Anisotropically pressure-sensitive electroconductive composite sheets and method for the preparation thereof

• US 4,199,637 A
• Filed: 06/01/1978
• Issued: 04/22/1980
• Est. Priority Date: 11/26/1975
• Status: Expired due to Term

• Current Assignee: Shin-Etsu Polymer Company Limited (Shin-Etsu Chemical Company Limited)
• Original Assignee: Shin-Etsu Polymer Company Limited (Shin-Etsu Chemical Company Limited)
• Inventors: Sado, Ryoichi
• Primary Examiner(s): Lesmes, George F.
• Assistant Examiner(s): Varndell, Jr., R. Eugene
• Application Number:
  US05/911,418
• Time in Patent Office: 691 Days
• Field of Search: 339/59 M, 339/60 M, 339/61 M, 339/DIG. 3, 175/35 C, 175/35 GC, 428/119, 428/292, 428/303, 428/374, 428/397, 428/400, 428/378, 428/379, 428/447, 428/401, 338/71, 338/99, 338/112, 338/114
• US Class Current: 428/119
• CPC Class Codes: B29C 48/022 characterised by the choice of material
• CPC Class Codes: B29C 48/08 flexible, e.g. films
• CPC Class Codes: B29C 70/14 oriented
• CPC Class Codes: B29C 70/882 partly or totally electrically conductive, e.g. for EMI shielding conductive floors or floor coverings H05F3/025; EMI shielding in general H05K9/00
• CPC Class Codes: B29K 2105/06 containing reinforcements, fillers or inserts
• CPC Class Codes: H01B 5/16 comprising conductive material in insulating or poorly conductive material, e.g. conductive rubber H01B1/14, H01B1/20 take precedence; insulating bodies with conductive admixtures H01B17/64; conductive paints C09D5/24
• CPC Class Codes: H01H 13/785 characterised by the material of the contacts, e.g. conductive polymers
• CPC Class Codes: H01H 2201/036 Variable resistance
• CPC Class Codes: H01R 13/2414 conductive elastomers
• CPC Class Codes: H01R 31/00 Coupling parts supported only by co-operation with counterpart
• CPC Class Codes: H01R 43/007 for elastomeric connecting elements
• CPC Class Codes: Y10T 428/1405 Capsule or particulate matter containing [e.g., sphere, flake, microballoon, etc.]
• CPC Class Codes: Y10T 428/1438 Metal containing
• CPC Class Codes: Y10T 428/24174 including sheet or component perpendicular to plane of web or sheet
• CPC Class Codes: Y10T 428/249945 Carbon or carbonaceous fiber
• CPC Class Codes: Y10T 428/2931 Fibers or filaments nonconcentric [e.g., side-by-side or eccentric, etc.]
• CPC Class Codes: Y10T 428/2938 Coating on discrete and individual rods, strands or filaments
• CPC Class Codes: Y10T 428/294 including metal or compound thereof [excluding glass, ceramic and asbestos]
• CPC Class Codes: Y10T 428/2973 Particular cross section
• CPC Class Codes: Y10T 428/2978 Surface characteristic
• CPC Class Codes: Y10T 428/31663 : As siloxane, silicone or silane

Abstract

Anisotropically pressure-sensitive electroconductive composite sheets are provided which have a very low electric conductive resistance in the direction perpendicular to the plane of the sheet when compressed with an adequate pressure in the direction but a high insulating resistance in all directions within the plane of the sheet. The composite sheets are constructed so that electrically conductive fibers are uniformly dispersed in the matrix of an electrically insulating substance, the average length of the fibers ranging from 20 to 80% of the thickness of the sheet, and are aligned in the direction substantially perpendicular to the plane. They are useful as a switching material in various miniaturized electronic circuits.

Claims

1. An anisotropically electroconductive thin composite sheet having a plane top surface and a plane bottom surface substantially parallel to said top surface, and composed of an electrically insulating material and a plurality of electrically conductive fibers dispersed through said sheet in alignment in a direction substantially perpendicular to said plane top surface and said plane bottom surface, the average length of said electrically conductive fibers ranging from 20 to 80% of the thickness of said sheet and at least some extending completely through said sheet.

2. The anisotropically electroconductive composite sheet, as claimed in claim 1, wherein said electrically conductive fiber is a carbon fiber.

3. The anisotropically electroconductive composite sheet, as claimed in claim 1, wherein said electrically conductive fiber is a metal fiber.

4. The anisotropically electroconductive composite sheet, as claimed in claim 1, wherein the diameter of said electrically conductive fiber is less than 0.2 mm.

5. The anisotropically electroconductive composite sheet, as claimed in claim 1, wherein the volume of said electrically conductive fibers is in the range of from about 0.1 to about 20% of the total volume of said composite sheet.

6. The anisotropically electroconductive composite sheet, as claimed in claim 1, wherein said electrically insulating material is a polymeric substance.

7. The anisotropically electroconductive composite sheet, as claimed in claim 6, wherein said polymeric substance is an elastomer.

8. The anisotropically electroconductive composite sheet, as claimed in claim 7, wherein said elastomer is a cured organopolysiloxane.

9. An anisotropically pressure sensitive electroconductive composite sheet comprising a sheet matrix having substantially parallel first and second planar surfaces on each side and being of a compressible polymeric insulating material, a multiplicity of electrically conductive fibers disposed substantially perpendicular to each of said first and second planar surfaces and being uniformly distributed within said matrix but separated from each other by insulating material of said sheet matrix, at least some of said fibers extending from one of said first surfaces to said second surface, and completely through said sheet and at least some of said fibers being shorter than the space in between said first and second surfaces, said short fibers contributing little to the conductivity of said sheet in the uncompressed state but adding to the conductivity thereof when said sheet is compressed, the number of fibers extending completely through said sheet being such that an average of the lengths of all of the fibers is within the range of 20 to 80% of the thickness of the sheet material.

10. A method of preparing an anisotropically conductive sheet comprising mixing an electrically insulating substance while soft but being capable of hardening with electrically conductive fibers, some of which are of a length which will be equal to the width of the sheet and extend completely through said sheet so as to render said sheet electrically conductive, and some of which are shorter than the width of the sheet, subjecting the mixture to a shearing deformation in one direction in a manner to align the electrically conductive fibers in a direction parallel to the shearing deformation and parallel to the surface of the sheet to form a composite of electrical insulating substance and electrically conductive fibers which are separated from each other by the insulating substance to obtain a composite, subjecting the composite to hardening, and slicing the hardened composite into a sheet having top and bottom surfaces substantially perpendicular to the direction of the alignment of the electrically conductive layers and in a manner such that some of the fibers extend from one surface to the other and others do not, the number of fibers extending completely through said sheet being such that an average of the lengths of all of the fibers is within the range of 20 to 80% of the thickness of the sheet material.