Method of providing a polycarbonate article with a uniform and durable organopolysiloxane coating

• US 4,197,335 A
• Filed: 11/13/1978
• Issued: 04/08/1980
• Est. Priority Date: 11/13/1978
• Status: Expired due to Term

• Current Assignee: General Electric Company
• Original Assignee: General Electric Company
• Inventors: Goossens, John C.
• Primary Examiner(s): Hoffman, James R.
• Application Number:
  US05/959,587
• Time in Patent Office: 512 Days
• Field of Search: 427/162, 427/163, 427/164, 427/379, 427/387
• US Class Current: 427/162
• CPC Class Codes: B05D 7/02 to macromolecular substances, e.g. rubber treatment or coating of shaped articles made of macromolecular substances C08J7/00
• CPC Class Codes: C08J 2369/00 Characterised by the use of polycarbonates; Derivatives of polycarbonates
• CPC Class Codes: C08J 2433/08 Homopolymers or copolymers of acrylic acid esters
• CPC Class Codes: C08J 2483/04 Polysiloxanes
• CPC Class Codes: C08J 7/042 with two or more layers, where at least one layer of a composition contains a polymer binder
• CPC Class Codes: C08J 7/043 Improving the adhesiveness of the coatings per se, e.g. forming primers adhesives in the form of films or foils characterised by the primer layers between the polymer carriers and the adhesives C09J7/50
• CPC Class Codes: C08J 7/046 Forming abrasion-resistant coatings; Forming surface-hardening coatings

Abstract

A process for providing a uniform, durable and tenaciously adhered scratch, mar, abrasion and chemical solvent resistant organopolysiloxane coating on a polycarbonate substrate. The process includes (i) applying a priming composition comprising an emulsion of a thermosettable acrylic polymer and a hydroxy ether to a polycarbonate substrate; (ii) curing the thermosettable acrylic polymer thereby forming a thermoset acrylic primer layer on said substrate; (iii) applying a top coat composition containing a further curable organopolysiloxane onto said primed substrate; and (iv) curing said further curable organopolysiloxane.

Claims

1. A method of producing a polycarbonate article having improved mar, abrasion, scratch and chemical solvent resistance comprising the steps of:

(i) applying onto a polycarbonate substrate a primer emulsion composition containing, in percent by weight, (a) from about 1 to about 10 percent of a thermosettable acrylic polymer, (b) from about 20 to about 45% of a hydroxy ether, and (c) from about 45 to about 79 percent of water;

(ii) evaporating off a substantial portion of said water and hydroxy ether from said primer emulsion composition to form a substantially solid layer comprised of thermosettable acrylic polymer;

(iii) thermally curing said thermosettable acrylic polymer to form a thermoset acrylic primer layer;

(iv) applying onto said cured primer layer a top coat composition comprised of a further curable organopolysiloxane;

(v) evaporating off a substantial portion of any solvents present in said top coat composition thereby forming a layer comprised of further curable organopolysiloxane; and

(vi) curing said further curable organopolysiloxane thereby forming a cured organopolysiloxane top coat.

2. A method of claim 1 wherein said hydroxy ether is represented by the general formula

3. The method of claim 2 wherein said hydroxy ether is butoxy ethanol.

4. The method of claim 1 wherein said further curable organopolysiloxane is the hydrolysis and partial condensation product of an alkyl trialkoxysilane.

5. The method of claim 4 wherein said alkyl trialkoxysilane is methyl trialkoxysilane.

6. The method of claim 1 wherein said polycarbonate article is a sheet.

7. The method of claim 6 wherein said sheet is transparent.

8. A method for providing a uniform and durably adhered mar, scratch, abrasion and chemical solvent resistant organopolysiloxane coating on a polycarbonate article which comprises:

(i) applying onto the surface of a polycarbonate substrate a primer emulsion composition containing, in percent by weight, (a) from about 1 to about 10 percent of a thermosettable acrylic polymer, (b) from about 20 to about 45 percent of a hydroxy ether, and (c) from about 45 to about 79 percent of water;

(ii) evaporating off a substantial portion of said water and hydroxy ether from said primer emulsion composition to form a layer comprised of a thermosettable acrylic;

(iii) thermally curing said thermosettable acrylic to form a thermoset acrylic primer layer;

(iv) applying onto said cured primer layer a top coat composition containing a further curable organopolysiloxane;

(v) evaporating off a substantial portion of any solvents present in said top coat composition thereby forming a layer comprised of further curable organopolysiloxane; and

(vi) further curing said organopolysiloxane thereby forming a cured organopolysiloxane coating.

9. The method of claim 8 wherein said hydroxy ether is represented by the general formula

10. The method of claim 9 wherein said hydroxy ether is butoxy ethanol.

11. The method of claim 8 wherein said further curable organopolysiloxane is the hydrolysis and partial condensation product of an alkyl trialkoxy silane.

12. The method of claim 11 wherein said alkyl trialkoxy silane is methyl trialkoxy silane.

13. The method of claim 8 wherein said polycarbonate article is a sheet.

14. The method of claim 13 wherein said sheet is transparent.