Impact resistant laminate

• US 4,198,468 A
• Filed: 10/19/1978
• Issued: 04/15/1980
• Est. Priority Date: 10/19/1978
• Status: Expired due to Term

• Current Assignee: General Electric Company
• Original Assignee: General Electric Company
• Inventors: Molari, Richard E.
• Primary Examiner(s): Kendell, Lorraine T.
• Application Number:
  US05/952,678
• Time in Patent Office: 544 Days
• Field of Search: 428/412, 428/447, 428/448, 428/911
• US Class Current: 428/412
• CPC Class Codes: B32B 17/10018 comprising only one glass sheet
• CPC Class Codes: B32B 17/10853 the membrane being bag-shaped
• CPC Class Codes: B32B 2307/558 Impact strength, toughness
• CPC Class Codes: B32B 2307/56 Damping, energy absorption
• CPC Class Codes: B32B 2333/04 Polymers of esters
• CPC Class Codes: B32B 2333/12 Polymers of methacrylic acid esters, e.g. PMMA, i.e. polymethylmethacrylate
• CPC Class Codes: B32B 2369/00 Polycarbonates
• CPC Class Codes: B32B 27/08 of synthetic resin
• CPC Class Codes: B32B 27/30 comprising vinyl (co)polymers; comprising acrylic (co)polymers
• CPC Class Codes: B32B 27/36 comprising polyesters
• CPC Class Codes: B32B 27/365 comprising polycarbonates
• CPC Class Codes: B32B 7/12 using interposed adhesives or interposed materials with bonding properties
• CPC Class Codes: F41H 5/0407 Transparent bullet-proof laminatesinformative reference: layered products essentially comprising glass in general B32B17/06, e.g. B32B17/10009; manufacture or composition of glass, e.g. joining glass to glass C03; permanent multiple-glazing windows, e.g. with spacing therebetween, E06B3/66
• CPC Class Codes: Y10S 428/911 Penetration resistant layer
• CPC Class Codes: Y10T 428/31507 Of polycarbonate
• CPC Class Codes: Y10T 428/31663 As siloxane, silicone or silane

Abstract

Improved impact or shock resistant laminates are provided comprising a plurality of laminae including a back polycarbonate lamina of controlled thickness opposite the direction of impact or shock, a front polycarbonate lamina facing the direction of impact or shock, and at least one acrylic resin lamina intermediate said back and front polycarbonate laminae, said polycarbonate laminae having a relatively brittle overlayer or coating on the outer surfaces thereof opposite said intermediate acrylic based lamina.

Claims

1. Impact or shock resistant laminate having improved spall resistance consisting essentially of a plurality of laminae including a back polycarbonate lamina having a controlled thickness of from about 30 mils to about 220 mils opposite the direction of impact or shock, said back polycarbonate lamina having a mar-resistant coating on the exposed surface thereof opposite the direction of impact, a front polycarbonate lamina facing the direction of impact or shock having a mar-resistant coating on the exposed surface thereof facing the direction of impact, and at least one acrylic resin lamina disposed intermediate said back and front polycarbonate laminae, the back and front polycarbonate laminae being bonded to said acrylic resin lamina by a compatible adhesive.

2. The laminate according to claim 1 wherein said front polycarbonate lamina has a thickness from about 30 mils to about 220 mils.

3. The laminate according to claim 1 wherein said mar resistant coating is from about 0.05 mils to about 2 mils thick.

4. The laminate according to claim 1 wherein said mar resistant coating is harder and more brittle than the underlying polycarbonate.

5. The laminate according to claim 1 wherein said adhesive is comprised of a block polysiloxane-polycarbonate copolymer prepared by reacting (A) a halogen chain-stopped polydiorganosiloxane composed of from about 5 to 200 chemically combined diorganosiloxy units consisting essentially of dialkylsiloxy units which are connected to each other by silicon-oxygen-silicon linkages wherein each of the silicon atoms has two organo radicals attached through a carbon-silicon bond, and (B) a dihydric phenol having the formula ##STR6## where Z is a member selected from the class consisting of hydrogen, lower alkyl radicals and halogen radicals and combinations thereof, and R is a member selected from the class consisting of hydrogen, hydrocarbon and halogenated hydrocarbon radicals, and phosgenating the purified reaction product.

6. The laminate according to claim 1 wherein one acrylic resin lamina is disposed between said back and front polycarbonate laminae.