Sonic spray of H.sub.2 SD.sub.4 in a swirling heated air stream

• US 4,208,192 A
• Filed: 10/27/1978
• Issued: 06/17/1980
• Est. Priority Date: 10/27/1978
• Status: Expired due to Term

• Current Assignee: UOP Des Plaines IL A NY General Partnership
• Original Assignee: UOP Llc (Honeywell International Inc.)
• Inventors: Sorenson, Paul H., Quigley, William A.
• Primary Examiner(s): Yudkoff, Norman
• Application Number:
  US05/955,554
• Time in Patent Office: 599 Days
• Field of Search: 55/5, 55/92, 55/235-238, 423/215.5, 239/403, 239/405, 261/79 A
• US Class Current: 95/2
• CPC Class Codes: B01D 51/10 Conditioning the gas to be cleaned

Abstract

In order to reduce the electrical resistance of entrained fine particles of fly ash resulting from the burning of low sulfur coal and to enhance the efficiency of their collection by an electrical precipitator means, there is a conditioning of the particles carried in the flue gas stream by having a vapor of H₂ SO₄ condensed and adsorbed on the particles themselves. Sulfuric acid at ambient temperature is mixed with air in an acoustic nozzle to form a mist having an average particle size of about 10 microns which is injected uniformly into a cyclonically flowing stream of hot gas in a chamber located adjacent an upstream inlet duct portion of the precipitator unit. The hot gas in the chamber vaporizes the acid which is then injected into the precipitator inlet duct so that the acid can condense on the particles. The hot gas is preferably obtained from the combustion air preheater.

Claims

1. Method of injecting an acid conditioning agent into a flue gas stream containing fly ash to be conditioned to enhance the efficiency with which the fly ash can be electrostatically precipitated comprising the steps of:

passing a liquid acid conditioning agent under pressure through a first line into a nozzle holder incorporating a sonic atomizing nozzle at a temperature lower than its vaporizing temperature;

passing a gas from a first supply source under pressure through a second line into said nozzle, said nozzle incorporating means to produce sonic vibrations capable of breaking up said liquid acid into a mist plume having an average droplet size of about 10 microns;

passing a stream of hot gas from a second supply source having a temperature greater than the vaporization temperature of said liquid acid and of a value of at least about 500°

F., tangentially into one end of a cylindrical chamber in which said nozzle holder and nozzle are mounted in such a manner that said stream of hot gas will travel in a helical manner and will entrain and vaporize substantially all of the acid mist plume emanating from said nozzle; and

passing the stream of hot gas containing said vaporized acid into said flue gas stream after it has traversed the length of said cylindrical chamber.

2. The method of claim 1 wherein said conditioning agent comprises H₂ SO₄ injected at a rate of 15-30 ppm acid to flue gas.

3. The method of claim 2 wherein the quantity of acid injected is automatically varied with changes in the flow rate for the flue gas stream.

4. The method of claim 3 wherein the volume of gas in said stream of hot gas is maintained constant while the quantity of acid injected into said hot gas is varied.

5. The method of claim 1 wherein said liquid acid conditioning agent is at ambient temperature when it is passed through the said first line into said nozzle holder.

6. The method of claim 4 wherein the stream of hot gas is tapped off from the air preheater for the boiler from which the flue gas stream is emanating.

7. The method of claim 1 wherein said nozzle is mounted on the axis of said cylindrical chamber and said chamber is positioned adjacent a duct containing said flue gas stream.

8. The method of claim 7 wherein said acid mist is introduced into said chamber by said nozzle at a location slightly downstream of the point at which the hot gas enters the chamber.

9. The method of claim 8 wherein said location is about 2 inches downstream from the point at which the hot gas enters the chamber.

10. An apparatus for injecting a vapor of liquid acid into a flue gas stream to condition fly ash in the stream and enhance the efficiency with which the fly ash can be electrostatically precipitated downstream of the apparatus comprising at least one cylindrical chamber positioned adjacent to and in communication with said flue gas stream;

a source of liquid acid;

a source of compressed air;

at least one sonic nozzle for delivering an acid mist, said nozzle being mounted on a nozzle holder in said at least one chamber on the axis of said chamber near one end thereof;

a pump for delivering acid to said nozzle under pressure;

said nozzle being connected to said sources of acid and air by flow lines, said chamber having a tangential inlet opening near said one end in communication with a source of hot gas and an outlet opening near the other end thereof in communication with said flue gas stream, said openings being positioned to cause said hot gas to follow a helical path around and past the spray pattern of mist from said at least one nozzle to entrain the mist and vaporize it before it is injected into the flue gas stream.

11. An apparatus in accordance with claim 10 wherein said nozzle includes an axially positioned venturi shaped orifice through which air is directed in an axial direction and a plurality of radial openings extend-out outwardly from said orifice to an acid-containing chamber for delivering acid to said orifice where it is entrained in said air and carried outwardly.

12. An apparatus in accordance with claim 10 wherein said at least one sonic nozzle has air and acid supply lines connected to it for delivering air and acid at ambient temperature.

13. An apparatus in accordance with claim 10 wherein said source of hot gas is the combustion air preheater for a boiler from which the flue gas stream emanates.

14. An apparatus in accordance with claim 10 wherein said nozzle is mounted on said nozzle holder so as to inject a mist of acid slightly downstream of said tangential inlet opening.

15. An apparatus in accordance with claim 14 wherein said nozzle injects a mist about 2 inches downstream of said inlet opening.

16. An apparatus in accordance with claim 14 wherein said nozzle holder has a conically shaped forward end portion having an included angle of about 60°

, said nozzle being positioned at the tip thereof with its sides flush with the walls of the nozzle holder.

17. An apparatus in accordance with claim 14 wherein both said inlet and outlet openings are positioned in the wall of the chamber so that the hot gas will enter and leave in a direction tangentially of the chamber.