Process for removing mercury from a gas

• US 4,196,173 A
• Filed: 09/29/1978
• Issued: 04/01/1980
• Est. Priority Date: 09/29/1977
• Status: Expired due to Term

• Current Assignee: Akzo Nvv.
• Original Assignee: Akzo Nvv.
• Inventors: deJong, Geert J., Vos, Hendrik J.
• Primary Examiner(s): Thomas, Earl C.
• Application Number:
  US05/946,861
• Time in Patent Office: 550 Days
• Field of Search: 423/210 M, 423/491, 204/99, 55/72, 55/74
• US Class Current: 423/210
• CPC Class Codes: B01D 53/02 by adsorption, e.g. preparative gas chromatography solid sorbent compositions B01J20/00, preparation of inorganic compounds or elements C01
• CPC Class Codes: B01D 53/64 Heavy metals or compounds thereof, e.g. mercury
• CPC Class Codes: C01B 32/342 characterised by non-gaseous activating agents
• CPC Class Codes: C22B 43/00 Obtaining mercury

Abstract

Mercury is removed from gases containing mercury vapor by passing the gases continuously through a bed of activated carbon on which a halogen is adsorbed. The bed may have a thickness of at most 5 cm. The chlorine content of the active carbon is maintained between 5% and 12% by weight. This is preferably effected by adding chlorine to the gases in an amount such that the carbon is caused to absorb a quantity thereof which equals the quantity that is consumed during the adsorption of mercury.

Claims

1. In a process for removing mercury gases containing mercury vapor which comprises contacting these gases with activated carbon on which a halogen is adsorbed, the improvement which comprises flowing a gas to be freed from mercury vapor continuously through a bed of activated carbon having a maximum thickness of 5 cm and having chlorine adsorbed thereon, and maintaining the chlorine content of the activated carbon in the range of from 5 to 12% by weight based on the weight of the carbon during the passage of the gas through the activated carbon bed by continuously or periodically supplying the bed with a replenishing amount of chlorine.

2. The process of claim 1, characterized in that the chlorine content of the activated carbon is kept within said limits by admixing the chlorine to be supplied to the carbon bed with the gas which is to be freed from mercury vapor and then flowing the resulting gas mixture through the bed thereby replacing the chlorine as it is lost during the adsorption of the mercury.

3. The process of claim 2, characterized in that the amount of chlorine admixed with the gas is adjusted so as to have a gas mixture containing 15 to 25 atoms of chlorine per atom of mercury.

4. The process of claim 1, characterized in that the chlorine content of the activated carbon is kept between said limits by periodically contacting the carbon with a chlorine-containing gas.

5. A process for improving the adsorption of mercury vapor by a filter from a gas passing through said filter containing activated carbon having chlorine adsorbed thereon which comprises supplying the activated carbon filter with a replenishing amount of chlorine thereby maintaining the chlorine content of the activated carbon between about 5% and 12% by weight based on the weight of activated carbon.

6. The process of claim 5 wherein the gas from which mercury is removed contains chlorine in an amount which replaces chlorine lost by the filter to maintain the chlorine content at all times within the stated percentages.

7. The process of claim 5 wherein the chlorine content of the activated carbon is maintained between the stated percentages and the mercury adsorption of the filter is not permitted to drop to below 85%.