Method for increasing the hydrogen sulphide concentration in an acid gas

• US 4,210,627 A
• Filed: 01/31/1978
• Issued: 07/01/1980
• Est. Priority Date: 02/04/1977
• Status: Expired due to Term

• Current Assignee: Shell Oil Company (Shell Plc)
• Original Assignee: Shell Oil Company (Shell Plc)
• Inventors: Verloop, Jan, Braam, Johannes W. T. M.
• Primary Examiner(s): Thomas, Earl C.
• Application Number:
  US05/873,821
• Time in Patent Office: 882 Days
• Field of Search: 423/220, 423/226, 423/228, 423/229, 423/232, 423/233, 423/574 L, 261/21-23 R, 261/45, 261/46, 261/54, 261/55, 261/63, 261/146-148, 55/30, 55/31, 55/18, 55/63, 55/68, 55/73, 55/180, 55/226, 55/225, 422/108-111
• US Class Current: 423/220
• CPC Class Codes: B01D 53/1412 Controlling the absorption process
• CPC Class Codes: B01D 53/1425 Regeneration of liquid absorbents
• CPC Class Codes: B01D 53/1456 Removing acid components
• CPC Class Codes: B01D 53/1468 Removing hydrogen sulfide
• CPC Class Codes: C01B 17/0408 Pretreatment of the hydrogen sulfide containing gases
• CPC Class Codes: C01B 17/167 Separation
• CPC Class Codes: Y02P 20/151 Reduction of greenhouse gas [GHG] emissions, e.g. CO2

Abstract

A method for increasing the hydrogen sulfide concentration in a gas stream, particularly a stream to be fed to a Claus unit, is disclosed. The method is characterized by the measurement of the flow of the gas stream to an absorption system, and in response to such measurement, separation of a portion of the acid gas leaving the regenerator of the system, and selective absorption of the H₂ S in the portion, with passage of the loaded absorbent to the regenerator.

Claims

1. A process for the removal of H₂ S and CO₂ from a gas stream comprising:

(a) measuring the flow of the gas stream to produce a value representing the magnitude of the gas stream,

(b) contacting said gas stream with a liquid regenerable absorbent in an absorber to absorb H₂ S and CO₂ from the gas stream and producing a loaded absorbent solution,

(c) regenerating the loaded absorbent solution in a regenerator to produce an acid gas stream containing H₂ S and CO₂, and an absorbent solution,

(d) comparing the value representing the magnitude of gas stream entering the absorber of step (a) with a predetermined value, and, if this value is smaller than a predetermined value, passing a portion of the acid gas stream to a second selective absorber, the second absorber being maintained under conditions to absorb H₂ S and reject CO₂ and the absorbent solution being a portion of that regenerated from the regenerator,

(e) returning loaded absorbent solution from the second selective absorber to the regenerator, and

(f) regenerating the loaded absorbent solutions from steps (c) and (e) to produce an acid gas having an increased H₂ S concentration.

2. The method of claim 1 wherein the flow of the gas stream is again measured to produce a value representing the magnitude of the gas stream, and if this value exceeds a second predetermined value, the passing of a portion of the acid gas stream to the second selective absorber is discontinued.

3. The method of claim 1 in which, when actuating the second absorber, the absorbent circulation is started first and the acid gas stream is passed to the second absorber.

4. The method of claim 1 in which the quantity of the acid gas stream passing to the second absorber is measured and the magnitude of the absorbent circulation in the second absorber is controlled in dependence on this quantity.

5. The method of claim 3 in which a value c is calculated from the formula c=-fa+kb, wherein a is the value of the magnitude of the gas stream passing to the absorber, b is the value of the hydrogen sulphide concentration in the acid gas stream or the magnitude of the acid gas stream, f and k represent constants, and the value c is compared with the predetermined value.

6. The method of claim 3 in which a value c is calculated from the formula c=-(m·

a)/(n·

b) wherein a is the magnitude of the gas stream passing to the absorber, b is the value of the hydrogen sulfide concentration in the acid gas stream or the magnitude of the acid gas stream, m and n represent constants, and the value of c is the value compared with the predetermined value.

7. A process for the removal of H₂ S and CO₂ from a gas stream comprising:

(a) measuring the flow of the gas stream to produce a value a representing the magnitude of the gas stream,

(b) contacting said gas stream with a liquid regenerable absorbent in an absorber to absorb H₂ S and CO₂ from the gas stream and producing a loaded absorbent solution,

(c) regenerating the loaded absorbent solution in a regenerator to produce an acid gas stream containing H₂ S and CO₂, and an absorbent solution,

(d) measuring the flow of the acid gas stream to produce a value b representing the magnitude of the acid gas stream or the H₂ S concentration in the acid gas stream,

(e) computing a value c from the formula c=-fa+kb wherein a and b are as above, and f and k represent constants,

(f) comparing the value c with a predetermined value, and, if this value is smaller than a predetermined value, passing a portion of the acid gas stream to a second selective absorber, the second absorber being maintained under conditions to absorb H₂ S and reject CO₂ and the absorbent solution being a portion of that regenerated from the regenerator,

(g) returning loaded absorbent solution from the second selective absorber to the regenerator, and

(h) regenerating the loaded absorbent solutions from steps (c) and (g) to produce an acid gas having an increased H₂ S concentration.

8. The method of claim 7 in which, when actuating the second absorber, the absorbent circulation is started first and the acid gas stream is passed to the second absorber.

9. The method of claim 7 in which the quantity of the acid gas stream passing to the second absorber is measured and the magnitude of the absorbent circulation in the second absorber is controlled in dependence on this quantity.

10. The method of claim 7 wherein the flow of the gas stream and the flow of the acid gas stream are again measured to produce the values a and b, respectively, and the value c is computed according to the formula c=-fa+kb, and if the value c exceeds a second predetermined value, the passing of a portion of the acid gas stream to the second selective absorber is discontinued.

11. A process for the removal of H₂ S and CO₂ from a gas stream comprising:

(a) measuring the flow of the gas stream to produce a value a representing the magnitude of the gas stream,

(b) contacting said gas stream with a liquid regenerable absorbent in an absorber to absorb H₂ S and CO₂ from the gas stream and producing a loaded absorbent solution,

(c) regenerating the loaded absorbent solution in a regenerator to produce an acid gas stream containing H₂ S and CO₂, and an absorbent solution,

(d) measuring the flow of the acid gas stream to produce a value b representing the magnitude of the acid gas stream or the H₂ S concentration in the acid gas stream,

(e) computing a value c from the formula c=-(m·

a/n·

b) wherein a and b are as above, and m and n represent constants,

(f) comparing the value c with a predetermined value, and, if this value is smaller than a predetermined value, passing a portion of the acid gas stream to a second selective absorber, the second absorber being maintained under conditions to absorb H₂ S and reject CO₂ and the absorbent solution being a portion of that regenerated from the regenerator,

(g) returning loaded absorbent solution from the second selective absorber to the regenerator, and

(h) regenerating the loaded absorbent solutions from steps (c) and (g) to produce an acid gas having an increased H₂ S concentration.

12. The method of claim 11 in which, when actuating the second absorber, the absorbent circulation is started first and the acid gas stream is passed to the second absorber.

13. The method of claim 11 in which the quantity of the acid gas stream passing to the second absorber is measured and the magnitude of the absorbent circulation in the second absorber is controlled in dependence on this quantity.

14. The method of claim 11 wherein the flow of the gas stream and the flow of the acid gas stream are again measured to produce the values a and b, respectively, and the value c is computed according to the formula c=-(m·

a/n·

b) and if the value c exceeds a second predetermined value, the passing of a portion of the acid gas stream to the second selective absorber is discontinued.