Lead-acid batteries

• US 4,200,683 A
• Filed: 01/12/1978
• Issued: 04/29/1980
• Est. Priority Date: 01/12/1978
• Status: Expired due to Term

• Current Assignee: Lucas Industries Limited (Zeppelin - Stiftung der Stadt Friedrichshafen)
• Original Assignee: Lucas Industries Limited (Zeppelin - Stiftung der Stadt Friedrichshafen)
• Inventors: Bant, John A.
• Primary Examiner(s): Skapars, Anthony
• Application Number:
  US05/868,785
• Time in Patent Office: 838 Days
• Field of Search: 429/48, 429/49, 429/224-228, 429/110, 429/118, 429/54, 429/204, 204/2.1, 29/623.2
• US Class Current: 429/48
• CPC Class Codes: H01M 10/12 Construction or manufacture
• CPC Class Codes: H01M 4/22 Forming of electrodes
• CPC Class Codes: Y02E 60/10 Energy storage using batteries
• CPC Class Codes: Y02P 70/50 Manufacturing or production processes characterised by the final manufactured product
• CPC Class Codes: Y10T 29/4911 including sealing

Abstract

A lead-acid battery capable of activation by the addition of electrolyte thereto includes at least one pack of formed positive and negative battery plates with insulating separators being interposed between adjacent plates. Part of the sulphuric acid used to form the plates is retained by the battery and has a specific gravity between 1.25 and 1.35, the amount of the retained acid being insufficient to electrically connect the plates during storage. In addition means is provided to seal the battery against ingress of air but allow gases generated in the battery to escape.

Claims

1. A method of producing a lead-acid battery capable of activation by the addition of electrolyte thereto, the method comprising the steps of:

(a) starting with a battery container accommodating at least one pack of battery plate grids having insulating separators interposed between adjacent grids, one set of grids in the pack carrying the lead-acid battery paste required to produce negative plate active material and the remaining grids carrying the paste required to produce positive plate active material,

(b) immersing the grids in the box in sulphuric acid having a specific gravity between 1.21 and 1.30 and passing an electric current between the grids to effect a forming operation on the grids and thereby convert the paste on the grids to the active material of the plates, the specific gravity of said acid rising during the passage of said current to a value between 1.26 and 1.35 at the end of the forming step,

(c) when forming is complete, draining sufficient of said forming acid from the box to prevent the retained forming acid electrically connecting the formed plates during storage, the amount of said retained acid being such that each positive plate contains at least 0.1 cc of the acid/gm of active material, and

(d) sealing the container with means which prevents ingress of air into the container but allows escape of gases generated in the container.

2. A method as claimed in claim 1, wherein the specific gravity of the forming acid at the start of step (b) is between 1.22 and 1.25.

3. A method as claimed in claim 1, wherein the amount of said retained acid is such that each positive plate contains at least 0.1 cc of the acid/gm of active material.

4. A method as claimed in claim 1, wherein step (b) includes a period of standing of at least 30 minutes without passage of the electric current and the temperature of the forming acid is allowed to rise to at least 150°

F. prior to the standing period.

5. A method as claimed in claim 1, wherein the container is sealed substantially immediately after draining of the forming acid.

6. A method as claimed in claim 1, wherein the container includes a battery box which is closed by a lid and which is divided by partition walls into a plurality of cell compartments each containing one of said packs of battery plate grids and separators, the lid being formed with apertures which communicate with the cell compartments respectively and through which said sulphuric acid is drained, and the apertures being sealed during step (d).

7. A lead-acid battery capable of activation by the addition of electrolyte thereto produced by a method as claimed in claim 1.