Ozone removal filter having manganese dioxide coated thereon

• US 4,207,291 A
• Filed: 04/03/1978
• Issued: 06/10/1980
• Est. Priority Date: 04/03/1978
• Status: Expired due to Term

• Current Assignee: Mcdonnell Douglas Corporation (The Boeing Co.)
• Original Assignee: Mcdonnell Douglas Corporation (The Boeing Co.)
• Inventors: Byrd, Norman R., Luoto, Reino E.
• Primary Examiner(s): Garris, Bradley R.
• Application Number:
  US05/892,976
• Time in Patent Office: 799 Days
• Field of Search: 21/74 R, 21/74 A, 21/53, 23/288 F, 23/288 FA, 23/288 FB, 23/288 FC, 23/288 R, 423/210 C, 423/219, 252/471, 422/4, 422/122, 422/180, 422/222, 55/524, 55/528
• US Class Current: 422/122
• CPC Class Codes: B01D 53/8675 Ozone
• CPC Class Codes: B01J 31/06 containing polymers organometallic polymers B01J31/123; polymer-bound organometallic complexes B01J31/165; coordination polymers B01J31/1691

Abstract

Filter for removal of ozone from air, e.g. in aircraft cabins, comprising a porous and preferably light weight and thermally stable substrate, particularly an organic polymer such as polybenzimidazole, containing a film or coating of manganese dioxide. The article can be formed by treating the substrate with a permanganate solution under conditions to reduce the permanganate to MnO₂.

Claims

1. A filter effective particularly for removing ozone from air, comprising a substrate formed of a porous light weight material containing a manganese dioxide coating deposited on said substrate from a permanganate solution, said substrate being a member selected from the group consisting of polybenzimidazole, a polyamide, a polyimide, a phenolic polymer, polyethylene, cellulose and derivatives and mixtures thereof.

2. A filter as defined in claim 1, wherein said substrate is in the form of batting or cloth.

3. A filter as defined in claim 1, said substrate being comprised of one or more layers of batting of said material positioned between outer layers of cloth of said material, said manganese dioxide being impregnated into and coated on said batting and said outer cloth layers.

4. A filter as defined in claim 1, wherein said substrate is a thermally stable material.

5. A filter as defined in claim 4, wherein said substrate is polybenzimidazole.

6. A filter as defined in claim 2, wherein said substrate is a chlorinated polyamide.

7. A filter as defined in claim 4, wherein said substrate is in the form of phenolic fibers punched on polyester.

8. A filter as defined in claim 1, said substrate being comprised of one or more layers of batting of said material stitched between outer layers of cloth of said material, and formed into a bag, said manganese dioxide being impregnated into and coated on said batting and said outer cloth layers.

9. A filter as defined in claim 8, wherein said bag is conically shaped.

10. A filter as defined in claim 8, wherein said substrate is polybenzimidazole.

11. A filter as defined in claim 8, wherein said substrate is a chlorinated polyamide.

12. A filter as defined in claim 8, wherein said substrate is in the form of phenolic fibers punched on polyester.

13. Apparatus for removing ozone from air which comprises in combination, an air duct, a filter positioned in said air duct, said filter comprising a substrate formed of a porous lightweight thermally stable material containing a manganese dioxide coating deposited on said substrate from a permanganate solution, said substrate being a member selected from the group consisting of polybenzimidazole, a polyamide, a polyimide, a phenolic polymer, and derivatives and mixtures thereof and means for mounting said filter in said air duct for passage of air containing ozone through said filter.

14. Apparatus as defined in claim 13, including a filter housing in said air duct, said mounting means being disposed in said housing.

15. Apparatus as defined in claim 13, wherein said substrate is in the form of batting.

16. Apparatus as defined in claim 13, said substrate being comprised of one or more layers of batting of said material stitched between outer layers of cloth of said material, and formed into a bag, said manganese dioxide being impregnated into and coated on said batting and said outer cloth layers.

17. Apparatus as defined in claim 16, said bag being conically shaped, and positioned axially in said air duct.

18. Apparatus as defined in claim 17, wherein said batting and said cloth of said bag are polybenzimidazole.

19. Apparatus as defined in claim 17, wherein said batting and said cloth of said bag are a chlorinated polyamide.