Determination of the partial pressure and the concentration of a gas

• US 4,205,913 A
• Filed: 06/22/1978
• Issued: 06/03/1980
• Est. Priority Date: 06/22/1977
• Status: Expired due to Term

• Current Assignee: Kernforschungszentrum Karlsruhe GmbH
• Original Assignee: Kernforschungszentrum Karlsruhe GmbH
• Inventors: Ehrfeld, Wolfgang, Krieg, Gunther
• Primary Examiner(s): Evans, F. L.
• Application Number:
  US05/917,797
• Time in Patent Office: 712 Days
• Field of Search: 250/339, 250/340, 250/343-346, 356/51, 356/414, 356/418, 356/419, 356/72, 356/73, 356/434, 356/437
• US Class Current: 356/72
• CPC Class Codes: G01N 21/3504 for analysing gases, e.g. multi-gas analysis
• CPC Class Codes: G01N 2201/1215 for interfering gases

Abstract

For determining the partial pressure and concentration of a measuring gas which is in mixture with at least one additional gas according to an optical absorption technique, in which a beam of light having a predetermined intensity and alternatingly and cyclically having a first spectral distribution in which the light intensity will be reduced by passage through the measuring gas and a second spectral distribution in which the light intensity will not be reduced by passage through the measuring gas, is passed through such a mixture and its radiation intensity after passage through the mixture is measured in a radiation detector having an active element which is heated by the radiation and which produces an output representative of its degree of heating and composed of alternating measuring signal segments, resulting, respectively, from light having the first and the second spectral distribution, and adjacent signals segments are processed in order to compensate for various interference effects, the detector output is delivered to an input amplifier having a large signal to noise ratio, and signal inaccuracies due to superimposition of each signal segment portion produced by heating of the active element on a component representing the cooling behavior which the element would experience after the preceding heating period if further heating did not occur are compensated by integrating, in an integration member, successive portions of the detector output with respect to an integration base which has a fixed value relative to the detector output value corresponding to a constant active element temperature.

Claims

1. In a method for determining the partial pressure and concentration of a measuring gas which is in mixture with at least one additional gas according to an optical absorption technique, which method includes producing a beam of light having a predetermined intensity, filtering the beam to alternatingly and cyclically give the light a first spectral distribution in which the light intensity will be reduced by passage through the measuring gas and a second spectral distribution in which the light intensity will not be reduced by passage through the measuring gas, passing the filtered beam through such a mixture, measuring the radiation intensity of the beam after passage through the mixture in a radiation detector having an active element which is heated by the radiation and which produces an output representative of its degree of heating, the output being composed of successive measuring signal segments, resulting from light having the first spectral distribution, alternating with successive reference signal segments, resulting from light having the second spectral distribution, and processing adjacent measuring signal and reference signal segments in order to compensate for fluctuations in the light beam being produced, variations in the light transmission and reflection properties of the beam path and other interference effects, the improvement wherein said step of processing comprises supplying the detector output to an input amplifier having a large signal to noise ratio, and compensating for signal inaccuracies due to superimposition of each signal segment portion produced by heating of the active element on a component representing the cooling behavior which the element would experience after the preceding heating period if further heating did not occur, said compensating step being performed by:

integrating, in an integration member, each measuring signal occurring during a period when the element is being heated by the radiation, which integration is performed with respect to an integration base;

applying to the integration member a direct voltage whose value determines the integration base; and

adjusting the direct voltage to a magnitude which will cause the integral of a measuring signal, with respect to the integrator base, to have a value of zero when light having the first spectral distribution experiences maximum intensity reduction upon passage through such measuring gas.

2. A method as defined in claim 1 wherein the input amplifier is caused to have a large signal to noise ratio by being provided with a very high feedback resistance.

3. A method as defined in claim 1 wherein the input amplifier is caused to have a large signal to noise ratio by being provided with a high input impedance.

4. In a method for determining the partial pressure and concentration of a measuring gas which is in mixture with at least one additional gas according to an optical absorption technique, which method includes producing a beam of light having a predetermined intensity, filtering the beam to alternatingly and cyclically give the light a first spectral distribution in which the light intensity will be reduced by passage through the measuring gas and a second spectral distribution in which the light intensity will not be reduced by passage through the measuring gas, passing the filtered beam through such a mixture, measuring the radiation intensity of the beam after passage through the mixture in a radiation detector having an active element which is heated by the radiation and which produces an output representative of its degree of heating, the output being composed of successive measuring signal segments, resulting from light having the first spectral distribution, alternating with successive reference signal segments, resulting from light having the second spectral distribution, and processing adjacent measuring signal and reference signal segments in order to compensate for fluctuations in the light beam being produced, variations in the light transmission and reflection properties of the beam path and other interference effects, the improvement wherein said step of processing comprises supplying the detector output to an input amplifier having a large signal to noise ratio, and compensating for signal inaccuracies due to superimposition of each signal segment portion produced by heating of the active element on a component representing the cooling behavior which the element would experience after the preceding heating period if further heating did not occur, said compensating step being performed by:

integrating, in an integration member, successive portions of the detector output with respect to an integration base which has a fixed value relative to the detector output value corresponding to a constant active element temperature, with the period of each integration being set by successive passage of the detector output through such values, thereby producing, cyclically and successively, a first integral corresponding in time to heating of the active element during a reference signal segment, a second integral corresponding in time to the respective succeeding cooling of the active element, a third integral corresponding in time to heating of the active element during the succeeding measuring signal segment, and a fourth integral corresponding in time to the respective succeeding cooling of the active element;

determining the actual difference between the first and second integrals;

determining the actual difference between the third and fourth integrals;

determining the difference which would exist between the third and fourth integrals if the measuring gas were present at a very high pressure; and

subtracting the difference which would exist from each of the actual differences.

5. A method as defined in claim 4 wherein the input amplifier is caused to have a large signal to noise ratio by being provided with a very high feedback resistance.

6. A method as defined in claim 4 wherein the input amplifier is caused to have a large signal to noise ratio by being provided with a high input impedance.

7. A method as defined in claim 4 wherein said step of integrating includes supplying said integration member with a direct voltage representing the integration base and giving the direct voltage a value such that the integration base is below the lowest detector output value.

8. A method as defined in claim 4 wherein said step of integrating includes supplying said integration member with a direct voltage representing the integration base and giving the direct voltage a value such that the integration base value is identical to the detector output value corresponding to a constant active element temperature.

9. In apparatus for determining the partial pressure and concentration of a measuring gas which is in mixture with at least one additional gas according to an optical absorption technique, which apparatus includes a light source producing a beam of light having a predetermined intensity, optical filter means arranged to filter the beam to alternatingly and cyclically give the light a first spectral distribution in which the light intensity will be reduced by passage through the measuring gas and a second spectral distribution in which the light intensity will not be reduced by passage through the measuring gas, a sample container arranged to contain such a gas mixture and disposed in the path of the filtered light beam beyond the filter means, a radiation detector disposed to receive the beam after passage through the container and having an active element which is heated by the radiation, the detector producing an output proportional to the degree of heating of the active element, the output being composed of successive measuring signal segments, resulting from light having the first spectral distribution, alternating with successive reference signal segments, resulting from light having the second spectral distribution, and means connected for processing adjacent measuring signal and reference signal segments in order to compensate for fluctuations in the light beam being produced, variations in the light transmission and reflection properties of the beam path and other interference effects, the improvement wherein said signal processing means are arranged for compensating for signal inaccuracies due to superimposition of each signal segment portion produced by heating of the active element on a component representing the cooling behavior which the element would experience after the preceding heating period if further heating did not occur, and include:

an analog computer stage containing an input amplifier having a large signal to noise ratio and connected to receive the detector output;

a digital control unit connected for controlling the operation of said computer stage;

a first indicator unit connected to said computer stage for providing an indication of the partial pressure of the measuring gas in said container; and

a second indicator connected to said computer stage for providing an indication of the concentration of the measuring gas in said container.

10. An arrangement as defined in claim 9 wherein said computer stage comprises:

a frequency filter connected in series with said input amplifier;

an integration member connected to receive the signals at the output of said amplifier and arranged to perform alternating separate integration of the reference signals and measuring signals appearing at the output of said amplifier;

a function generator having a logarithmic characteristic function connected to the output of said integration member;

an electronic switch having an input connected to the output of said function generator and having two outputs;

first and second sample and hold units each connected to a respective output of said electronic switch, said switch being controlled by said control unit to deliver integration results relating to the reference signals to said first sample and hold unit and integration results relating to the measuring signal to said second sample and hold unit;

an adder stage having a first input connected to the output of said first sample and hold unit; and

an inverter connecting the output of said second sample and hold unit to a second input of said adder stage;

a calibrating member connected to said adder stage for setting the result of the addition effected therein to represent the partial pressure of the measuring gas in said container;

a divider stage having a first input connected to the output of said adder stage; and

a pressure gauge connected to measure the gas pressure in said container and having a pressure signal output connected to a second input of said divider.

11. An arrangement as defined in claim 10 wherein said computer stage further comprises a direct voltage source connected to the input of said integration member for simultaneously matching said integration member and said input amplifier.

12. An arrangement as defined in claim 10 wherein there is a plurality of measuring gases in such mixture and said computer stage comprises a plurality of assemblies each for monitoring a respective measuring gas and each including respective first and second sample and hold units, a respective inverter, a respective adder stage, a respective calibrating member and a respective divider stage.

13. An arrangement as defined in claim 10 wherein:

said digital control unit comprises an oscillator having a predetermined frequency output, a first frequency divider connected to the output of said oscillator, a second frequency divider connected to the output of said oscillator, and a counter connected between said second divider and said integration member;

said digital control unit has a further output connected to said electronic switch for controlling switching thereof;

said filter means are connected to be rotated by an electric motor; and

said first divider is connected to control the movement of the motor.

14. An arrangement as defined in claim 13 further comprising means defining a light barrier connected to said counter and arranged to monitor movement of said filter means for resetting said counter to zero after each complete cycle of movement of said filter means.

15. In apparatus for determining the partial pressure and concentration of a measuring gas which is in mixture with at least one additional gas according to an optical absorption technique, which apparatus includes a light source producing a beam of light having a predetermined intensity, optical filter means arranged to filter the beam to alternatingly and cyclically give the light a first spectral distribution in which the light intensity will be reduced by passage through the measuring gas and a second spectral distribution in which the light intensity will not be reduced by passage through the measuring gas, a sample container arranged to contain such a gas mixture and disposed in the path of the filtered light beam beyond the filter means, a radiation detector disposed to receive the beam after passage through the container and having an active element which is heated by the radiation, the detector producing an output proportional to the degree of heating of the active element, the output being composed of successive measuring signal segments, resulting from light having the first spectral distribution, alternating with successive reference signal segments, resulting from light having the second spectral distribution, and means connected for processing adjacent measuring signal and reference signal segment in order to compensate for fluctuations in the light beam being produced, variations in the light transmission and reflection properties of the beam path and other interference effects, the improvement wherein said signal processing means are arranged for compensating for signal inaccuracies due to superimposition of each signal segment portion produced by heating of the active element on a component representing the cooling behavior which the element would experience after the preceding heating period if further heating did not occur, and include:

a digital computer stage containing an input amplifier having a large signal to noise ratio and connected to receive the detector output;

a digital control unit connected for controlling the operation of said computer stage;

a first indicator unit connected to said computer stage for providing an indication of the partial pressure of the measuring gas in said container; and

a second indicator connected to said computer stage for providing an indication of the concentration of the measuring gas in said container.

16. An arrangement as defined in claim 15 wherein said digital computer stage further includes an integrating analog/digital converter connected to the output of said amplifier, a multiplexer connected to the output of said converter, a digital multichannel memory connected to the output of said multiplexer, and a digital computer unit connected to the output of said memory.

17. Circuit arrangement as defined in claim 16 wherein said digital computer stage further includes an electronically controllable variable resistor connected to said amplifier for controlling the amplification factor of said amplifier, a reference voltage source, and a comparator connected between said reference voltage source and said resistor for controlling said resistor in a manner to maintain output signals from said converter corresponding to the integrals of the reference signal segments at a predetermined constant value.

18. An arrangement as defined in claim 16 wherein there is a plurality of measuring gases in such mixture said digital computer stage comprises a plurality of digital memories each associated with a respective one of the measuring gases.

19. An arrangement as defined in claim 16 wherein said digital computer unit is arranged to establish a predetermined integration base by addition of a digital constant to the digital representations of the measuring signals and the reference signals.