Polymer concrete compositions and cured products thereof

• US 4,197,225 A
• Filed: 12/12/1978
• Issued: 04/08/1980
• Est. Priority Date: 05/19/1976
• Status: Expired due to Term

• Current Assignee: Rohm and Haas Company (Dow, Inc.)
• Original Assignee: Rohm and Haas Company (Dow, Inc.)
• Inventors: Sperry, Peter R., Emmons, William D.
• Primary Examiner(s): Person, Sandra M.
• Application Number:
  US05/968,706
• Time in Patent Office: 483 Days
• Field of Search: 526/282, 260/42.13, 260/42.52, 260/42.53, 260/23 AR
• US Class Current: 524/650
• CPC Class Codes: B27K 3/15 Impregnating involving polymerisation including use of polymer-containing impregnating agents macromolecular compounds derived from lignocellulosic materials C08H; compositions of lignin-containing materials C08L97/02
• CPC Class Codes: C04B 14/02 Granular materials , e.g. microballoons
• CPC Class Codes: C04B 24/045 Esters, e.g. lactones
• CPC Class Codes: C04B 24/2641 Polyacrylates; Polymethacrylates
• CPC Class Codes: C04B 26/06 Acrylates
• CPC Class Codes: C04B 28/02 containing hydraulic cements other than calcium sulfates
• CPC Class Codes: C04B 41/009 characterised by the material treated
• CPC Class Codes: C04B 41/483 Polyacrylates
• CPC Class Codes: C04B 41/63 Macromolecular compounds
• CPC Class Codes: C04B 7/00 Hydraulic cements calcium sulfate cements C04B11/00
• CPC Class Codes: C08L 33/06 of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
• CPC Class Codes: C08L 97/02 Lignocellulosic material, e.g. wood, straw or bagasse manufacture of articles made from lignocellulosic material by dry processes B27N

Abstract

This application concerns compositions comprising a mixture of air-drying dicyclopentenyl acrylate or methacrylate binder and a granular or particulate aggregate material, which may comprise a hydraulic cement, and is adapted to be formed by casting, extruding, or molding in any fashion into any desired shape and air-drying and resulting shaped article, thereby producing an integral, solid article of unitary mass and structure. The dicyclopentenyl (meth)acrylate may be used as an impregnant, polymerizable in situ, for already formed articles of porous nature, e.g., concrete, wood, pressed boards, and powdered pressed metal, such as aluminum, iron, steel, etc., to reduce the permeability at their surfaces and provides hard, continuous, hydrophobic, wear-resistant, and weather-resistant surfaces thereon.

Claims

1. A composition suitable for use as a polymer concrete comprising (a) a granular aggregate having a void fraction of less than 0.37, (b) a liquid selected from dicyclopentenyl acrylate, dicyclopentenyl methacrylate, mixtures thereof, and mixtures of at least one of said (meth)acrylates with up to 40% by weight of another non-volatile monomer, such as a higher alkyl or alkenyl acrylate or methacrylate, and (c) a siccative or drier, the proportion of component (b) being such as to make the composition of workable consistency, and the amount of (c) being from 0.0005 to 2% by weight of component (b).

2. A composition according to claim 1 wherein the aggregate material (a) of the composition comprises (1) a hydraulic cement and (2) other aggregate material, the relative proportions between (1) and (2) being from 1:

100 to 10;

1, preferably from 1;

20 to 3;

1.

3. A product obtained from the casting or molding of the composition of claim 1 or 2 in or on a form and air-curing the cast or molded mass.

4. A composition according to claim 1 or 2 which is essentially anhydrous.

5. A composition according to claim 2 which also contains a small amount of water.

6. A product obtained by casting or molding, and subsequently air-curing the cast or molded mass, a composition according to claim 4.

7. A product obtained by casting or molding, and subsequently air-curing the cast or molded mass, a composition according to claim 5.