Spectrometer

• US 4,193,691 A
• Filed: 05/02/1977
• Issued: 03/18/1980
• Est. Priority Date: 05/02/1977
• Status: Expired due to Term

• Current Assignee: RCA Corporation (General Electric Company)
• Original Assignee: RCA Corporation (General Electric Company)
• Inventors: Fjarlie, Earl J.
• Primary Examiner(s): Bauer, Edward S.
• Application Number:
  US04/792,676
• Time in Patent Office: 1,051 Days
• Field of Search: 356/97, 356/98, 350/331
• US Class Current: 356/330
• CPC Class Codes: G01J 2003/2866 Markers; Calibrating of scan
• CPC Class Codes: G01J 3/0229 using masks, aperture plates, spatial light modulators or spatial filters, e.g. reflective filters
• CPC Class Codes: G01J 3/04 Slit arrangements slit adjustment
• CPC Class Codes: G01J 3/457 Correlation spectrometry, e.g. of the intensity G01J3/453 takes precedence
• CPC Class Codes: G02F 1/1313 specially adapted for a particular application

Abstract

The slit assembly of the present spectrometer comprises a liquid crystal cell. The electrodes of the cell are selectively actuated for producing a pattern of slits appropriate to the spectral lines of interest in the spectrum derived from the substance under analysis.

Claims

1. In a spectrographic analysis system in which a spectrum derived from a sample under test in projected onto a slit assembly, the assembly including slits positioned to pass only those spectral lines of interest in the measurement of the concentration of one of a number of different substances which may be present in the sample, the improvement comprising:

said slit assembly comprising a liquid crystal cell with electrodes at opposite surfaces of the cell for defining the slits in response to voltages applied thereto; and

control means connected to said slit assembly for applying voltages to said electrodes for producing a selected one of a plurality of possible slit patterns, that one pattern being appropriate to the analysis of the particular substance of interest in the sample,

said control means including modulating means for generating a slit modulating signal and for applying said slit modulation signal to a selected group of said slits to generate a modulated selected spectrum for opening the slits at the modulation frequency, and output means including detecting means for detecting said modulated spectrum, and means responsive to said detected modulated spectrum applied as an input thereto for generating said spectrum signal as an output thereof.

2. In the system of claim 1 wherein said control means includes preprogram means connected to said slit assembly for successively selectively applying said voltages to said electrodes in accordance with a given program to successively produce said plurality of slit patterns.

3. In the system of claim 2 further including means for detecting the energy transmitted by said plurality of patterns and for producing an output signal representing the spectra of each said transmitted energy.

4. In the system of claim 1 wherein said slit assembly includes means for orienting said slits parallel and coplanar.

5. In the system of claim 1 wherein said control means includes means for controlling the effective slit width of each slit in said slit patterns.

6. In a spectrographic analysis system for indicating the presence and concentration in a sample under test of any one of a number of different substances, and which includes means for translating radiation which has passed through the sample into a spectrum and means for directing that spectrum onto a slit assembly, an improved such assembly comprising:

a liquid crystal cell comprising a liquid crystal and electrodes at opposite surfaces of said liquid crystal responsive to applied voltages for switching the liquid crystal between clear and opaque optical states, said electrodes defining a pattern of slits; and

means for selectively applying voltages to said electrodes for producing a desired pattern of slits in positions corresponding to the spectral lines of interest in the spectrum being produced by the substance under analysis, said means for selectively applying including modulating means for generating a slit modulating signal and for applying said slit modulation signal to a selected group of said slits to generate a modulated selected spectrum for opening the slits at the modulation frequency, and output means including detecting means for detecting said modulated spectrum, and means responsive to said detected modulated spectrum applied as an input thereto for generating said spectrum signal as an output thereof.

7. The system of claim 6 wherein said means for selectively applying voltages includes means for controlling the effective slit width of said pattern of slits.

8. A spectrometer comprising:

means for producing a spectrum of light,

detector means for producing an output signal in response to said light spectrum incident thereon,

an array of slits disposed between said detector means and said means for producing a spectrum of light, said array of slits being formed of liquid crystal material having first and second light transmission states, said slits transmitting the light incident thereon only when in one of said states, said liquid crystal material being selectively placed in said states in accordance with a plurality of slit control voltages applied thereto,

electronic means connected to said liquid crystal material for generating said control voltages, said control voltates selectively placing a group of said slits in said one state, said electronic means including modulating means for generating a slit modulating signal and for applying said slit modulation signal to a selected group of said slits to generate a modulated selected spectrum for opening the slits at the modulation frequency, and output means including detecting means for detecting said modulated spectrum, and means responsive to said detected modulated spectrum applied as an input thereto for generating said spectrum signal as an output thereof, and

output means responsive to said output signal applied as an input thereto for producing a spectrum signal representing the spectra transmitted by said selected group of slits.

9. The spectrometer of claim 8 wherein said electronic means for generating said slit control voltages including means for successively selectively placing a plurality of separate, different groups of said slits in said one state, and said output means includes means for producing a signal representing the spectra transmitted by each of said plurality of groups of slits.

10. The spectrometer of claim 8 wherein said electronic means including addressing means for selectively energizing said liquid crystal material corresponding to said group of slits in response to an address input signal and means for applying said address input signal to said array addressing means.

11. The spectrometer of claim 10 wherein said array addressing means includes means responsive to a periodic signal having a repetition rate in a given range, said liquid crystal material being responsive to said periodic signal applied thereto for placing said material in said one state, and said means for applying said address input signal to said addressing means includes means for selecting a given repetition rate of said periodic signal and applying said periodic signal recurring at said given repetition rate to said array addressing means.

12. The spectrometer of claim 11 wherein different groups of said slits each correspond to a different predetermined repetition rate of said periodic signal, said means for selecting and applying said periodic signal including means for cyclically selectively applying said periodic signals recurring at said different repetition rates to said array addressing means, said array addressing means including means for applying said periodic signals recurring at said different repetition rates to said liquid crystal material corresponding thereto.

13. The spectrometer of claim 8 wherein said means responsive to said detected modulated spectrum includes signal demodulating means for selectively demodulating said detected signal.

14. The spectrometer of claim 13 wherein said modulating means includes means for generating a plurality of slit modulating signals recurring at different repetition rates, each repetition rate corresponding to a group of slits, said electronic means including preprogrammed means for selectively energizing each group of slits with a corresponding modulating signal of a given repetition rate, said demodulating means including a like plurality of signal demodulators each corresonding to a separate group of slits for producing said spectrum signal representing the spectrum produced by all said groups of slits.