Method of chemically vapor-depositing a low-stress glass layer

• US 4,196,232 A
• Filed: 12/18/1975
• Issued: 04/01/1980
• Est. Priority Date: 12/18/1975
• Status: Expired due to Term

• Current Assignee: RCA Corporation (General Electric Company)
• Original Assignee: RCA Corporation (General Electric Company)
• Inventors: Fisher, Albert W., Schnable, George L.
• Primary Examiner(s): Hoffman, James R.
• Application Number:
  US05/642,141
• Time in Patent Office: 1,566 Days
• Field of Search: 427/248 C, 427/95
• US Class Current: 427/255.37
• CPC Class Codes: C23C 16/401 containing silicon
• CPC Class Codes: C23C 16/402 Silicon dioxide

Abstract

A method of chemically vapor-depositing a low-stress glass layer onto a substrate which is heated in an atmosphere including silane, oxygen, and an inert carrier gas, comprises the step of adding water vapor to the atmosphere to increase the water vapor content of the atmosphere substantially above that normally present therein from the oxidation of the silane.

Claims

1. In a method of chemically vapor-depositing a glass layer onto a substrate wherein said substrate is heated in an atmosphere comprising silane and oxygen to a temperature such that said silane is oxidized, the improvement in said method comprising the step of adding water vapor to said atmosphere to increase the water vapor content of said atmosphere substantially above that normally present therein from the oxidation of said silane, whereby the tensile stress of said deposited glass layer is reduced.

2. A method as recited in claim 1 wherein the water vapor content in mole percent of said atmosphere is at least two times that normally present from the oxidation of said silane.

3. A method as recited in claim 2 wherein the water vapor content in mole percent of said atmosphere is increased by a factor of about four times that normally present from the oxidation of said silane.

4. A method as recited in claim 3 wherein said deposition temperature is about 350°

C. and said layer of glass is deposited at a rate of about 1750 A per minute.

5. A method as recited in claim 2 wherein the water vapor content in mole percent of said atmosphere is increased by a factor of about seven times that normally present from the oxidation of said silane.

6. A method as recited in claim 5 wherein said deposition temperature is about 350°

C. and said layer of glass is deposited at a rate of about 500 A per minute.

7. A method as recited in claim 2 wherein the water vapor content in mole percent of said atmosphere is increased by a factor of about nine times that normally present from the oxidation of said silane.

8. A method as recited in claim 7 wherein said deposition temperature is about 450°

C. and said layer of glass is deposited at a rate of about 1000 A per minute.

9. A method as recited in claim 8 wherein said substrate is a silicon wafer and wherein said glass layer is silicon dioxide.

10. A method as recited in claim 8 wherein said substrate is a patterned aluminum layer disposed on a silicon wafer and wherein said glass layer is silicon dioxide.

11. A method as recited in claim 8 wherein said substrate is a patterned aluminum layer disposed on a silicon wafer and wherein said glass layer is phosphosilicate glass.

12. A method as recited in claim 2 wherein the water vapor content in mole percent of said atmosphere is increased by a factor of about fifteen times that normally present from the oxidation of said silane.

13. A method as recited in claim 12 wherein said deposition temperature is about 450°

C. and said layer of glass is deposited at a rate of about 350 A per minute.

14. A method as recited in claim 1 wherein the step of adding said water vapor to said atmosphere is performed prior to including said silane in said atmosphere.

15. A method of chemically vapor depositing a glass layer onto a surface of a substrate comprising heating said substrate while contacting said surface with a vaporous mixture comprising silane, oxygen, and water vapor, said water vapor being present in an amount substantially above that normally present therein from the oxidation of said silane, whereby the tensile stress of said deposited glass layer is reduced.

16. A method as recited in claim 15 wherein the water vapor content in mole percent of said vaporous mixture is at least two times that normally present from the oxidation of said silane.