Process for removing CO.sub.2, H.sub.2 S and other gaseous impurities from gaseous mixtures

• US 4,198,378 A
• Filed: 11/02/1977
• Issued: 04/15/1980
• Est. Priority Date: 11/12/1976
• Status: Expired due to Term

• Current Assignee: Giuseppe Giammarco, Paolo Giammarco
• Original Assignee: Giuseppe Giammarco, Paolo Giammarco
• Inventors: Giammarco, Paolo, Giammarco, Giuseppe
• Primary Examiner(s): Thomas, Earl C.
• Application Number:
  US05/847,885
• Time in Patent Office: 895 Days
• Field of Search: 423/220, 423/221, 423/223, 423/226, 423/228, 423/229, 423/232, 423/233, 203/96, 203/DIG. 8, 203/DIG. 10, 203/DIG. 11, 48/197 R, 122/1 R, 122/5, 122/16
• US Class Current: 423/220
• CPC Class Codes: B01D 53/1425 Regeneration of liquid absorbents
• CPC Class Codes: B01D 53/1456 Removing acid components
• CPC Class Codes: C01B 2203/0415 Purification by absorption in liquids
• CPC Class Codes: C01B 2203/0465 Composition of the impurity
• CPC Class Codes: C01B 2203/0475 the impurity being carbon dioxide
• CPC Class Codes: C01B 2203/048 the impurity being an organic compound
• CPC Class Codes: C01B 2203/0485 the impurity being a sulfur compound
• CPC Class Codes: C01B 3/52 by contacting with liquids; Regeneration of used liquids C01B3/508 takes precedence
• CPC Class Codes: Y02C 20/40 of CO2
• CPC Class Codes: Y02P 20/151 Reduction of greenhouse gas [GHG] emissions, e.g. CO2

Abstract

A process for removing gaseous impurities such as CO₂ and/or H₂ S from a gaseous mixture obtained by reacting combustible substances with steam, said steam being produced in boilers fed with water previously purified in degassing columns. The gaseous impurities are removed by means of an absorbent solution and the latter is regenerated in a regeneration column by stripping with steam. The stripping steam necessary for the degassing is delivered, at a pressure at least equal to that in the regeneration column, to the degassing columns and then to the regeneration column. The boiler feed water to be purified is previously heated, by supply of residual heats, to a temperature in the vicinity of the boiling temperature of the absorbent solution in the regeneration column.

Claims

1. In a process for removing gaseous impurities, such as CO₂ and/or H₂ S and the like from a gaseous mixture obtained by a gasification method in which combustible substances are reacted at elevated temperature with steam, comprising an absorption step in which said gaseous mixture is brought into contact in an absorption column with an aqueous alkaline absorbent solution, and a regeneration step in which said impurities are removed from the absorbent solution in a regeneration column by stripping with steam obtained mainly from a reboiler in which heat is recovered from the gaseous mixture to be purified by indirect heat exchange in the reboiler with the aqueous alkaline absorbent solution, and wherein the steam utilized in said gasification methods is produced in boilers fed with boiler feed water previously degassed and purified by a treatment with steam in suitable means, the improvement which comprises:

delivering said steam, at a pressure at least equal to that in said regeneration column, first to said degassing and purification columns and then to said regeneration column to be used again, wherein after said steam is used for degassing and purifying in said means said steam is delivered, at a pressure at least equal to the pressure in said regeneration column, to said regeneration column, said steam yielding heat initially to said boiler feed water in said degassing and purification means and then to the absorbent solution in the regeneration column.

2. The process of claim 1, in which said degassing and purification means operates at the same pressure and temperature as in said regeneration column.

3. The process of claim 1, in which said degassing and purification means operates at a pressure higher than that in said regeneration column, so that the steam extracted from said degassing and purification means is used in a reboiler located at the bottom of said regeneration column.

4. The process of claim 1, in which said degassing and purification means operates at a pressure higher than that in said regeneration column, so that the steam extracted from said degassing and purification means is used as motive steam in an ejector to create a drop in pressure and extract steam from the regenerated solution issuing from said regeneration column, said extracted steam being delivered, together with said motive steam, to said regeneration column.

5. In a process for removing gaseous impurities, such as CO₂ and/or H₂ S and the like, from a gaseous mixture obtained by a gasification method in which combustible substances are reacted at elevated temperature with steam, comprising an absorption step in which said gaseous mixture is brought into contact in an absorbent column with an aqueous alkaline absorbent solution, and a regeneration step in which said impurities are removed from the absorbent solution in a regeneration column by stripping with steam obtained mainly from a reboiler in which heat is recovered from the gaseous mixture to be purified by indirect heat exchange in the reboiler with the aqueous alkaline absorbent solution, and wherein the steam utilized in the said gasification method is produced in boilers fed with boiler feed water previously degassed and purified by treatment with steam in suitable means, the improvement which comprises:

(a) recovering the residual heats of the regenerated solution issuing from said regeneration column and that of the gaseous mixture to be purified issuing from said reboiler, and using said residual heats to gradually heat said boiler feed waters to a temperature in the vicinity of the boiling temperature of the solution in said regeneration column;

(b) delivering said boiler feed water pre-heated in (a) to said degassing and purification means;

(c) extracting the steam remaining in thermal excess from said degassing and purification means and delivering said steam to the regeneration column, wherein after said steam is used for degassing and purifying in said means, said steam is delivered, at a pressure at least equal to the pressure in said regeneration column, to said regeneration column, said steam yielding heat initially to said boiler feed water in said degassing and purification means and then to the absorbent solution in the regeneration column.

6. The process of claim 5, in which the amount and the temperature of the residual heat of the regenerated solution issuing from said regeneration column are increased by increasing the pressure in said regeneration column, to an extent such as to create a temperature difference of from 10°

to 35°

C. between the bottom and the top of said regeneration column according to the degree of regeneration of the solution issuing from the said regeneration column.

7. The process of claim 5, in which said degassing and purification means operates at the same pressure and temperature as the regeneration column.

8. The process of claim 5, in which said degassing and purification means operates at a higher pressure than that in said regeneration column, so that steam is extracted from said degassing and purification means and used in a suitable reboiler located at the bottom of said regeneration column.

9. The process of claim 5, in which said degassing and purification means operates at a higher pressure than that in said regeneration column, so that steam is extracted from the said degassing and purification means and used as motive steam in an ejector, to create a drop in pressure and extract steam from the regenerated solution issuing from said regeneration column, said extracted steam being delivered, together with said motive steam, to said regeneration column.

10. In a process for removing gaseous impurities, such as CO₂ and/or H₂ S and the like, from a gaseous mixture obtained by a gasification method in which combustible substances are reacted at elevated temperature with steam, comprising an absorption step in which said gaseous mixture is brought into contact in an absorption column with an aqueous alkaline absorbent solution, and a regeneration step in which said impurities are removed from the absorbent solution in a regeneration column by stripping with steam obtained mainly from a reboiler in which heat is recovered from the gaseous mixture to be purified by indirect heat exchange in the reboiler with the aqueous alkaline absorbent solution, and wherein the steam utilized in said gasification method is produced in boilers fed with boiler feed water previously degassed and purified by treatment with steam in suitable means, the improvement which comprises:

(a) delivering steam, at a pressure at least equal to that in said regeneration column, first to said degassing and purification means and then, together with the impurities removed from said boiler feed waters, to said regeneration column to be used again, said steam thus yielding heat to said boiler feed water in said degassing and purification means and then to the absorbent solution in the regeneration column;

(b) extracting from the apparatus for removing CO₂ and/or H₂ S a part of the condensation waters of the coolers for CO₂ and/or H₂ S issuing at the top of said regeneration column, delivering said condensation water to a column in which a part of the impurities present in said condensation water is removed by stripping with inert gas, and then recycling a part of said condensation water to the apparatus for removing CO₂ and/or H₂ S.

11. The process of claim 10, in which said inert gas is constituted by a part of the gas to be delivered to the apparatus for conducting said gasification method and is delivered to said apparatus for conducting said gasification method together with the impurities removed from said condensation water, said impurities being destroyed in said apparatus for conducting said gasification method.

12. The process of claim 10, in which said inert gas, prior to its utilization for stripping said condensation water, is previously heated and humidified (by addition of steam) by bringing it into direct contact with the boiler feed water issuing from said degassing and purification means.

13. In a process for removing gaseous impurities such as CO₂ and/or H₂ S and the like, from a gaseous mixture obtained by a gasification method in which combustible substances are reacted at elevated temperature with steam, comprising an absorption step in which said gaseous mixture is brought into contact in an absorption column with an aqueous alkaline absorbent solution, and a regeneration step in which said impurities are removed from the absorbent solution in a regeneration column by stripping with steam obtained mainly from a reboiler in which heat is yielded by the gaseous mixture to be purified, and wherein the steam utilized in said gasification method is produced in boilers fed with boiler feed water previously degassed and purified by treatment with steam in suitable columns, the improvement which comprises:

(a) delivering steam, at a pressure at least equal to that in said regeneration column, first to said degassing and purification means and then, together with the impurities removed from said boiler feed water, to said regeneration column to be used again, said steam thus yielding heat to said boiler feed water in said degassing and purification means and then to the absorbent solution in the regeneration column;

(b) scrubbing the gaseous mixture to be purified, prior to its introduction into the absorption column, with water in a scrubbing column, to remove by means of said water a part of the impurities present in said gaseous mixture to be purified, treating in another column said water with inert gas to remove a part of the impurities present in said water, and recycling said water to the scrubbing column.

14. The process of claim 13, in which said inert gas is constituted by a part of the gas to be delivered to the apparatus for conducting said gasification method, said inert gas being delivered to said apparatus for conducting said gasification method together with said impurities removed from said scrubbing water, and said impurities being destroyed in said apparatus for conducting said gasification method.

15. The process of claim 13, in which said inert gas, prior to its utilization for the stripping of said scrubbing water, is previously heated and humidified (by addition of steam) by bringing it into direct contact with the boiler feed water issuing from said degassing and purification means.

16. In a process for removing gaseous impurities, such as CO₂ and/or H₂ S and the like, from a gaseous mixture obtained by a gasification method in which combustible substances are reacted at elevated temperature with steam, comprising an absorption step in which said gaseous mixture is brought into contact in an absorption column with an aqueous alkaline absorbent solution, and a regeneration step in which said impurities are removed from the absorbent solution in a regeneration column by stripping with steam obtained mainly from a reboiler in which heat is recovered from the gaseous mixture to be purified by indirect heat exchange in the reboiler with the aqueous alkaline absorbent solution, and wherein the steam utilized in said gasification method is produced in boilers fed with boiler feed water previously degassed and purified by treatment in suitable columns, the improvement which comprises:

(a) carrying out a pre-degassing and pre-purification of said boiler feed water in a first degassing and purification column in which said boiler feed water is treated by means of an inert gas which removes the major part of the impurities present in said boiler feed water, said removed impurities being discharged to the outside;

(b) completing the degassing and purification of said boiler feed water in a second degassing and purification column by stripping with steam, and then delivering said stripping steam, together with the impurities removed by the latter, to said regeneration column, said stripping stream thus yielding heat to said boiler feed water in said second degassing and purification column and then to the absorbent solution in the regeneration column.

17. The process of claim 16, in which said inert gas is constituted by a part of the gas to be delivered to the apparatus for conducting said gasification method, said inert gas being delivered to said apparatus for conducting said gasification method together with the impurities removed from said boiler feed water, and said impurities being destroyed in said apparatus for conducting said gasification method.

18. The process of claim 16, in which said inert gas, prior to its utilization for the stripping of said boiler feed water, is previously heated and humidified (by addition of steam) by bringing it into direct contact with the boiler feed water issuing from said degassing and purification columns.

19. In a process for removing gaseous impurities, such as CO₂ and/or H₂ S and the like, from a gaseous mixture obtained by a gasification method in which combustible substances are reacted at elevated temperature with steam, comprising an absorption step in which said gaseous mixture is brought into contact in an absorption column with an aqueous alkaline absorbent solution, and a regeneration step in which said impurities are removed from the absorbent solution in a regeneration column by stripping with steam obtained mainly from a reboiler in which heat is recovered from the gaseous mixture to be purified by indirect heat exchange in the reboiler with the aqueous alkaline absorbent solution, and wherein the steam utilized in said gasification method is produced in a boiler fed with boiler feed water previously degassed and purified by treatment with steam in suitable columns, the improvement which comprises:

(a) carrying out the degassing and purification of said boiler feed water in a two-stage column, comprising an upper zone and a lower zone, said boiler feed water being introduced into said upper zone and passed in sequence through said upper zone and then through said lower zone;

(b) delivering steam to the bottom of said lower zone, and dividing said steam, at the top of said lower zone, into a major, first fraction and a minor, second fraction;

delivering said first fraction, together with the impurities removed in said lower zone, to the regeneration column;

flowing said second fraction through said upper zone to remove in the latter the major part of the impurities present in said boiler feed water, and discharging to the outside said impurities removed in said upper zone together with said second fraction of steam.

20. In a process for removing gaseous impurities such as CO₂ and/or H₂ S and the like, from a gaseous mixture obtained by a gasification method, in which combustible substances are reacted at elevated temperature with steam, comprising an absorption step in which said gaseous mixture is brought into contact in an absorption column with an aqueous alkaline absorbent solution, and a regeneration step in which said impurities are removed from the absorbent solution in a regeneration column by stripping with steam obtained mainly from a reboiler in which heat is recovered from the gaseous mixture to be purified by indirect heat exchange in the reboiler with the aqueous alkaline absorbent solution, and wherein the steam utilized in said degasification methods is produced in boilers fed with boiler feed water previously degassed and purified by treatment with steam in suitable columns, the improvement which comprises:

(a) carrying out the degassing and purification of said boiler feed water in a two-stage column, comprising an upper zone and a lower zone, said boiler feed water being introduced into said upper zone and passed in sequence through said upper zone and then through said lower zone;

(b) delivering steam to the bottom of said lower zone, and dividing said steam, at the top of said lower zone, into a major, first fraction and a minor, second fraction;

delivering said first fraction to the regeneration column together with the impurities removed in said lower zone;

flowing said second fraction through said upper zone and removing in the latter the major part of the impurities present in said boiler feed water, and discharging to the outside the impurities removed in said upper zone, together with said second fraction of steam;

(c) extracting from the apparatus for the removal of CO₂ and/or H₂ S a part of the condensation water of the coolers for CO₂ and/or H₂ S issuing at the top of said regeneration column, delivering said condensation water to a column in which a part of the impurities present in said condensation water is stripped off by means of inert gas, and then recycling a part of said condensation water to the apparatus for removing CO₂ and/or H₂ S.

21. The process of claim 20, in which said inert gas is constituted by a part of the gas to be used in the apparatus for conducting said gasification method, said inert gas being delivered to said apparatus for conducting said gasification method together with the impurities removed from said condensation water, and said impurities being destroyed in said apparatus for conducting said gasification method.

22. The process of claim 20, in which said inert gas, prior to its utilization for the stripping of said condensation water is previously heated and humidified (by addition of steam) by bringing it into direct contact with the boiler feed water issuing from said degassing and purification column.

23. In a process for removing gaseous impurities such as CO₂ and/or H₂ S and the like, from a gaseous mixture obtained by a gasification method in which combustible substances are reacted at elevated temperature with steam, comprising an absorption step in which said gaseous mixture is brought into contact in an absorption column with an aqueous alkaline absorbent solution, and a regeneration step in which said impurities are removed from the absorbent solution in a regeneration column by stripping with steam obtained mainly from a reboiler in which heat is recovered from the gaseous mixture to be purified by indirect heat exchange in the reboiler with the aqueous alkaline absorbent solution, and wherein the steam utilized in said gasification method is produced in boilers fed with boiler feed water previously degassed and purified by treatment with steam in suitable columns, the improvement which comprises:

(a) carrying out the degassing and purification of said boiler feed water in a two-stage column, comprising an upper zone and a lower zone, said boiler feed water being introduced into said upper zone and passed in sequence through said upper zone and then through said lower zone;

(b) delivering steam to the bottom of said lower zone and dividing said steam, at the top of said lower zone, into a major, first fraction and a minor, second fraction;

delivering said first fraction to said regeneration column together with the impurities removed in said lower zone;

flowing said second fraction through said upper zone, removing in the latter the major part of the impurities contained in said boiler feed water, and discharging to the outside the impurities removed in said upper zone, together with said second fraction of steam;

(c) scrubbing the gaseous mixture to be purified, prior to its introduction into said adsorption column, with water in a scrubbing column, removing with said water a part of the impurities contained in said gaseous mixture to be purified, treating in another column said water by means of inert gas to remove a part of the impurities present in said water, and recycling said water to the scrubbing column.

24. The process of claim 23, in which said inert gas is constituted by a part of the gas to be delivered to the apparatus for conducting said gasification method, said inert gas being delivered to said apparatus for conducting said gasification method together with the impurities removed from said scrubbing water, and said impurities being destroyed in said apparatus for conducting said gasification method.

25. The process of claim 23, in which said inert gas, prior to its utilization for the stripping of the scrubbing water, is previously heated and humified (by addition of steam), by bringing it into direct contact with the boiler feed water issuing from the said degassing and purification column.

26. In a process for removing gaseous impurities such as CO₂ and/or H₂ S and the like, from a gaseous mixture obtained by a gasification method in which combustible substances are reacted at elevated temperature with steam, comprising an absorption step in which said gaseous mixture is brought into contact in an absorption column with an aqueous alkaline absorbent solution, and a regeneration step in which said impurities are removed from the absorbent solution in a regeneration column by stripping with steam obtained mainly from a reboiler in which heat is recovered from the gaseous mixture to be purified by indirect heat exchange in the reboiler with the aqueous alkaline absorbent solution, and wherein the steam utilized in said gasification method is produced in boilers fed with boiler feed water previously degassed and purified by treatment with steam in suitable columns, the improvement which comprises:

(a) carrying out the degassing and purification of said boiler feed water in a column comprising an upper zone operating at a higher pressure and a lower zone operating at a lower pressure, said boiler feed water being introduced into said upper zone and passed in sequence through said upper zone and then through said lower zone;

(b) delivering steam to the bottom of said upper zone and, after its utilization in the latter as stripping steam, substantially condensing said steam for heating said boiler feed water; and

discharging to the outside the impurities removed from the boiler feed water in said upper zone;

(c) delivering said boiler feed water purified and heated in said upper zone, to said lower zone operating at a pressure lower than that of the upper zone and at least equal to the pressure in said regeneration column, and expanding therein said boiler feed water, with release of steam;

(d) delivering the steam evolved in said lower zone to said regeneration column to use it a second time.

27. The process of claim 26, in which said lower zone operates at a pressure higher than that in said regeneration column, so that the steam extracted from said lower zone is used in a suitable reboiler located at the bottom of said regeneration column.

28. In a process for removing gaseous impurities, such as CO₂ and/or H₂ S and the like, from a gaseous mixture obtained by a gasification method in which combustible substances are reacted at elevated temperature with steam, comprising an absorption step in which said gaseous mixture is brought into contact in an absorption column with an aqueous alkaline absorbent solution, and a regeneration step in which said impurities are removed from the absorbent solution in a regeneration column by stripping with steam obtained mainly from a reboiler in which heat is recovered from the gaseous mixture to be purified by indirect heat exchange in the reboiler with the aqueous alkaline absorbent solution, and wherein the steam utilized in said gasification method is produced in boilers fed with boiler feed water previously degassed and purified by treatment with steam in suitable columns, the improvement which comprises:

(a) utilizing for the regeneration step a main regeneration column, operating at a higher pressure and with supply of heat from the outside, and a secondary regeneration column operating at a lower pressure and by means of the heat recovered from the regenerated solution issued from said main regeneration column;

(b) delivering steam, at a pressure at least equal to that in said main regeneration column, said steam thus yielding heat to said boiler feed water in the degassing and purification columns and then to the absorbent solution in the main regeneration column.

29. In a process for removing gaseous impurities, such as CO₂ and/or H₂ S and the like, from a gaseous mixture obtained by a gasification method in which combustible substances are reacted at elevated temperature with steam, comprising an absorption step in which said gaseous mixture is brought into contact in an absorption column with an aqueous alkaline absorbent solution, and a regeneration step in which said impurities are removed from the absorbent solution in a regeneration column by stripping with steam obtained mainly from a reboiler in which heat is recovered from the gaseous mixture to be purified by indirect heat exchange in the reboiler with the aqueous alkaline absorbent solution, and wherein the steam utilized in said gasification method is produced in boilers fed with boiler feed water previously degassed and purified by treatment with steam in suitable columns, the improvement which comprises:

(a) utilizing for the regeneration step a main regeneration column, operating at a higher pressure and by means of heat supplied from the outside, and a secondary regeneration column operating at a lower pressure and by means of heat recovered from the regenerated solution issued from said main regeneration column;

(b) delivering steam at a pressure at least equal to that in said secondary regeneration column, first to said degassing and purification columns for said boiler feed water, and then to said secondary regeneration column, said steam thus yielding heat to said boiler feed water in the degassing and purification columns and then to the absorbent solution in the secondary regeneration column.