Electrical power cable with stranded insulated wires

• US 4,207,427 A
• Filed: 03/15/1978
• Issued: 06/10/1980
• Est. Priority Date: 03/16/1977
• Status: Expired due to Term

• Current Assignee: Societa' Pirelli SPA
• Original Assignee: Industrie Pirelli SPA (Pirelli & C SPA)
• Inventors: Tuci, Giulio, Beretta, Germano, Seveso, Cesare
• Primary Examiner(s): Kucia, Richard R.
• Application Number:
  US05/886,630
• Time in Patent Office: 818 Days
• Field of Search: 174/25 R, 174/26 R, 174/110 SR, 174/128, 174/131 B
• US Class Current: 174/26.00R
• CPC Class Codes: C08K 5/29 Compounds containing one or more carbon-to-nitrogen double bonds
• CPC Class Codes: C08L 2666/14 Macromolecular compounds according to C08L59/00 - C08L87/00; Derivatives thereof
• CPC Class Codes: C08L 29/04 Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
• CPC Class Codes: C08L 61/28 with melamine
• CPC Class Codes: H01B 3/446 from vinylacetals
• CPC Class Codes: H01B 7/303 Conductors comprising interwire insulation
• CPC Class Codes: H01B 9/0611 Oil-pressure cables
• CPC Class Codes: Y10S 174/26 having a plural-layer insulation system
• CPC Class Codes: Y10S 174/31 having a shield or metallic layer
• CPC Class Codes: Y10S 174/32 having means for cooling

Abstract

An electric power cable having a Milliken-type conductor comprising at least four sectors, the conductor being paper-insulated and oil filled and each sector comprising metal wires stranded together. Each wire is covered with a layer of a cross-linked synthetic resin having a thermal classification of 120° C., a CEI resistance to abrasion of at least 50 cycles, a CEI thermal pressure value higher than 170° C. and an insulating oil contaminating effect of substantially zero, such resin also being substantially completely volatizable by the heat used for joining cables by welding. Preferred resins are a polyvinyl-acetal resin, such as a polyvinyl-formal resin, cross-linked with a phenol resin and, optionally, a melamine resin and such with the addition of a blocked isocyanate.

Claims

1. In a power cable comprising a Millikentype conductor comprising at least four sector-shaped conductive elements, said conductor being paper-insulated and oil-filled, each of said conductive elements comprising conductive metal wires stranded together, each of said wires having an insulating covering which provides a contact resistance radially which is high with respect to the longitudinal resistance of said wires for reducing current flow from wire to wire, an improved insulating covering which is a cross-linked synthetic resin having a thickness in the range from 4 to 10 microns, a thermal classification of at least 120°

C., i.e. resists breakdown for at least 20,000 hours when subjected to a temperature of 120°

C., a resistance to bidirectional abrasion at least equal to 50 cycles in accordance with Comitato Elettrotecnico Italiano Standard No. 55.1, a value of thermal pressure higher than 170°

C. in accordance with Comitato Elettrotecnico Italiano Standard No. 55.1, and a contamination effect on fluid oil which is substantially nil, said resin being substantially completely volatizable by heating at temperatures encountered with the welding of the conductor of one such cable to the conductor of another such cable and said resin being a polyvinyl-acetal resin cross-linked with a phenol-aldehyde resin and, optionally, a melamine resin in percentages by weight in the range from 10 and 80 parts of the phenol-aldehyde resin, 0 and 15 parts of the melamine resin and 100 parts by weight of said polyvinylacetal resin.

2. A cable as set forth in claim 1, wherein said cross-linked synthetic resin also comprises a blocked isocyanate in an amount in the range from 10 to 75 parts to 100 parts of polyvinyl-acetal resin.

3. A cable as set forth in claim 2, wherein said blocked isocyanate is a phenol-blocked toluene diisocyanate.

4. A cable as set forth in claim 1, wherein said polyvinyl-acetal resin is the condensation product of a formaldehyde with a hydrolysis product of a polyvinyl-acetate.

5. A cable as set forth in claim 1, wherein said phenol-aldehyde resin is the condensation product of cresol with formaldehyde.

6. A cable as set forth in claim 1, wherein said melamine resin is a condensation product of melamine and formaldehyde.