinyl acetate, polyethylacrylate, polyloweralkylacrylate, polyloweralkylmethacrylate, polyacrylic acid, polymethacrylic acid and mixtures of said acrylate resins, rubber latices dispersed in water, the dispersion being 45 to 65% of said resinous solids and the remainder substantially water.

5. The mastic as defined in claim 1, wherein the intumescing solids are cenospheres, the ceramic fusible frit is substantially borosilicate glass and the hydrated substance is a member of the group consisting of hydrous alumina and hydrous magnesia.

6. A fire stop panel comprising a moulded board formed of the dried mastic as defined in claim 1.

7. A fire protected electrical cable having a heat insulating coating of a mastic as defined in claim 1.

8. A fire protective panel, comprising a heat insulating board having an outer coating of a mastic as defined in claim 1.

9. A fire stop comprising a wall through which electric cables pass in groups, said cables being disposed as separated cables in trays and passing through an opening in said wall, each of the cables in said trays being surrounded and separated by a dry coating of a fire protective mastic as defined in claim 1 the wall being closed about said cables by fire resistant panels filling said opening and shaped to fit about the cables and trays passing therethrough, the crevices and cracks between panels, trays and cables being filled with said mastic.

10. The fire stop as defined in claim 9, wherein said panels comprise an essentially halogen-free mixture of solids and thermoplastic binder resins dispersed as an emulsion in water, said solids including heat intumescing and expanding substances in approximate quantity of 4 to 25% to expand the mastic to porous heat insulating form, ceramic fusible frits in approximate quantity of 5 to 40% to provide a ceramic glaze upon the surface of the dry expanded mastic when exposed to high temperatures developed by fire, hydrated substances in approximate quantity of 10 to 40% and having bonded water evolable only by application of sufficient heat to decompose and evolve water vapors, fire protective solids of the character of antimony oxide and zinc borate activated by the heat of a fire to a fire protective form in approximate quantity of each of about 2 to 15%, and a resinous thermoplastic binder in approximate quantity of 5 to 40% to bind said solids to a flexible film in coated form of the mastic, said binder being dispersed as an emulsion in water, there being sufficient water in the emulsion to convert said solids into a fluidized form for application as a coating upon said cables and panels, said percentages being by weight, the said solids quantity being based on the total solids of the composition.

11. The fire stop as defined in claim 10, wherein the panels are a laminate having an outer laminar coating of said mastic.

12. An insulated electrical cable having an outer coating of a fire protective mastic as defined in claim 1.

13. A plurality of insulated electrical cables, each separated from the other embedded in a dried mastic as defined in claim 1.

14. A plurality cables embedded in dried mastic as defined in claim 1, said mastic being further encased in a sleeve.

15. A fire protective panel formed of molded dried mastic composition as defined in claim 1.